Methyl Cinnamate Aroma Chemical
CAS# 103-26-4
Sweet, Fruity, Balsamic, Spicy, Cinnamon
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Methyl Cinnamate is a material with a natural-like character, found abundantly in the essential oils of basil, eucalyptus, and strawberry, and also produced commercially through the esterification of cinnamic acid with methanol. At room temperature, it exists as white to slightly yellow crystals and has a relatively low melting point, so it liquefies easily when gently warmed. The history of Methyl Cinnamate is closely tied to the development of organic chemistry in the 19th century, when scientists began successfully isolating compounds from nature for industrial applications. The introduction of this material marked a major advance, providing an effective solution for recreating realistic fruity aromas in both the food and cosmetic industries.
Description
Methyl Cinnamate belongs to the Fruity, Balsamic, and Spicy family. It offers a sweet aroma strongly reminiscent of ripe strawberry and cherry, interwoven with the warmth of cinnamon and balsamic resin. Functioning mainly from the middle note to the base note, it serves as both a modifier and a fixative, adding depth to carnation accords, tuberose compositions, and Oriental fragrance structures. In Perfume and Flavor Chemicals, Steffen Arctander described it as having a “fruity, balsamic, sweet, and powerful odor,” and also praised its usefulness in creating spicy and fruity notes. In practical formulation work, Methyl Cinnamate is often paired with Eugenol, Ionones, or Vanilla to create classic fragrance effects. Because of its solid physical form and relatively strong odor intensity, it is often recommended to dilute it to 10% or 20% in safe solvents such as DPG, IPM, or DEP to make weighing and blending easier.
Applications
The applications of Methyl Cinnamate extend across fine fragrance, soap, scented candles, and the food industry. However, its use in cosmetic products requires strict compliance with IFRA standards. Due to its potential to cause skin sensitization and allergic reactions, its concentration is tightly restricted, and it is generally permitted only at very low levels in leave-on products. In addition, in many major markets, the name of this substance must be clearly declared on the product label to warn consumers who may be prone to allergies. Despite these strict regulations, Methyl Cinnamate remains an important ingredient, appearing in countless Oriental-style perfumes and in many strawberry-flavored or strawberry-scented products worldwide.
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Technical standards
Technical standards
| Physical appearance | Crystals or crystalline powder | Conform |
| Color | White to pale yellow | Conform |
| Purity | ≥ 99.0% | 99.9% |
Solubility @25˚C
Solubility @25˚C
| Solvent | Solubility (g/L) |
|---|---|
| ethanol | 186.29 |
| methanol | 206.53 |
| isopropanol | 81.96 |
| water | 0.17 |
| ethyl acetate | 440.99 |
| n-propanol | 115.19 |
| acetone | 181.64 |
| n-butanol | 87.79 |
| acetonitrile | 290.18 |
| DMF | 413.41 |
| toluene | 191.2 |
| isobutanol | 62.12 |
| 1,4-dioxane | 511.62 |
| methyl acetate | 348.46 |
| THF | 319.77 |
| 2-butanone | 273.3 |
| n-pentanol | 73.3 |
| sec-butanol | 87.47 |
| n-hexane | 3.09 |
| ethylene glycol | 45.86 |
| NMP | 247.98 |
| cyclohexane | 5.82 |
| DMSO | 392.73 |
| n-butyl acetate | 146.01 |
| n-octanol | 23.38 |
| chloroform | 649.22 |
| n-propyl acetate | 159.69 |
| acetic acid | 169.8 |
| dichloromethane | 782.48 |
| cyclohexanone | 223.89 |
