Hedione Aroma Chemical
CAS# 24851-98-7
Floral, Jasmin, Green, Fruity, Oily
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Hedione is the trade name registered by Firmenich for the compound Methyl Dihydrojasmonate, often abbreviated MDJ. This material also appears under other names such as Kharismal (IFF), Claigeon (Zeon), and Cepionate. It is a clear synthetic liquid-colorless or very pale yellow-with a fresh, transparent, airy jasmine scent, accented by a soft citrus nuance. In the late 1950s, while researching the composition of jasmine essential oil, Firmenich scientists identified Methyl Jasmonate as a core factor, but it was too unstable and difficult to prepare, so they shifted toward successfully synthesizing MDJ. Although MDJ was later found in trace amounts in nature (for example in black tea and jasmine), all commercial material today is man-made. The compound was discovered in 1958 by Dr. Edouard Demole of Firmenich, Switzerland, and named Hedione, derived from the Greek word hedone, meaning joy or pleasure. However, it truly became legendary in 1966 when perfumer Edmond Roudnitska boldly used about 2% to 3% Hedione in the formula for Dior Eau Sauvage, ushering in a new era of modern perfumery focused on freshness and diffusion.
Description
In terms of character, Hedione belongs to the green-floral and citrus family, sits mainly in the heart, and functions as both a radiance booster and a modulating agent. It recreates a green, fresh jasmine effect with a hint of lemon, while completely removing the harsh, indolic, or animalic facets found in natural jasmine. Smelled neat, it can seem quite gentle, yet it has outstanding diffusive power-lifting other notes and projecting them farther into the air-with strip longevity ranging from several days to up to a week. In formulation, Hedione creates a bright, transparent effect: it helps bind materials together, smooths sharp edges, and increases overall volume without changing the core odor identity. It appears frequently in jasmine, lily-of-the-valley, and citrus accords. Paired with bergamot or lemon, it softens sharpness, extends freshness, and makes the citrus feel more natural; paired with Iso E Super, the duo forms a modern, abstract, highly wearable base with strong diffusion and substantivity. Thanks to its stable liquid form and good solubility in both alcohol and carrier oils, perfumers often use Hedione directly without pre-dilution.
Applications
Its range of use is extremely broad, making it one of the most widely used materials in the history of fine fragrance. It is also common in personal-care products such as shampoo, shower gel, and creams because it is very stable and does not discolor formulas, as well as in home-fragrance products like scented candles and reed/air diffusers. From a safety standpoint, Hedione is considered very gentle, with low sensitization potential, and is not restricted in concentration by IFRA-allowing highly flexible use levels from 1% to 30%, or even higher in special formulas. For storage, keep it tightly closed in a dry, cool, well-ventilated place and avoid high temperatures. On the market, beyond the pioneering Dior Eau Sauvage, Hedione is also used heavily in Calvin Klein CK One to create a clean unisex profile, in Giorgio Armani Acqua di Giò to build its watery-floral freshness, and to add lift in Maison Francis Kurkdjian Baccarat Rouge 540 alongside Ambroxan and Ethyl Maltol. Finally, in the 1969 book Perfume and Flavor Chemicals, expert Steffen Arctander described material No. 1884 as having a floral character with a somewhat powerful oily nuance, reminiscent of jasmine; when suitably diluted, it becomes very pleasant-sweet, warm, yet still fresh. He also accurately predicted that it would appear in many perfumes beyond jasmine, including Chypre and Oriental types, where it brings radiance and an elegant, rich floral effect.
