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Hedione Aroma Chemical
CAS# 24851-98-7

Floral, Jasmin, Green, Fruity, Oily

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Hedione is the trade name registered by Firmenich for the compound Methyl Dihydrojasmonate, often abbreviated MDJ. This material also appears under other names such as Kharismal (IFF), Claigeon (Zeon), and Cepionate. It is a clear synthetic liquid-colorless or very pale yellow-with a fresh, transparent, airy jasmine scent, accented by a soft citrus nuance. In the late 1950s, while researching the composition of jasmine essential oil, Firmenich scientists identified Methyl Jasmonate as a core factor, but it was too unstable and difficult to prepare, so they shifted toward successfully synthesizing MDJ. Although MDJ was later found in trace amounts in nature (for example in black tea and jasmine), all commercial material today is man-made. The compound was discovered in 1958 by Dr. Edouard Demole of Firmenich, Switzerland, and named Hedione, derived from the Greek word hedone, meaning joy or pleasure. However, it truly became legendary in 1966 when perfumer Edmond Roudnitska boldly used about 2% to 3% Hedione in the formula for Dior Eau Sauvage, ushering in a new era of modern perfumery focused on freshness and diffusion.

Description

In terms of character, Hedione belongs to the green-floral and citrus family, sits mainly in the heart, and functions as both a radiance booster and a modulating agent. It recreates a green, fresh jasmine effect with a hint of lemon, while completely removing the harsh, indolic, or animalic facets found in natural jasmine. Smelled neat, it can seem quite gentle, yet it has outstanding diffusive power-lifting other notes and projecting them farther into the air-with strip longevity ranging from several days to up to a week. In formulation, Hedione creates a bright, transparent effect: it helps bind materials together, smooths sharp edges, and increases overall volume without changing the core odor identity. It appears frequently in jasmine, lily-of-the-valley, and citrus accords. Paired with bergamot or lemon, it softens sharpness, extends freshness, and makes the citrus feel more natural; paired with Iso E Super, the duo forms a modern, abstract, highly wearable base with strong diffusion and substantivity. Thanks to its stable liquid form and good solubility in both alcohol and carrier oils, perfumers often use Hedione directly without pre-dilution.

Applications

Its range of use is extremely broad, making it one of the most widely used materials in the history of fine fragrance. It is also common in personal-care products such as shampoo, shower gel, and creams because it is very stable and does not discolor formulas, as well as in home-fragrance products like scented candles and reed/air diffusers. From a safety standpoint, Hedione is considered very gentle, with low sensitization potential, and is not restricted in concentration by IFRA-allowing highly flexible use levels from 1% to 30%, or even higher in special formulas. For storage, keep it tightly closed in a dry, cool, well-ventilated place and avoid high temperatures. On the market, beyond the pioneering Dior Eau Sauvage, Hedione is also used heavily in Calvin Klein CK One to create a clean unisex profile, in Giorgio Armani Acqua di Giò to build its watery-floral freshness, and to add lift in Maison Francis Kurkdjian Baccarat Rouge 540 alongside Ambroxan and Ethyl Maltol. Finally, in the 1969 book Perfume and Flavor Chemicals, expert Steffen Arctander described material No. 1884 as having a floral character with a somewhat powerful oily nuance, reminiscent of jasmine; when suitably diluted, it becomes very pleasant-sweet, warm, yet still fresh. He also accurately predicted that it would appear in many perfumes beyond jasmine, including Chypre and Oriental types, where it brings radiance and an elegant, rich floral effect.

