Camphenilone

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  • Identifiers

    CAS number
    13211-15-9

    Molecular formula
    C9H14O

    SMILES
    CC1(C2CCC(C2)C1=O)C

    Safety labels

    Irritant
    Irritant

    Retention indicies (RI)

    • DB5: 1083.0

  • Odor profile

    Camphoreous 72.59%
    Herbal 67.15%
    Mint 66.12%
    Woody 58.96%
    Fresh 50.07%
    Cooling 49.62%
    Pine 44.35%
    Earthy 39.93%
    Tobacco 34.41%
    Terpenic 32.03%

    Scent© AI

  • Properties

    XLogP3-AA
    1.9

    Molecular weight
    138.21 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Fast

    Boiling point est.
    199°C

    Flash point est.
    49.99 ˚C

  • Synonyms

    • 3,3-Dimethylbicyclo[2.2.1]heptan-2-one
    • 13211-15-9
    • Camphenilone
    • Bicyclo[2.2.1]heptan-2-one, 3,3-dimethyl-
    • 2-Norbornanone, 3,3-dimethyl-
    • 3,3-Dimethylnorcamphor
    • EINECS 236-179-9
    • 3,3-Dimethylbicyclo(2.2.1)heptan-2-one
    • CHEBI:132827
    • DTXSID60927542
    • Bicyclo(2.2.1)heptan-2-one, 3,3-dimethyl-
    • Camphenilon
    • 6069-71-2
    • NSC176900
    • 3,3-Dimethyl-bicyclo[2.2.1]heptan-2-one
    • 3,3-Dimethylnorbornan-2-on
    • SCHEMBL14721197
    • DTXCID20912833
    • NAA21115
    • AKOS004120829
    • NSC-176900
    • CS-0265213
    • NS00051776
    • EN300-96983
    • (1S,4R)-3,3-dimethylbicyclo[2.2.1]heptan-2-one
    • Q67879755
    • 236-179-9
    • 52363-25-4

  • Applications

    Camphenilone (CAS 13211-15-9) is a bicyclic monoterpene ketone with a camphoraceous, fresh, pine-woody odor, used mainly as a fragrance ingredient to add camphor/pine facets and improve diffusion and tenacity in fine fragrances, soaps, detergents, personal-care products, and air care; it also serves as an intermediate in aroma chemistry for building related terpenoid alcohols, esters, lactones, and ketones, as a flavor modifier imparting minty/resinous nuances at trace levels where permitted, and as a versatile scaffold in organic synthesis and pharma/agro research due to its rigid hydrophobic bicyclic framework; additionally, it is employed as a reference/analytical standard for QC; implementation should follow safety and regulatory requirements (e.g., IFRA, REACH and local flavor/fragrance rules), with impurity control, very low typical use levels (ppm range), and standard handling for volatile ketones.

