Liffarome alt. Leafovert Aroma Chemical
CAS# 67633-96-9
Green, Floral, Fruity, Fresh, Apple
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Liffarome (CAS# 67633-96-9), chemically identified as (Z)-3-hexen-1-yl methyl carbonate, is a synthetic carbonate ester widely utilized in the fragrance and flavor industries. It appears as a clear, colorless liquid and acts as a crucial link that bridges volatile top notes with the heart of a fragrance. This compound is highly valued by perfumers for its ability to replicate the ephemeral freshness of nature while offering superior stability for industrial applications.
The product features a rich and diverse odor profile, primarily characterized by the scent of fresh green leaves and cut grass, which conveys a crunchy and succulent sensation. It also possesses distinct nuances of fruits like green apple, pear, and peach, alongside floral aspects reminiscent of violet leaf or iris. Compared to traditional green chemicals, Liffarome is considered smoother and less metallic, with a tenacity of approximately 12 hours on a smelling strip, ensuring a long-lasting fresh effect throughout the fragrance's evaporation process.
In practical use, Liffarome is an indispensable ingredient for creating "dewy" or "fresh" effects in high-end perfumes, body washes, shampoos, and lotions. It is remarkably effective even in trace amounts, brightening floral accords such as muguet (lily of the valley) and enhancing the authenticity of tropical fruit notes. Furthermore, due to its stable carbonate structure, it demonstrates excellent stability in harsh environments like bar soaps and alkaline detergents, where many other esters would typically hydrolyze and lose their scent.
Regarding technical safety and handling, Liffarome is typically used at concentration levels ranging from 0.1% to 2.0% in fragrance compounds. The material is regulated by IFRA Standards, which establish maximum acceptable concentrations to mitigate the risk of dermal sensitization. To maintain its optimal quality, Liffarome should be stored in tightly sealed containers—such as amber glass or aluminum bottles—in a cool, dry, and well-ventilated area, protected from direct heat and light to prevent oxidative degradation.
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Technical standards
Technical standards
Solubility @25˚C
Solubility @25˚C
| Solvent | Solubility (g/L) |
|---|---|
| ethanol | 2012.43 |
| methanol | 2336.15 |
| isopropanol | 1572.03 |
| water | 0.77 |
| ethyl acetate | 1745.32 |
| n-propanol | 1455.01 |
| acetone | 3026.57 |
| n-butanol | 1314.56 |
| acetonitrile | 1853.32 |
| DMF | 5127.29 |
| toluene | 730.61 |
| isobutanol | 1129.33 |
| 1,4-dioxane | 2042.37 |
| methyl acetate | 1425.81 |
| THF | 3063.26 |
| 2-butanone | 1997.79 |
| n-pentanol | 1053.13 |
| sec-butanol | 1479.5 |
| n-hexane | 209.46 |
| ethylene glycol | 350.86 |
| NMP | 3441.46 |
| cyclohexane | 179.81 |
| DMSO | 6100.67 |
| n-butyl acetate | 1138.62 |
| n-octanol | 323.41 |
| chloroform | 2767.73 |
| n-propyl acetate | 1119.66 |
| acetic acid | 2507.46 |
| dichloromethane | 3156.56 |
| cyclohexanone | 2143.76 |
| propylene glycol | 474.73 |
| isopropyl acetate | 1080.14 |
| DMAc | 2777.67 |
| 2-ethoxyethanol | 1503.63 |
| isopentanol | 1198.74 |
| n-heptane | 56.34 |
| ethyl formate | 900.43 |
| 1,2-dichloroethane | 2645.76 |
| n-hexanol | 715.44 |
| 2-methoxyethanol | 2395.45 |
