Eugenol Aroma Chemical
CAS# 97-53-0
Spicy, Sweet, Phenolic, Woody, Clove
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Eugenol is a natural and nature-identical material with an important historical role in the fragrance industry. In nature, it is obtained primarily from clove bud oil, cinnamon leaf oil, basil oil, and bay leaf oil. First isolated in the 19th century, Eugenol holds a notable place in history as one of the key starting materials once used to synthesize artificial vanillin before petrochemical technology became established. Physically, it is a clear to pale yellow liquid that tends to darken upon exposure to air, and it is characterized by a spicy profile with woody and floral facets.
Description
The scent of Eugenol radiates the warm, sweet, and rich spiciness of clove. Functioning from the heart note to the base note, and serving as both an effective blender and modifier, this material has very strong odor impact, excellent diffusion, and lasting power of around 100 to 200 hours on a blotter. In fragrance formulas, it helps build carnation notes, supports oriental and rose accords, and adds warmth and depth to the overall composition. Perfumers often combine it with Isoeugenol, Benzyl Salicylate, and Ylang Ylang to create the classic carnation accord, or pair it with Citronellol, vanilla, and patchouli. Because of its very powerful odor, it is often diluted in DPG for easier control.
Applications
In terms of applications, this material is widely used in perfumes, scented candles, leave-on cosmetics, rinse-off products, soaps, as well as in dentistry and food flavoring. However, Eugenol is strictly regulated by IFRA with respect to maximum use levels due to its skin sensitization potential, and recommended usage is often limited to below about 0.5% to 2.5% depending on the product category. Users should note in particular that it is a mandatory allergen for labeling in Europe and can easily discolor soap to brown or dark yellow in alkaline conditions. Proper storage requires keeping the container tightly closed, in a cool, dry place, away from direct light. Many great oriental and carnation fragrances, such as L’Air du Temps by Nina Ricci and Opium by Yves Saint Laurent, bear the strong signature of this material. Finally, the value of Eugenol was firmly recognized in Perfume and Flavor Chemicals, where expert Steffen Arctander described it as having a warm, sweet spicy odor with a strong woody undertone. He emphasized that it is an indispensable material in carnation and oriental accords, while also warning about its tendency to discolor when exposed to alkali or iron.
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Technical standards
Technical standards
Solubility @25˚C
Solubility @25˚C
| Solvent | Solubility (g/L) |
|---|---|
| ethanol | 912.03 |
| methanol | 1052.53 |
| isopropanol | 628.94 |
| water | 1.01 |
| ethyl acetate | 897.32 |
| n-propanol | 767.1 |
| acetone | 1145.43 |
| n-butanol | 526.63 |
| acetonitrile | 874.13 |
| DMF | 967.34 |
| toluene | 145.17 |
| isobutanol | 428.42 |
| 1,4-dioxane | 1213.16 |
| methyl acetate | 922.88 |
| THF | 1275.13 |
| 2-butanone | 821.75 |
| n-pentanol | 306.51 |
| sec-butanol | 480.66 |
| n-hexane | 28.3 |
| ethylene glycol | 259.68 |
| NMP | 490.18 |
| cyclohexane | 57.77 |
| DMSO | 1570.21 |
| n-butyl acetate | 410.47 |
| n-octanol | 125.56 |
| chloroform | 882.05 |
| n-propyl acetate | 437.6 |
| acetic acid | 742.45 |
| dichloromethane | 929.63 |
| cyclohexanone | 707.57 |
| propylene glycol | 273.56 |
