Methyl Benzoate Aroma Chemical
CAS# 93-58-3
Fruity, Floral, Sweet, Cherry, Almond
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Methyl Benzoate (CAS 93-58-3) is an organic compound belonging to the aromatic ester group with the chemical formula C6H5COOCH3. It is a clear, colorless liquid that is poorly soluble in water but miscible with many organic solvents. The most prominent characteristic of this chemical is its highly distinctive odor: sweet, rich, and a blend of floral and fruity notes, reminiscent of feijoa, ylang-ylang, tuberose, cherry, and almond. In nature, Methyl Benzoate is emitted from various fruits and flower essential oils, such as guava, mango, kiwi, snapdragon, and petunia, to attract pollinating bees.
In the perfumery and food industries, thanks to its captivating scent profile, Methyl Benzoate plays an indispensable role. It is particularly useful in formulating and recreating intense, deep white floral notes such as ylang-ylang, tuberose, jasmine, and narcissus. Furthermore, this chemical is recognized by the US Food and Drug Administration (FDA) and the European Union (EU) as Generally Recognized As Safe (GRAS) for use as a food flavoring agent. When diluted at appropriate concentrations, it imparts flavors of cherry, vanilla, tropical fruits, and rum to food products, chewing gum, and beverages.
In the industrial and manufacturing sectors, Methyl Benzoate acts as a powerful solvent. It is commonly used as a solvent for cellulose ethers, cellulose esters, synthetic resins, and rubber. In the textile industry, it is applied as a dyeing assistant (carrier) for polyester fibers, which helps to shorten the dyeing time, lower the required temperature, and improve the color fastness of the dyed fabric. Additionally, it serves as an important intermediate for synthesizing other chemical and pharmaceutical compounds.
Its potential applications in biorational agriculture and forensic science are attracting significant attention. Recently, it has been proven to be an efficient and environmentally friendly "green pesticide". Studies demonstrate that this chemical can repel and kill the eggs and larvae of numerous agricultural and stored-product pests (such as the spotted wing drosophila, brown marmorated stink bug, diamondback moth, and red imported fire ant) by inhibiting the neural enzyme acetylcholinesterase (AChE). While highly toxic to insect pests, it is safe for natural enemies and pollinators like honeybees and lady beetles, making it ideal for integrated pest management (IPM) programs. In forensics, because Methyl Benzoate is a natural degradation product of cocaine in humid environments, it is frequently used as a signature scent to train drug-detection dogs.
Regarding safety and the environment, Methyl Benzoate exhibits a low to moderate level of toxicity to humans. It carries hazard warnings that it is harmful if swallowed (H302) and is suspected of damaging the unborn child (H361d). It may also cause mild irritation to the skin, eyes, and respiratory tract. However, according to ecological assessments, Methyl Benzoate is readily biodegradable in the environment (achieving a 62% degradation rate after 29 days) and does not have the potential for long-term bioaccumulation. This makes it a sustainable material choice when stored and used in compliance with safety regulations.
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Technical standards
Technical standards
Solubility @25˚C
Solubility @25˚C
| Solvent | Solubility (g/L) |
|---|---|
| ethanol | 530.93 |
| methanol | 537.87 |
| isopropanol | 374.32 |
| water | 6.44 |
| ethyl acetate | 589.44 |
| n-propanol | 379.9 |
| acetone | 812.52 |
| n-butanol | 352.2 |
| acetonitrile | 1083.33 |
| DMF | 1297.28 |
| toluene | 371.18 |
| isobutanol | 295.45 |
| 1,4-dioxane | 1017.64 |
| methyl acetate | 751.94 |