| propylene glycol | 57.03 |
| isopropyl acetate | 153.91 |
| DMAc | 435.43 |
| 2-ethoxyethanol | 209.45 |
| isopentanol | 83.26 |
| n-heptane | 3.17 |
| ethyl formate | 129.55 |
| 1,2-dichloroethane | 548.23 |
| n-hexanol | 65.62 |
| 2-methoxyethanol | 337.7 |
| isobutyl acetate | 82.01 |
| tetrachloromethane | 34.38 |
| n-pentyl acetate | 53.76 |
| transcutol | 1052.15 |
| n-heptanol | 25.88 |
| ethylbenzene | 77.33 |
| MIBK | 106.7 |
| 2-propoxyethanol | 162.94 |
| tert-butanol | 126.66 |
| MTBE | 145.56 |
| 2-butoxyethanol | 81.61 |
| propionic acid | 142.39 |
| o-xylene | 84.85 |
| formic acid | 89.25 |
| diethyl ether | 248.2 |
| m-xylene | 74.1 |
| p-xylene | 75.05 |
| chlorobenzene | 171.84 |
| dimethyl carbonate | 137.59 |
| n-octane | 1.38 |
| formamide | 266.04 |
| cyclopentanone | 270.1 |
| 2-pentanone | 180.63 |
| anisole | 229.35 |
| cyclopentyl methyl ether | 147.01 |
| gamma-butyrolactone | 365.78 |
| 1-methoxy-2-propanol | 201.81 |
| pyridine | 523.32 |
| 3-pentanone | 173.55 |
| furfural | 370.66 |
| n-dodecane | 1.54 |
| diethylene glycol | 138.21 |
| diisopropyl ether | 39.99 |
| tert-amyl alcohol | 121.26 |
| acetylacetone | 250.27 |
| n-hexadecane | 1.82 |
| acetophenone | 178.03 |
| methyl propionate | 292.98 |
| isopentyl acetate | 124.97 |
| trichloroethylene | 1074.63 |
| n-nonanol | 23.15 |
| cyclohexanol | 62.5 |
| benzyl alcohol | 139.35 |
| 2-ethylhexanol | 46.12 |
| isooctanol | 23.61 |
| dipropyl ether | 63.84 |
| 1,2-dichlorobenzene | 154.77 |
| ethyl lactate | 64.46 |
| propylene carbonate | 170.68 |
| n-methylformamide | 226.34 |
| 2-pentanol | 58.65 |
| n-pentane | 2.65 |
| 1-propoxy-2-propanol | 98.91 |
| 1-methoxy-2-propyl acetate | 170.25 |
| 2-(2-methoxypropoxy) propanol | 132.52 |
| mesitylene | 36.65 |
| ε-caprolactone | 199.78 |
| p-cymene | 31.06 |
| epichlorohydrin | 655.35 |
| 1,1,1-trichloroethane | 262.54 |
| 2-aminoethanol | 90.76 |
| morpholine-4-carbaldehyde | 355.68 |
| sulfolane | 373.58 |
| 2,2,4-trimethylpentane | 4.55 |
| 2-methyltetrahydrofuran | 248.82 |
| n-hexyl acetate | 80.84 |
| isooctane | 2.96 |
| 2-(2-butoxyethoxy)ethanol | 178.55 |
| sec-butyl acetate | 111.21 |
| tert-butyl acetate | 157.27 |
| decalin | 8.93 |
| glycerin | 99.6 |
| diglyme | 412.51 |
| acrylic acid | 136.07 |
| isopropyl myristate | 33.96 |
| n-butyric acid | 150.64 |
| acetyl acetate | 192.68 |
| di(2-ethylhexyl) phthalate | 38.35 |
| ethyl propionate | 171.53 |
| nitromethane | 460.82 |
| 1,2-diethoxyethane | 226.75 |
| benzonitrile | 154.38 |
| trioctyl phosphate | 21.54 |
| 1-bromopropane | 185.98 |
| gamma-valerolactone | 370.04 |
| n-decanol | 17.39 |
| triethyl phosphate | 59.27 |
| 4-methyl-2-pentanol | 37.13 |
| propionitrile | 197.33 |
| vinylene carbonate | 179.75 |
| 1,1,2-trichlorotrifluoroethane | 314.69 |
| DMS | 134.68 |
| cumene | 41.88 |
| 2-octanol | 15.42 |
| 2-hexanone | 128.2 |
| octyl acetate | 38.95 |
| limonene | 40.26 |
| 1,2-dimethoxyethane | 338.92 |
| ethyl orthosilicate | 56.78 |
| tributyl phosphate | 33.85 |
| diacetone alcohol | 168.19 |
| N,N-dimethylaniline | 120.63 |
| acrylonitrile | 291.71 |
| aniline | 190.0 |
| 1,3-propanediol | 118.81 |
| bromobenzene | 194.13 |
| dibromomethane | 402.78 |
| 1,1,2,2-tetrachloroethane | 690.12 |
| 2-methyl-cyclohexyl acetate | 83.53 |
| tetrabutyl urea | 46.05 |
| diisobutyl methanol | 29.0 |
| 2-phenylethanol | 102.26 |
| styrene | 124.0 |
| dioctyl adipate | 64.73 |
| dimethyl sulfate | 198.06 |
| ethyl butyrate | 121.68 |
| methyl lactate | 95.51 |
| butyl lactate | 47.89 |
| diethyl carbonate | 99.92 |