| isopropyl acetate | 323.35 |
| DMAc | 431.33 |
| 2-ethoxyethanol | 593.63 |
| isopentanol | 368.62 |
| n-heptane | 20.58 |
| ethyl formate | 486.68 |
| 1,2-dichloroethane | 831.95 |
| n-hexanol | 328.91 |
| 2-methoxyethanol | 1049.5 |
| isobutyl acetate | 210.85 |
| tetrachloromethane | 123.93 |
| n-pentyl acetate | 161.3 |
| transcutol | 1293.28 |
| n-heptanol | 122.9 |
| ethylbenzene | 91.83 |
| MIBK | 279.17 |
| 2-propoxyethanol | 524.66 |
| tert-butanol | 861.13 |
| MTBE | 621.0 |
| 2-butoxyethanol | 240.66 |
| propionic acid | 556.31 |
| o-xylene | 100.54 |
| formic acid | 280.59 |
| diethyl ether | 803.89 |
| m-xylene | 112.28 |
| p-xylene | 101.35 |
| chlorobenzene | 271.03 |
| dimethyl carbonate | 254.4 |
| n-octane | 10.48 |
| formamide | 590.86 |
| cyclopentanone | 907.02 |
| 2-pentanone | 575.84 |
| anisole | 267.98 |
| cyclopentyl methyl ether | 453.38 |
| gamma-butyrolactone | 1066.08 |
| 1-methoxy-2-propanol | 600.51 |
| pyridine | 557.67 |
| 3-pentanone | 396.26 |
| furfural | 649.06 |
| n-dodecane | 9.98 |
| diethylene glycol | 458.26 |
| diisopropyl ether | 136.09 |
| tert-amyl alcohol | 563.82 |
| acetylacetone | 522.77 |
| n-hexadecane | 11.56 |
| acetophenone | 221.18 |
| methyl propionate | 596.08 |
| isopentyl acetate | 297.43 |
| trichloroethylene | 1208.8 |
| n-nonanol | 104.52 |
| cyclohexanol | 345.41 |
| benzyl alcohol | 205.92 |
| 2-ethylhexanol | 154.77 |
| isooctanol | 99.11 |
| dipropyl ether | 183.4 |
| 1,2-dichlorobenzene | 216.17 |
| ethyl lactate | 158.09 |
| propylene carbonate | 461.7 |
| n-methylformamide | 672.06 |
| 2-pentanol | 321.75 |
| n-pentane | 32.39 |
| 1-propoxy-2-propanol | 310.11 |
| 1-methoxy-2-propyl acetate | 313.45 |
| 2-(2-methoxypropoxy) propanol | 211.73 |
| mesitylene | 78.62 |
| ε-caprolactone | 566.67 |
| p-cymene | 62.5 |
| epichlorohydrin | 1206.06 |
| 1,1,1-trichloroethane | 565.08 |
| 2-aminoethanol | 412.22 |
| morpholine-4-carbaldehyde | 573.23 |
| sulfolane | 940.08 |
| 2,2,4-trimethylpentane | 24.93 |
| 2-methyltetrahydrofuran | 791.09 |
| n-hexyl acetate | 231.56 |
| isooctane | 22.13 |
| 2-(2-butoxyethoxy)ethanol | 327.31 |
| sec-butyl acetate | 220.06 |
| tert-butyl acetate | 335.21 |
| decalin | 29.3 |
| glycerin | 351.34 |
| diglyme | 606.63 |
| acrylic acid | 451.99 |
| isopropyl myristate | 83.78 |
| n-butyric acid | 622.02 |
| acetyl acetate | 348.17 |
| di(2-ethylhexyl) phthalate | 77.05 |
| ethyl propionate | 307.68 |
| nitromethane | 1344.63 |
| 1,2-diethoxyethane | 369.25 |
| benzonitrile | 248.66 |
| trioctyl phosphate | 64.05 |
| 1-bromopropane | 395.48 |
| gamma-valerolactone | 856.06 |
| n-decanol | 77.63 |
| triethyl phosphate | 99.57 |
| 4-methyl-2-pentanol | 158.98 |
| propionitrile | 581.55 |
| vinylene carbonate | 405.62 |
| 1,1,2-trichlorotrifluoroethane | 615.68 |
| DMS | 213.91 |
| cumene | 67.97 |
| 2-octanol | 85.03 |
| 2-hexanone | 354.97 |
| octyl acetate | 107.32 |
| limonene | 93.46 |
| 1,2-dimethoxyethane | 796.37 |
| ethyl orthosilicate | 97.77 |
| tributyl phosphate | 80.33 |
| diacetone alcohol | 374.27 |
| N,N-dimethylaniline | 136.57 |
| acrylonitrile | 674.08 |
| aniline | 271.83 |
| 1,3-propanediol | 546.5 |
| bromobenzene | 252.99 |
| dibromomethane | 623.12 |
| 1,1,2,2-tetrachloroethane | 852.41 |
| 2-methyl-cyclohexyl acetate | 153.32 |
| tetrabutyl urea | 95.61 |
| diisobutyl methanol | 95.03 |
| 2-phenylethanol | 194.61 |
| styrene | 122.89 |
| dioctyl adipate | 119.82 |
| dimethyl sulfate | 332.67 |
| ethyl butyrate | 229.28 |
| methyl lactate | 230.8 |