| THF | 698.66 |
| 2-butanone | 682.54 |
| n-pentanol | 297.2 |
| sec-butanol | 366.15 |
| n-hexane | 67.56 |
| ethylene glycol | 196.79 |
| NMP | 850.64 |
| cyclohexane | 112.95 |
| DMSO | 928.94 |
| n-butyl acetate | 440.39 |
| n-octanol | 346.34 |
| chloroform | 2576.01 |
| n-propyl acetate | 513.07 |
| acetic acid | 673.93 |
| dichloromethane | 2925.16 |
| cyclohexanone | 757.96 |
| propylene glycol | 142.23 |
| isopropyl acetate | 297.81 |
| DMAc | 818.77 |
| 2-ethoxyethanol | 506.46 |
| isopentanol | 295.08 |
| n-heptane | 87.12 |
| ethyl formate | 704.24 |
| 1,2-dichloroethane | 1538.74 |
| n-hexanol | 307.85 |
| 2-methoxyethanol | 678.06 |
| isobutyl acetate | 246.85 |
| tetrachloromethane | 426.65 |
| n-pentyl acetate | 348.96 |
| transcutol | 1123.79 |
| n-heptanol | 259.97 |
| ethylbenzene | 295.38 |
| MIBK | 275.71 |
| 2-propoxyethanol | 433.67 |
| tert-butanol | 448.38 |
| MTBE | 355.94 |
| 2-butoxyethanol | 375.92 |
| propionic acid | 544.27 |
| o-xylene | 303.08 |
| formic acid | 273.98 |
| diethyl ether | 442.65 |
| m-xylene | 277.66 |
| p-xylene | 384.18 |
| chlorobenzene | 646.26 |
| dimethyl carbonate | 331.52 |
| n-octane | 57.51 |
| formamide | 684.77 |
| cyclopentanone | 851.34 |
| 2-pentanone | 487.54 |
| anisole | 531.69 |
| cyclopentyl methyl ether | 348.58 |
| gamma-butyrolactone | 1040.9 |
| 1-methoxy-2-propanol | 425.89 |
| pyridine | 1027.32 |
| 3-pentanone | 401.16 |
| furfural | 1081.51 |
| n-dodecane | 52.5 |
| diethylene glycol | 388.22 |
| diisopropyl ether | 143.89 |
| tert-amyl alcohol | 401.51 |
| acetylacetone | 510.71 |
| n-hexadecane | 59.66 |
| acetophenone | 493.13 |
| methyl propionate | 485.67 |
| isopentyl acetate | 330.24 |
| trichloroethylene | 2898.99 |
| n-nonanol | 282.11 |
| cyclohexanol | 331.47 |
| benzyl alcohol | 397.41 |
| 2-ethylhexanol | 232.04 |
| isooctanol | 205.19 |
| dipropyl ether | 293.63 |
| 1,2-dichlorobenzene | 651.98 |
| ethyl lactate | 244.63 |
| propylene carbonate | 657.37 |
| n-methylformamide | 901.66 |
| 2-pentanol | 256.96 |
| n-pentane | 68.09 |
| 1-propoxy-2-propanol | 336.96 |
| 1-methoxy-2-propyl acetate | 304.71 |
| 2-(2-methoxypropoxy) propanol | 339.65 |
| mesitylene | 198.95 |
| ε-caprolactone | 657.89 |
| p-cymene | 180.62 |
| epichlorohydrin | 1199.26 |
| 1,1,1-trichloroethane | 1183.26 |
| 2-aminoethanol | 264.61 |
| morpholine-4-carbaldehyde | 892.75 |
| sulfolane | 1076.57 |
| 2,2,4-trimethylpentane | 46.11 |
| 2-methyltetrahydrofuran | 575.68 |
| n-hexyl acetate | 519.19 |
| isooctane | 38.19 |
| 2-(2-butoxyethoxy)ethanol | 470.13 |
| sec-butyl acetate | 258.0 |
| tert-butyl acetate | 284.03 |
| decalin | 77.06 |
| glycerin | 231.16 |
| diglyme | 970.12 |
| acrylic acid | 527.22 |
| isopropyl myristate | 200.27 |
| n-butyric acid | 563.93 |
| acetyl acetate | 357.87 |
| di(2-ethylhexyl) phthalate | 151.7 |
| ethyl propionate | 394.03 |
| nitromethane | 1408.6 |
| 1,2-diethoxyethane | 467.28 |
| benzonitrile | 681.61 |
| trioctyl phosphate | 135.16 |
| 1-bromopropane | 689.23 |
| gamma-valerolactone | 899.96 |
| n-decanol | 210.13 |
| triethyl phosphate | 177.92 |
| 4-methyl-2-pentanol | 149.72 |
| propionitrile | 762.6 |
| vinylene carbonate | 766.99 |
| 1,1,2-trichlorotrifluoroethane | 806.92 |
| DMS | 359.68 |
| cumene | 205.72 |
| 2-octanol | 222.71 |
| 2-hexanone | 447.15 |
| octyl acetate | 264.38 |
| limonene | 223.47 |
| 1,2-dimethoxyethane | 905.26 |
| ethyl orthosilicate | 166.01 |
| tributyl phosphate | 152.39 |
| diacetone alcohol | 343.54 |
| N,N-dimethylaniline | 379.26 |
| acrylonitrile | 1096.0 |
| aniline | 405.66 |
| 1,3-propanediol | 352.83 |
| bromobenzene | 760.51 |
| dibromomethane | 1829.2 |
| 1,1,2,2-tetrachloroethane | 1770.29 |
| 2-methyl-cyclohexyl acetate | 242.05 |
| tetrabutyl urea | 225.0 |
| diisobutyl methanol | 151.23 |
| 2-phenylethanol | 332.77 |