| propanediol butyl ether | 77.59 |
| triethyl orthoformate | 80.78 |
| p-tert-butyltoluene | 29.83 |
| methyl 4-tert-butylbenzoate | 98.48 |
| morpholine | 518.86 |
| tert-butylamine | 65.7 |
| n-dodecanol | 13.58 |
| dimethoxymethane | 304.86 |
| ethylene carbonate | 126.94 |
| cyrene | 111.31 |
| 2-ethoxyethyl acetate | 135.82 |
| 2-ethylhexyl acetate | 103.12 |
| 1,2,4-trichlorobenzene | 204.0 |
| 4-methylpyridine | 367.38 |
| dibutyl ether | 52.65 |
| 2,6-dimethyl-4-heptanol | 29.0 |
| DEF | 269.21 |
| dimethyl isosorbide | 216.82 |
| tetrachloroethylene | 370.97 |
| eugenol | 103.46 |
| triacetin | 119.19 |
| span 80 | 78.47 |
| 1,4-butanediol | 41.14 |
| 1,1-dichloroethane | 334.76 |
| 2-methyl-1-pentanol | 79.32 |
| methyl formate | 147.62 |
| 2-methyl-1-butanol | 78.42 |
| n-decane | 2.34 |
| butyronitrile | 131.63 |
| 3,7-dimethyl-1-octanol | 34.75 |
| 1-chlorooctane | 19.36 |
| 1-chlorotetradecane | 7.97 |
| n-nonane | 1.98 |
| undecane | 1.86 |
| tert-butylcyclohexane | 8.38 |
| cyclooctane | 2.27 |
| cyclopentanol | 57.89 |
| tetrahydropyran | 260.16 |
| tert-amyl methyl ether | 117.88 |
| 2,5,8-trioxanonane | 265.35 |
| 1-hexene | 32.41 |
| 2-isopropoxyethanol | 134.36 |
| 2,2,2-trifluoroethanol | 64.48 |
| methyl butyrate | 186.7 |
Scent© AI

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CAS NUMBER
103-26-4
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FAMILIES
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BRAND
Scent.vn
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EVAPORATION RATE
Slow
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Odor impact
High est.
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FLASH POINT
114.72 ˚C est.
Olfactory Pyramid
Notes
| Sweet |
| Fruity |
| Balsamic |
| Spicy |
| Cinnamon |
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
|
Category 1
Products applied to the lips
|
No restriction |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
No restriction |
|
Category 2
Products applied to the axillae
|
No restriction |
Category 7B
Leave-on products applied to the hair with some hand contact
|
No restriction |
|
Category 3
Products applied to the face/body using fingertips
|
No restriction |
Category 8
Products with significant anogenital exposure
|
No restriction |
|
Category 4
Products related to fine fragrance
|
No restriction |
Category 9
Products with body and hand exposure, primarily rinse off
|
No restriction |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
No restriction |
Category 10A
Household care products with mostly hand contact
|
No restriction |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
No restriction |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
No restriction |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
No restriction |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
No restriction |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
No restriction |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
No restriction |
|
Category 6
Products with oral and lip exposure
|
No restriction |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |
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Certificates of Quality
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Certificate of Analysis (COA)
Provides information on the physical and chemical properties of the product.Download -
IFRA Certificate of Conformity
Sets safety standards and guidelines for the product in manufacturing.Download -
Safety Data Sheet (SDS)
Provides important safety guidelines for transporting, storing, and using the product.Download