| isobutyl acetate | 613.75 |
| tetrachloromethane | 393.63 |
| n-pentyl acetate | 624.43 |
| transcutol | 3805.87 |
| n-heptanol | 300.32 |
| ethylbenzene | 418.9 |
| MIBK | 1036.06 |
| 2-propoxyethanol | 1244.0 |
| tert-butanol | 2162.81 |
| MTBE | 1899.87 |
| 2-butoxyethanol | 643.44 |
| propionic acid | 1420.83 |
| o-xylene | 465.08 |
| formic acid | 807.43 |
| diethyl ether | 1850.44 |
| m-xylene | 536.31 |
| p-xylene | 493.25 |
| chlorobenzene | 952.11 |
| dimethyl carbonate | 592.96 |
| n-octane | 29.97 |
| formamide | 1481.02 |
| cyclopentanone | 2881.26 |
| 2-pentanone | 1851.67 |
| anisole | 924.02 |
| cyclopentyl methyl ether | 1772.43 |
| gamma-butyrolactone | 3057.13 |
| 1-methoxy-2-propanol | 1940.53 |
| pyridine | 1827.86 |
| 3-pentanone | 1225.86 |
| furfural | 2089.63 |
| n-dodecane | 25.81 |
| diethylene glycol | 853.66 |
| diisopropyl ether | 479.82 |
| tert-amyl alcohol | 1886.85 |
| acetylacetone | 1798.34 |
| n-hexadecane | 29.85 |
| acetophenone | 853.71 |
| methyl propionate | 1420.36 |
| isopentyl acetate | 969.73 |
| trichloroethylene | 4401.59 |
| n-nonanol | 279.63 |
| cyclohexanol | 1131.6 |
| benzyl alcohol | 673.39 |
| 2-ethylhexanol | 411.88 |
| isooctanol | 259.66 |
| dipropyl ether | 469.7 |
| 1,2-dichlorobenzene | 873.18 |
| ethyl lactate | 425.2 |
| propylene carbonate | 1279.72 |
| n-methylformamide | 2064.1 |
| 2-pentanol | 1106.0 |
| n-pentane | 155.19 |
| 1-propoxy-2-propanol | 856.96 |
| 1-methoxy-2-propyl acetate | 956.47 |
| 2-(2-methoxypropoxy) propanol | 679.2 |
| mesitylene | 331.51 |
| ε-caprolactone | 1771.13 |
| p-cymene | 196.2 |
| epichlorohydrin | 3241.48 |
| 1,1,1-trichloroethane | 1921.84 |
| 2-aminoethanol | 804.59 |
| morpholine-4-carbaldehyde | 2364.48 |
| sulfolane | 4314.31 |
| 2,2,4-trimethylpentane | 107.29 |
| 2-methyltetrahydrofuran | 2535.26 |
| n-hexyl acetate | 853.01 |
| isooctane | 83.41 |
| 2-(2-butoxyethoxy)ethanol | 1000.17 |
| sec-butyl acetate | 752.01 |
| tert-butyl acetate | 1356.55 |
| decalin | 131.15 |
| glycerin | 641.03 |
| diglyme | 1735.05 |
| acrylic acid | 1278.22 |
| isopropyl myristate | 278.21 |
| n-butyric acid | 1732.73 |
| acetyl acetate | 989.94 |
| di(2-ethylhexyl) phthalate | 284.77 |
| ethyl propionate | 964.49 |
| nitromethane | 3822.26 |
| 1,2-diethoxyethane | 1188.8 |
| benzonitrile | 904.43 |
| trioctyl phosphate | 201.91 |
| 1-bromopropane | 1468.52 |
| gamma-valerolactone | 2780.49 |
| n-decanol | 203.87 |
| triethyl phosphate | 290.05 |
| 4-methyl-2-pentanol | 529.83 |
| propionitrile | 1297.39 |
| vinylene carbonate | 1140.11 |
| 1,1,2-trichlorotrifluoroethane | 1961.04 |
| DMS | 706.49 |
| cumene | 279.27 |
| 2-octanol | 252.77 |
| 2-hexanone | 1189.12 |
| octyl acetate | 372.8 |
| limonene | 315.76 |
| 1,2-dimethoxyethane | 2114.4 |
| ethyl orthosilicate | 288.42 |
| tributyl phosphate | 297.73 |
| diacetone alcohol | 1409.77 |
| N,N-dimethylaniline | 654.69 |
| acrylonitrile | 1764.66 |
| aniline | 939.06 |
| 1,3-propanediol | 1094.31 |
| bromobenzene | 1084.94 |
| dibromomethane | 2107.79 |
| 1,1,2,2-tetrachloroethane | 3330.26 |
| 2-methyl-cyclohexyl acetate | 526.67 |
| tetrabutyl urea | 383.27 |
| diisobutyl methanol | 247.06 |
| 2-phenylethanol | 550.92 |
| styrene | 574.18 |
| dioctyl adipate | 428.96 |
| dimethyl sulfate | 1140.4 |
| ethyl butyrate | 652.5 |
| methyl lactate | 632.63 |
| butyl lactate | 511.66 |
| diethyl carbonate | 423.14 |