| styrene | 399.93 |
| dioctyl adipate | 261.48 |
| dimethyl sulfate | 449.58 |
| ethyl butyrate | 396.22 |
| methyl lactate | 267.32 |
| butyl lactate | 247.51 |
| diethyl carbonate | 310.12 |
| propanediol butyl ether | 338.37 |
| triethyl orthoformate | 240.09 |
| p-tert-butyltoluene | 167.51 |
| methyl 4-tert-butylbenzoate | 380.37 |
| morpholine | 873.71 |
| tert-butylamine | 313.42 |
| n-dodecanol | 164.46 |
| dimethoxymethane | 611.58 |
| ethylene carbonate | 600.03 |
| cyrene | 301.35 |
| 2-ethoxyethyl acetate | 398.19 |
| 2-ethylhexyl acetate | 260.33 |
| 1,2,4-trichlorobenzene | 654.44 |
| 4-methylpyridine | 853.51 |
| dibutyl ether | 350.37 |
| 2,6-dimethyl-4-heptanol | 151.23 |
| DEF | 649.34 |
| dimethyl isosorbide | 458.48 |
| tetrachloroethylene | 1325.77 |
| eugenol | 364.8 |
| triacetin | 408.73 |
| span 80 | 271.15 |
| 1,4-butanediol | 189.44 |
| 1,1-dichloroethane | 1388.1 |
| 2-methyl-1-pentanol | 263.65 |
| methyl formate | 786.22 |
| 2-methyl-1-butanol | 288.66 |
| n-decane | 83.41 |
| butyronitrile | 710.88 |
| 3,7-dimethyl-1-octanol | 239.88 |
| 1-chlorooctane | 293.9 |
| 1-chlorotetradecane | 118.42 |
| n-nonane | 85.79 |
| undecane | 64.81 |
| tert-butylcyclohexane | 71.86 |
| cyclooctane | 46.22 |
| cyclopentanol | 355.7 |
| tetrahydropyran | 632.7 |
| tert-amyl methyl ether | 290.28 |
| 2,5,8-trioxanonane | 615.34 |
| 1-hexene | 218.74 |
| 2-isopropoxyethanol | 352.72 |
| 2,2,2-trifluoroethanol | 312.97 |
| methyl butyrate | 572.98 |
Scent© AI

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CAS NUMBER
93-58-3
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FAMILIES
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BRAND
Scent.vn
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EVAPORATION RATE
Moderately fast
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Odor impact
Medium est.
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FLASH POINT
77.72 ˚C est.
Olfactory Pyramid
Notes
| Fruity |
| Floral |
| Sweet |
| Cherry |
| Almond |
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
|
Category 1
Products applied to the lips
|
No restriction |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
No restriction |
|
Category 2
Products applied to the axillae
|
No restriction |
Category 7B
Leave-on products applied to the hair with some hand contact
|
No restriction |
|
Category 3
Products applied to the face/body using fingertips
|
No restriction |
Category 8
Products with significant anogenital exposure
|
No restriction |
|
Category 4
Products related to fine fragrance
|
No restriction |
Category 9
Products with body and hand exposure, primarily rinse off
|
No restriction |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
No restriction |
Category 10A
Household care products with mostly hand contact
|
No restriction |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
No restriction |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
No restriction |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
No restriction |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
No restriction |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
No restriction |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
No restriction |
|
Category 6
Products with oral and lip exposure
|
No restriction |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |
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Certificates of Quality
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Certificate of Analysis (COA)
Provides information on the physical and chemical properties of the product.Download -
IFRA Certificate of Conformity
Sets safety standards and guidelines for the product in manufacturing.Download -
Safety Data Sheet (SDS)
Provides important safety guidelines for transporting, storing, and using the product.Download