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Technical standards
Technical standards
| Physical appearance | Transparent liquid | Conform |
| Color | Colorless to pale yellow | Conform |
| Specific Gravity @20˚C | 0.997 → 1.008 | 1.003 |
| Refractive Index @20˚C | 1.454 → 1.465 | 1.459 |
| Acid value (mgKOH/g) | ≤ 2.0 | 0.042 |
| cis Isomer | 9.0% → 11.0% | 10.68% |
| trans Isomer | ≥ 85.0% | 87.86% |
Solubility @25˚C
Solubility @25˚C
| Solvent | Solubility (g/L) |
|---|---|
| ethanol | 3192.19 |
| methanol | 5383.34 |
| isopropanol | 2483.81 |
| water | 1.38 |
| ethyl acetate | 3226.91 |
| n-propanol | 2180.47 |
| acetone | 4650.35 |
| n-butanol | 1718.25 |
| acetonitrile | 3414.05 |
| DMF | 4017.12 |
| toluene | 796.27 |
| isobutanol | 1522.44 |
| 1,4-dioxane | 3313.3 |
| methyl acetate | 2023.96 |
| THF | 3636.61 |
| 2-butanone | 2570.7 |
| n-pentanol | 961.81 |
| sec-butanol | 1416.28 |
| n-hexane | 19.41 |
| ethylene glycol | 403.24 |
| NMP | 2298.72 |
| cyclohexane | 72.43 |
| DMSO | 3829.72 |
| n-butyl acetate | 1166.38 |
| n-octanol | 160.08 |
| chloroform | 5384.33 |
| n-propyl acetate | 1368.71 |
| acetic acid | 3488.2 |
| dichloromethane | 4356.79 |
| cyclohexanone | 3258.09 |
| propylene glycol | 660.49 |
| isopropyl acetate | 1918.25 |
| DMAc | 2163.1 |
| 2-ethoxyethanol | 1744.73 |
| isopentanol | 1553.24 |
| n-heptane | 5.93 |
| ethyl formate | 1725.1 |
| 1,2-dichloroethane | 2828.45 |
| n-hexanol | 579.78 |
| 2-methoxyethanol | 3327.94 |
| isobutyl acetate | 789.78 |
| tetrachloromethane | 485.9 |
| n-pentyl acetate | 529.52 |
| transcutol | 4736.5 |
| n-heptanol | 186.98 |
| ethylbenzene | 307.55 |
| MIBK | 1182.91 |
| 2-propoxyethanol | 1279.87 |
| tert-butanol | 2402.57 |
| MTBE | 1736.25 |
| 2-butoxyethanol | 598.87 |
| propionic acid | 1748.07 |
| o-xylene | 409.49 |
| formic acid | 1211.79 |
| diethyl ether | 1632.05 |
| m-xylene | 487.81 |
| p-xylene | 425.7 |
| chlorobenzene | 1349.18 |
| dimethyl carbonate | 638.01 |
| n-octane | 3.4 |
| formamide | 2067.65 |
| cyclopentanone | 3190.56 |
| 2-pentanone | 2152.69 |
| anisole | 897.09 |
| cyclopentyl methyl ether | 1352.08 |
| gamma-butyrolactone | 3780.68 |
| 1-methoxy-2-propanol | 2251.88 |
| pyridine | 2877.48 |
| 3-pentanone | 1120.17 |
| furfural | 3021.5 |
| n-dodecane | 4.35 |
| diethylene glycol | 1054.08 |
| diisopropyl ether | 294.63 |
| tert-amyl alcohol | 1402.87 |
| acetylacetone | 2461.17 |
| n-hexadecane | 5.47 |
| acetophenone | 883.42 |
| methyl propionate | 1650.88 |
| isopentyl acetate | 1017.81 |
| trichloroethylene | 5733.42 |
| n-nonanol | 144.03 |
| cyclohexanol | 1339.73 |
| benzyl alcohol | 886.16 |
| 2-ethylhexanol | 261.29 |
| isooctanol | 172.23 |
| dipropyl ether | 231.65 |
| 1,2-dichlorobenzene | 1101.84 |
| ethyl lactate | 440.59 |
| propylene carbonate | 1900.84 |
| n-methylformamide | 2616.43 |
| 2-pentanol | 909.19 |
| n-pentane | 19.1 |
| 1-propoxy-2-propanol | 756.72 |
| 1-methoxy-2-propyl acetate | 1079.36 |
| 2-(2-methoxypropoxy) propanol | 565.09 |
| mesitylene | 246.42 |
| ε-caprolactone | 2653.56 |
| p-cymene | 126.39 |
| epichlorohydrin | 3789.72 |
| 1,1,1-trichloroethane | 2468.7 |
| 2-aminoethanol | 1038.23 |
| morpholine-4-carbaldehyde | 2390.8 |
| sulfolane | 3076.65 |
| 2,2,4-trimethylpentane | 23.6 |
| 2-methyltetrahydrofuran | 2531.01 |
| n-hexyl acetate | 640.89 |
| isooctane | 19.6 |
| 2-(2-butoxyethoxy)ethanol | 900.92 |
| sec-butyl acetate | 913.36 |
| tert-butyl acetate | 1489.18 |
| decalin | 41.22 |
| glycerin | 871.9 |
| diglyme | 1852.38 |
| acrylic acid | 1456.16 |
| isopropyl myristate | 171.72 |
| n-butyric acid | 3071.84 |
| acetyl acetate | 1599.62 |
| di(2-ethylhexyl) phthalate | 221.86 |
| ethyl propionate | 975.47 |
| nitromethane | 5489.02 |
| 1,2-diethoxyethane | 998.3 |
| benzonitrile | 1323.16 |
| trioctyl phosphate | 127.7 |
| 1-bromopropane | 1082.27 |
| gamma-valerolactone | 4202.35 |
| n-decanol | 96.82 |
| triethyl phosphate | 219.89 |
| 4-methyl-2-pentanol | 454.17 |
| propionitrile | 1803.52 |
| vinylene carbonate | 1724.1 |
| 1,1,2-trichlorotrifluoroethane | 2528.68 |
| DMS | 692.29 |
| cumene | 183.49 |
| 2-octanol | 124.08 |
| 2-hexanone | 1104.46 |
| octyl acetate | 220.05 |
| limonene | 179.13 |