| propanediol butyl ether | 743.61 |
| triethyl orthoformate | 404.66 |
| p-tert-butyltoluene | 205.42 |
| methyl 4-tert-butylbenzoate | 579.52 |
| morpholine | 2863.27 |
| tert-butylamine | 1355.81 |
| n-dodecanol | 149.29 |
| dimethoxymethane | 1942.32 |
| ethylene carbonate | 903.05 |
| cyrene | 668.36 |
| 2-ethoxyethyl acetate | 874.75 |
| 2-ethylhexyl acetate | 728.44 |
| 1,2,4-trichlorobenzene | 1069.11 |
| 4-methylpyridine | 2040.3 |
| dibutyl ether | 481.89 |
| 2,6-dimethyl-4-heptanol | 247.06 |
| DEF | 2367.54 |
| dimethyl isosorbide | 1077.72 |
| tetrachloroethylene | 1954.13 |
| eugenol | 609.55 |
| triacetin | 700.08 |
| span 80 | 626.8 |
| 1,4-butanediol | 484.66 |
| 1,1-dichloroethane | 2335.12 |
| 2-methyl-1-pentanol | 1001.12 |
| methyl formate | 1245.23 |
| 2-methyl-1-butanol | 1176.37 |
| n-decane | 41.97 |
| butyronitrile | 1405.64 |
| 3,7-dimethyl-1-octanol | 357.1 |
| 1-chlorooctane | 233.9 |
| 1-chlorotetradecane | 90.39 |
| n-nonane | 41.5 |
| undecane | 31.8 |
| tert-butylcyclohexane | 126.92 |
| cyclooctane | 57.45 |
| cyclopentanol | 1320.53 |
| tetrahydropyran | 2193.48 |
| tert-amyl methyl ether | 1376.42 |
| 2,5,8-trioxanonane | 1105.25 |
| 1-hexene | 725.41 |
| 2-isopropoxyethanol | 1020.02 |
| 2,2,2-trifluoroethanol | 667.81 |
| methyl butyrate | 1361.03 |
Scent© AI

Olfactory Pyramid
Notes
| Green |
| Floral |
| Fruity |
| Fresh |
| Apple |
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
|
Category 1
Products applied to the lips
|
0.1 % |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
1.1 % |
|
Category 2
Products applied to the axillae
|
0.03 % |
Category 7B
Leave-on products applied to the hair with some hand contact
|
1.1 % |
|
Category 3
Products applied to the face/body using fingertips
|
0.6 % |
Category 8
Products with significant anogenital exposure
|
0.047 % |
|
Category 4
Products related to fine fragrance
|
0.56 % |
Category 9
Products with body and hand exposure, primarily rinse off
|
1.1 % |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
0.14 % |
Category 10A
Household care products with mostly hand contact
|
3.9 % |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
0.14 % |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
3.9 % |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
0.14 % |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
0.047 % |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
0.047 % |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
0.047 % |
|
Category 6
Products with oral and lip exposure
|
0.33 % |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |
Shipping & Returns
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All orders will be processed within 1-2 business days from the time the order is confirmed. -
Free shipping is available for orders valued at $200 or more. -
Delivery time is 1-3 business days for local areas, 3-7 days for suburban and nationwide deliveries, and 1-4 weeks for international orders. -
You have 30 days from the date of receipt to initiate the return process.
Certificates of Quality
-
Certificate of Analysis (COA)
Provides information on the physical and chemical properties of the product.Download -
IFRA Certificate of Conformity
Sets safety standards and guidelines for the product in manufacturing.Download -
Safety Data Sheet (SDS)
Provides important safety guidelines for transporting, storing, and using the product.Download