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 771.42
    methanol 1239.91
    isopropanol 549.26
    water 52.24
    ethyl acetate 839.94
    n-propanol 542.77
    acetone 875.88
    n-butanol 512.77
    acetonitrile 927.41
    DMF 768.71
    toluene 472.5
    isobutanol 409.61
    1,4-dioxane 1250.25
    methyl acetate 733.79
    THF 1128.03
    2-butanone 575.5
    n-pentanol 300.6
    sec-butanol 349.36
    n-hexane 53.02
    ethylene glycol 242.97
    NMP 417.82
    cyclohexane 77.26
    DMSO 408.96
    n-butyl acetate 522.23
    n-octanol 215.26
    chloroform 2455.44
    n-propyl acetate 451.95
    acetic acid 959.17
    dichloromethane 1723.64
    cyclohexanone 632.26
    propylene glycol 212.34
    isopropyl acetate 689.39
    DMAc 504.79
    2-ethoxyethanol 584.96
    isopentanol 513.52
    n-heptane 43.2
    ethyl formate 628.86
    1,2-dichloroethane 842.17
    n-hexanol 373.29
    2-methoxyethanol 970.0
    isobutyl acetate 348.13
    tetrachloromethane 608.35
    n-pentyl acetate 353.3
    transcutol 2015.27
    n-heptanol 257.46
    ethylbenzene 266.4
    MIBK 501.55
    2-propoxyethanol 765.7
    tert-butanol 591.65
    MTBE 558.8
    2-butoxyethanol 550.35
    propionic acid 532.97
    o-xylene 320.89
    formic acid 671.15
    diethyl ether 578.69
    m-xylene 402.38
    p-xylene 431.97
    chlorobenzene 661.02
    dimethyl carbonate 364.74
    n-octane 24.4
    formamide 936.47
    cyclopentanone 790.75
    2-pentanone 539.46
    anisole 595.25
    cyclopentyl methyl ether 451.15
    gamma-butyrolactone 969.61
    1-methoxy-2-propanol 645.61
    pyridine 920.4
    3-pentanone 360.13
    furfural 1083.61
    n-dodecane 19.51
    diethylene glycol 607.19
    diisopropyl ether 289.57
    tert-amyl alcohol 382.35
    acetylacetone 820.03
    n-hexadecane 22.5
    acetophenone 471.19
    methyl propionate 525.2
    isopentyl acetate 523.66
    trichloroethylene 1802.02
    n-nonanol 200.96
    cyclohexanol 328.25
    benzyl alcohol 399.64
    2-ethylhexanol 214.13
    isooctanol 229.5
    dipropyl ether 259.75
    1,2-dichlorobenzene 643.79
    ethyl lactate 212.84
    propylene carbonate 674.03
    n-methylformamide 698.93
    2-pentanol 333.83
    n-pentane 66.9
    1-propoxy-2-propanol 499.82
    1-methoxy-2-propyl acetate 630.91
    2-(2-methoxypropoxy) propanol 445.07
    mesitylene 301.94
    ε-caprolactone 614.64
    p-cymene 184.88
    epichlorohydrin 1142.89
    1,1,1-trichloroethane 1283.04
    2-aminoethanol 445.01
    morpholine-4-carbaldehyde 836.2
    sulfolane 614.15
    2,2,4-trimethylpentane 48.11
    2-methyltetrahydrofuran 647.26
    n-hexyl acetate 449.55
    isooctane 59.16
    2-(2-butoxyethoxy)ethanol 608.0
    sec-butyl acetate 365.75
    tert-butyl acetate 687.76
    decalin 61.21
    glycerin 339.68
    diglyme 1163.8
    acrylic acid 534.36
    isopropyl myristate 179.34
    n-butyric acid 769.77
    acetyl acetate 750.74
    di(2-ethylhexyl) phthalate 194.33
    ethyl propionate 401.37
    nitromethane 1445.63
    1,2-diethoxyethane 674.61
    benzonitrile 657.24
    trioctyl phosphate 118.99
    1-bromopropane 441.46
    gamma-valerolactone 1138.92
    n-decanol 136.98
    triethyl phosphate 181.1
    4-methyl-2-pentanol 301.8
    propionitrile 645.61
    vinylene carbonate 759.27
    1,1,2-trichlorotrifluoroethane 790.0
    DMS 462.74
    cumene 221.08
    2-octanol 166.9
    2-hexanone 352.11
    octyl acetate 204.09
    limonene 180.01
    1,2-dimethoxyethane 835.02
    ethyl orthosilicate 192.58
    tributyl phosphate 153.49
    diacetone alcohol 519.17
    N,N-dimethylaniline 370.83
    acrylonitrile 843.93
    aniline 560.47
    1,3-propanediol 622.23
    bromobenzene 651.41
    dibromomethane 1010.25
    1,1,2,2-tetrachloroethane 1209.26
    2-methyl-cyclohexyl acetate 292.73
    tetrabutyl urea 147.09
    diisobutyl methanol 202.47
    2-phenylethanol 459.23
    styrene 320.39
    dioctyl adipate 230.13
    dimethyl sulfate 368.44
    ethyl butyrate 389.21
    methyl lactate 290.33
    butyl lactate 269.61
    diethyl carbonate 297.24
    propanediol butyl ether 378.98
    triethyl orthoformate 293.81
    p-tert-butyltoluene 203.33
    methyl 4-tert-butylbenzoate 431.3
    morpholine 979.83
    tert-butylamine 432.53
    n-dodecanol 98.71
    dimethoxymethane 697.85
    ethylene carbonate 637.43
    cyrene 285.26
    2-ethoxyethyl acetate 584.25
    2-ethylhexyl acetate 360.16
    1,2,4-trichlorobenzene 669.21
    4-methylpyridine 870.57
    dibutyl ether 236.32
    2,6-dimethyl-4-heptanol 202.47
    DEF 440.06
    dimethyl isosorbide 627.33
    tetrachloroethylene 1038.01
    eugenol 414.18
    triacetin 465.41
    span 80 312.12
    1,4-butanediol 217.51
    1,1-dichloroethane 1123.43
    2-methyl-1-pentanol 292.21
    methyl formate 622.24
    2-methyl-1-butanol 370.75
    n-decane 34.98
    butyronitrile 581.28
    3,7-dimethyl-1-octanol 249.14
    1-chlorooctane 135.76
    1-chlorotetradecane 54.99
    n-nonane 31.97
    undecane 24.72
    tert-butylcyclohexane 70.58
    cyclooctane 38.64
    cyclopentanol 337.34
    tetrahydropyran 677.8
    tert-amyl methyl ether 332.53
    2,5,8-trioxanonane 673.1
    1-hexene 165.9
    2-isopropoxyethanol 436.2
    2,2,2-trifluoroethanol 585.27
    methyl butyrate 439.92