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Technical standards

Physical appearance Transparent liquid Conform
Color Colorless to pale yellow Conform
Specific Gravity @20˚C 0.997 → 1.008 1.003
Refractive Index @20˚C 1.454 → 1.465 1.459
Acid value (mgKOH/g) ≤ 2.0 0.042
cis Isomer 9.0% → 11.0% 10.68%
trans Isomer ≥ 85.0% 87.86%

Solubility @25˚C

Solvent Solubility (g/L)
ethanol 3192.19
methanol 5383.34
isopropanol 2483.81
water 1.38
ethyl acetate 3226.91
n-propanol 2180.47
acetone 4650.35
n-butanol 1718.25
acetonitrile 3414.05
DMF 4017.12
toluene 796.27
isobutanol 1522.44
1,4-dioxane 3313.3
methyl acetate 2023.96
THF 3636.61
2-butanone 2570.7
n-pentanol 961.81
sec-butanol 1416.28
n-hexane 19.41
ethylene glycol 403.24
NMP 2298.72
cyclohexane 72.43
DMSO 3829.72
n-butyl acetate 1166.38
n-octanol 160.08
chloroform 5384.33
n-propyl acetate 1368.71
acetic acid 3488.2
dichloromethane 4356.79
cyclohexanone 3258.09
propylene glycol 660.49
isopropyl acetate 1918.25
DMAc 2163.1
2-ethoxyethanol 1744.73
isopentanol 1553.24
n-heptane 5.93
ethyl formate 1725.1
1,2-dichloroethane 2828.45
n-hexanol 579.78
2-methoxyethanol 3327.94
isobutyl acetate 789.78
tetrachloromethane 485.9
n-pentyl acetate 529.52
transcutol 4736.5
n-heptanol 186.98
ethylbenzene 307.55
MIBK 1182.91
2-propoxyethanol 1279.87
tert-butanol 2402.57
MTBE 1736.25
2-butoxyethanol 598.87
propionic acid 1748.07
o-xylene 409.49
formic acid 1211.79
diethyl ether 1632.05
m-xylene 487.81
p-xylene 425.7
chlorobenzene 1349.18
dimethyl carbonate 638.01
n-octane 3.4
formamide 2067.65
cyclopentanone 3190.56
2-pentanone 2152.69
anisole 897.09
cyclopentyl methyl ether 1352.08
gamma-butyrolactone 3780.68
1-methoxy-2-propanol 2251.88
pyridine 2877.48
3-pentanone 1120.17
furfural 3021.5
n-dodecane 4.35
diethylene glycol 1054.08
diisopropyl ether 294.63
tert-amyl alcohol 1402.87
acetylacetone 2461.17
n-hexadecane 5.47
acetophenone 883.42
methyl propionate 1650.88
isopentyl acetate 1017.81
trichloroethylene 5733.42
n-nonanol 144.03
cyclohexanol 1339.73
benzyl alcohol 886.16
2-ethylhexanol 261.29
isooctanol 172.23
dipropyl ether 231.65
1,2-dichlorobenzene 1101.84
ethyl lactate 440.59
propylene carbonate 1900.84
n-methylformamide 2616.43
2-pentanol 909.19
n-pentane 19.1
1-propoxy-2-propanol 756.72
1-methoxy-2-propyl acetate 1079.36
2-(2-methoxypropoxy) propanol 565.09
mesitylene 246.42
ε-caprolactone 2653.56
p-cymene 126.39
epichlorohydrin 3789.72
1,1,1-trichloroethane 2468.7
2-aminoethanol 1038.23
morpholine-4-carbaldehyde 2390.8
sulfolane 3076.65
2,2,4-trimethylpentane 23.6
2-methyltetrahydrofuran 2531.01
n-hexyl acetate 640.89
isooctane 19.6
2-(2-butoxyethoxy)ethanol 900.92
sec-butyl acetate 913.36
tert-butyl acetate 1489.18
decalin 41.22
glycerin 871.9
diglyme 1852.38
acrylic acid 1456.16
isopropyl myristate 171.72
n-butyric acid 3071.84
acetyl acetate 1599.62
di(2-ethylhexyl) phthalate 221.86
ethyl propionate 975.47
nitromethane 5489.02
1,2-diethoxyethane 998.3
benzonitrile 1323.16
trioctyl phosphate 127.7
1-bromopropane 1082.27
gamma-valerolactone 4202.35
n-decanol 96.82
triethyl phosphate 219.89
4-methyl-2-pentanol 454.17
propionitrile 1803.52
vinylene carbonate 1724.1
1,1,2-trichlorotrifluoroethane 2528.68
DMS 692.29
cumene 183.49
2-octanol 124.08
2-hexanone 1104.46
octyl acetate 220.05
limonene 179.13
1,2-dimethoxyethane 2572.47
ethyl orthosilicate 215.37
tributyl phosphate 202.27
diacetone alcohol 1465.28
N,N-dimethylaniline 444.5
acrylonitrile 2206.24
aniline 1469.9
1,3-propanediol 1754.15
bromobenzene 1333.19
dibromomethane 2421.94
1,1,2,2-tetrachloroethane 4253.13
2-methyl-cyclohexyl acetate 403.08
tetrabutyl urea 230.36
diisobutyl methanol 152.27
2-phenylethanol 595.61
styrene 486.18
dioctyl adipate 299.0
dimethyl sulfate 917.64
ethyl butyrate 608.6
methyl lactate 700.36
butyl lactate 444.73
diethyl carbonate 405.64
propanediol butyl ether 621.58
triethyl orthoformate 368.09
p-tert-butyltoluene 121.79
methyl 4-tert-butylbenzoate 496.92
morpholine 4256.55
tert-butylamine 1065.38
n-dodecanol 67.11
dimethoxymethane 1867.96
ethylene carbonate 1560.36
cyrene 546.03
2-ethoxyethyl acetate 937.06
2-ethylhexyl acetate 656.98
1,2,4-trichlorobenzene 1320.15
4-methylpyridine 2881.66
dibutyl ether 239.33
2,6-dimethyl-4-heptanol 152.27
DEF 2057.82
dimethyl isosorbide 859.93
tetrachloroethylene 2535.6
eugenol 504.34
triacetin 687.39
span 80 453.24
1,4-butanediol 532.56
1,1-dichloroethane 3264.87
2-methyl-1-pentanol 799.65
methyl formate 1774.77
2-methyl-1-butanol 1221.9
n-decane 7.55
butyronitrile 1866.5
3,7-dimethyl-1-octanol 223.64
1-chlorooctane 85.56
1-chlorotetradecane 28.02
n-nonane 6.1
undecane 5.41
tert-butylcyclohexane 33.21
cyclooctane 13.63
cyclopentanol 1396.88
tetrahydropyran 2755.83
tert-amyl methyl ether 790.82
2,5,8-trioxanonane 1007.28
1-hexene 205.67
2-isopropoxyethanol 1041.62
2,2,2-trifluoroethanol 1054.75
methyl butyrate 1529.71