| butyl lactate | 132.87 |
| diethyl carbonate | 158.65 |
| propanediol butyl ether | 239.61 |
| triethyl orthoformate | 141.54 |
| p-tert-butyltoluene | 62.76 |
| methyl 4-tert-butylbenzoate | 160.46 |
| morpholine | 1258.25 |
| tert-butylamine | 410.24 |
| n-dodecanol | 59.06 |
| dimethoxymethane | 727.93 |
| ethylene carbonate | 368.68 |
| cyrene | 204.19 |
| 2-ethoxyethyl acetate | 254.52 |
| 2-ethylhexyl acetate | 216.35 |
| 1,2,4-trichlorobenzene | 253.83 |
| 4-methylpyridine | 415.82 |
| dibutyl ether | 150.09 |
| 2,6-dimethyl-4-heptanol | 95.03 |
| DEF | 478.06 |
| dimethyl isosorbide | 309.07 |
| tetrachloroethylene | 545.56 |
| eugenol | 170.16 |
| triacetin | 208.37 |
| span 80 | 168.96 |
| 1,4-butanediol | 200.6 |
| 1,1-dichloroethane | 740.41 |
| 2-methyl-1-pentanol | 251.5 |
| methyl formate | 616.46 |
| 2-methyl-1-butanol | 345.96 |
| n-decane | 15.91 |
| butyronitrile | 448.24 |
| 3,7-dimethyl-1-octanol | 119.52 |
| 1-chlorooctane | 76.39 |
| 1-chlorotetradecane | 30.96 |
| n-nonane | 15.53 |
| undecane | 12.22 |
| tert-butylcyclohexane | 28.86 |
| cyclooctane | 19.0 |
| cyclopentanol | 393.27 |
| tetrahydropyran | 1012.35 |
| tert-amyl methyl ether | 335.77 |
| 2,5,8-trioxanonane | 362.92 |
| 1-hexene | 128.78 |
| 2-isopropoxyethanol | 359.26 |
| 2,2,2-trifluoroethanol | 235.46 |
| methyl butyrate | 415.27 |
Scent© AI

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CAS NUMBER
97-53-0
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FAMILIES
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BRAND
Scent.vn
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EVAPORATION RATE
Slow
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Odor impact
Medium est.
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FLASH POINT
110.04 ˚C est.
Olfactory Pyramid
Notes
| Spicy |
| Sweet |
| Phenolic |
| Woody |
| Clove |
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
|
Category 1
Products applied to the lips
|
0.45 % |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
2 % |
|
Category 2
Products applied to the axillae
|
0.14 % |
Category 7B
Leave-on products applied to the hair with some hand contact
|
2 % |
|
Category 3
Products applied to the face/body using fingertips
|
1 % |
Category 8
Products with significant anogenital exposure
|
0.21 % |
|
Category 4
Products related to fine fragrance
|
2.5 % |
Category 9
Products with body and hand exposure, primarily rinse off
|
4.9 % |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
0.64 % |
Category 10A
Household care products with mostly hand contact
|
4 % |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
0.64 % |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
18 % |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
0.64 % |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
0.21 % |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
0.21 % |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
0.21 % |
|
Category 6
Products with oral and lip exposure
|
1.5 % |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |
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Certificates of Quality
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Certificate of Analysis (COA)
Provides information on the physical and chemical properties of the product.Download -
IFRA Certificate of Conformity
Sets safety standards and guidelines for the product in manufacturing.Download -
Safety Data Sheet (SDS)
Provides important safety guidelines for transporting, storing, and using the product.Download