| 1,2-dimethoxyethane | 2572.47 |
| ethyl orthosilicate | 215.37 |
| tributyl phosphate | 202.27 |
| diacetone alcohol | 1465.28 |
| N,N-dimethylaniline | 444.5 |
| acrylonitrile | 2206.24 |
| aniline | 1469.9 |
| 1,3-propanediol | 1754.15 |
| bromobenzene | 1333.19 |
| dibromomethane | 2421.94 |
| 1,1,2,2-tetrachloroethane | 4253.13 |
| 2-methyl-cyclohexyl acetate | 403.08 |
| tetrabutyl urea | 230.36 |
| diisobutyl methanol | 152.27 |
| 2-phenylethanol | 595.61 |
| styrene | 486.18 |
| dioctyl adipate | 299.0 |
| dimethyl sulfate | 917.64 |
| ethyl butyrate | 608.6 |
| methyl lactate | 700.36 |
| butyl lactate | 444.73 |
| diethyl carbonate | 405.64 |
| propanediol butyl ether | 621.58 |
| triethyl orthoformate | 368.09 |
| p-tert-butyltoluene | 121.79 |
| methyl 4-tert-butylbenzoate | 496.92 |
| morpholine | 4256.55 |
| tert-butylamine | 1065.38 |
| n-dodecanol | 67.11 |
| dimethoxymethane | 1867.96 |
| ethylene carbonate | 1560.36 |
| cyrene | 546.03 |
| 2-ethoxyethyl acetate | 937.06 |
| 2-ethylhexyl acetate | 656.98 |
| 1,2,4-trichlorobenzene | 1320.15 |
| 4-methylpyridine | 2881.66 |
| dibutyl ether | 239.33 |
| 2,6-dimethyl-4-heptanol | 152.27 |
| DEF | 2057.82 |
| dimethyl isosorbide | 859.93 |
| tetrachloroethylene | 2535.6 |
| eugenol | 504.34 |
| triacetin | 687.39 |
| span 80 | 453.24 |
| 1,4-butanediol | 532.56 |
| 1,1-dichloroethane | 3264.87 |
| 2-methyl-1-pentanol | 799.65 |
| methyl formate | 1774.77 |
| 2-methyl-1-butanol | 1221.9 |
| n-decane | 7.55 |
| butyronitrile | 1866.5 |
| 3,7-dimethyl-1-octanol | 223.64 |
| 1-chlorooctane | 85.56 |
| 1-chlorotetradecane | 28.02 |
| n-nonane | 6.1 |
| undecane | 5.41 |
| tert-butylcyclohexane | 33.21 |
| cyclooctane | 13.63 |
| cyclopentanol | 1396.88 |
| tetrahydropyran | 2755.83 |
| tert-amyl methyl ether | 790.82 |
| 2,5,8-trioxanonane | 1007.28 |
| 1-hexene | 205.67 |
| 2-isopropoxyethanol | 1041.62 |
| 2,2,2-trifluoroethanol | 1054.75 |
| methyl butyrate | 1529.71 |
Scent© AI

Olfactory Pyramid
Notes
| Floral |
| Jasmin |
| Green |
| Fruity |
| Oily |
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
|
Category 1
Products applied to the lips
|
No restriction |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
No restriction |
|
Category 2
Products applied to the axillae
|
No restriction |
Category 7B
Leave-on products applied to the hair with some hand contact
|
No restriction |
|
Category 3
Products applied to the face/body using fingertips
|
No restriction |
Category 8
Products with significant anogenital exposure
|
No restriction |
|
Category 4
Products related to fine fragrance
|
No restriction |
Category 9
Products with body and hand exposure, primarily rinse off
|
No restriction |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
No restriction |
Category 10A
Household care products with mostly hand contact
|
No restriction |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
No restriction |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
No restriction |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
No restriction |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
No restriction |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
No restriction |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
No restriction |
|
Category 6
Products with oral and lip exposure
|
No restriction |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |
Shipping & Returns
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All orders will be processed within 1-2 business days from the time the order is confirmed. -
Free shipping is available for orders valued at $500 or more. -
Delivery time is 1-3 business days for local areas, 3-7 days for suburban and nationwide deliveries, and 1-4 weeks for international orders. -
You have 30 days from the date of receipt to initiate the return process.
Certificates of Quality
-
Certificate of Analysis (COA)
Provides information on the physical and chemical properties of the product.Download -
IFRA Certificate of Conformity
Sets safety standards and guidelines for the product in manufacturing.Download -
Safety Data Sheet (SDS)
Provides important safety guidelines for transporting, storing, and using the product.Download