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  • CAS NUMBER

    24851-98-7

  • FAMILIES

    Floral

  • BRAND

    Kao

  • EVAPORATION RATE

    Ultra slow

  • Odor impact

    Medium est.

  • FLASH POINT

    133.86 ˚C est.

base
Floral
Jasmin
Green
Fruity
Oily
Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
No restriction
Category 2
Products applied to the axillae
No restriction Category 7B
Leave-on products applied to the hair with some hand contact
No restriction
Category 3
Products applied to the face/body using fingertips
No restriction Category 8
Products with significant anogenital exposure
No restriction
Category 4
Products related to fine fragrance
No restriction Category 9
Products with body and hand exposure, primarily rinse off
No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
No restriction Category 10A
Household care products with mostly hand contact
No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
No restriction
Category 5D
Baby Creams, baby Oils and baby talc
No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
No restriction
Category 6
Products with oral and lip exposure
No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
No restriction
  • All orders will be processed within 1-2 business days from the time the order is confirmed.
  • Free shipping is available for orders valued at $500 or more.
  • Delivery time is 1-3 business days for local areas, 3-7 days for suburban and nationwide deliveries, and 1-4 weeks for international orders.
  • You have 30 days from the date of receipt to initiate the return process.
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  • Certificate of Analysis (COA)

    Provides information on the physical and chemical properties of the product.
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  • IFRA Certificate of Conformity

    Sets safety standards and guidelines for the product in manufacturing.
    Download  
  • Safety Data Sheet (SDS)

    Provides important safety guidelines for transporting, storing, and using the product.
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