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction

Botanical

Name CAS Botanical Proportion
Citronella java (China) 8000-29-1 Cymbopogon winterianus Jowitt., fam. Poaceae (Gramineae) 0.01%
Citronella java (Argentina) 2 8000-29-1 Cymbopogon winterianus Jowitt., fam. Poaceae (Gramineae) 0.01%
Citronella java (S. America) 8000-29-1 Cymbopogon winterianus Jowitt., fam. Poaceae (Gramineae) 0.01%
Citronella ceylon 5 8000-29-1 Cymbopogon nardus (L.) Rendle, fam. Poaceae (Gramineae) 0.07%
Lavandin (France) (Abrialis) 2 8022-15-9 Lavandula x hybrida Rev. (L. x intermedia Emeric ex Loiseleur), Lamiaceae 0.01%
Micromeria carminea (Turkey) Micromeria carminea P.H. Davis (syn.M.cristata), fam. Lamiaceae (Labiatae) 0.11%
Artemisia umbelliformis (Italy) Artemisia umbelliformis Lam., fam. Asteraceae (Compositae) 0.01%
Artemisia campestris (Italy) 1 Artemisia campestris L. ssp. borealis (Pallas), H.M. Hall et Clements 0.01%
Artemisia genipi (Italy) Artemisia genipi Weber, fam. Asteraceae (Compositae) 0.01%
Artemisia petrosa (Italy) Artemisia petrosa Baumg. ssp. eriantha Ten., fam. Asteraceae (Compositae) 0.01%
Artemisia vallesiaca (Italy) Artemisia vallesiaca All., fam. Asteraceae (Compositae) 0.01%
Wormwood (Mugwort) (Italy) 2 8008-93-3 Artemisia absinthium L., fam. Asteraceae (Compositae) 0.01%
Artemisia chamaemelifolia (Italy) Artemisia chamaemelifolia Vill., fam. Asteraceae (Compositae) 0.01%
Artemisia glacialis (Italy) Artemisia glacialis L., fam. Asteraceae (Compositae) 0.01%
Artemisia campestris (Italy) 2 Artemisia campestris L. ssp. campestris, fam. Asteraceae (Compositae) 0.01%
Artemisia alba (Italy) 84775-75-7 Artemisia alba Turra, fam. Asteraceae (Compositae) 0.1%
Artemisia abrotanum (Italy) Artemisia abrotanum L., fam. Asteraceae (Compositae) 0.01%
Annual wormwood (Italy) Artemisia annua L., fam. Asteraceae (Compositae) 0.01%
Artemisia verlotiorum (Italy) Artemisia verlotiorum Lamotte, fam. Asteraceae (Compositae) 0.01%
Armoise (Italy) 8008-93-3 Artemisia vulgaris L., fam. Asteraceae (Compositae) 0.01%