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Green Acetate aka. OTBCHA alt. Verdox Aroma Chemical
CAS# 88-41-5

Woody, Fruity, Herbal, Floral, Green

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Verdox, also widely known by its chemical name ortho-tert-Butylcyclohexyl acetate (OTBCHA), is a synthetic material that plays an essential role in the fragrance industry. Its development is closely linked to the mid-20th-century work of chemists studying alkyl cyclohexyl acetate derivatives in search of stable, cost-effective fruity and woody notes for use in soap and detergent manufacturing. While the para isomer is characterized by a strong patchouli-woody profile, the ortho isomer stands out for its vivid green apple note and was later commercialized by IFF under the name Verdox. In physical form, this material is a clear, colorless liquid with a characteristic fruity-woody scent profile. The odor of Verdox is described as the fresh, crisp quality of green apple, intertwined with nuances of pinewood and a gentle cool freshness.

Description

Acting as a top-to-middle note, a modifier, and a blender, Verdox has strong odor intensity and very good diffusion, although its tenacity is only moderate, lasting around 24 to 48 hours on a blotter. In fragrance formulas, it is commonly used to recreate apple and pear notes, helping to brighten and energize floral or woody compositions. Perfumers often combine Verdox with Linalool, Hedione, Galaxolide, Iso E Super, and Allyl Amyl Glycolate to create modern fruity-floral or fougère accords. Because it is a volatile liquid and easy to handle, it is typically used either neat or diluted in DPG.

Applications

In terms of applications, Verdox appears in a wide range of products, from perfumes, scented candles, and leave-on cosmetics to rinse-off products such as shampoos, shower gels, soaps, and fabric softeners. This material is considered very safe and is not subject to strict IFRA toxicity restrictions, allowing flexible usage levels from 1% to 10%, and even up to 20% in specialized accords. Users generally do not need to worry about a high risk of sensitization, phototoxicity, or mandatory ingredient labeling requirements in Europe, provided the material is stored in tightly sealed packaging in a cool, dry place away from light.

Many shampoos on the market with a characteristic green apple scent, as well as commercial perfumes in the floral fruity family, have successfully used this material. According to Perfume and Flavor Chemicals by Steffen Arctander, ortho-tert-Butylcyclohexyl acetate is described as having a powerful fruity odor, strongly reminiscent of apple with woody and camphoraceous undertones. Although Arctander noted its tenacity as moderate to weak, he still rated it very highly for soap applications because of its excellent stability and its ability to blend perfectly with ionone notes and woody materials.

48 total reviews

Technical standards

Physical appearance Transparent liquid Conform
Color Colorless Conform
Specific Gravity @20˚C 0.94 → 0.946 0.943
Refractive Index @20˚C 1.45 → 1.455 0.1453
Acid value (mgKOH/g) ≤ 1.0 Conform
Cis isomer 80% → 88% 85%
Trans isomer 12% → 20% 14.6%
Purity ≥ 98.5% 99.6%

Solubility @25˚C

Solvent Solubility (g/L)
ethanol 430.55
methanol 529.55
isopropanol 530.98
water 1.18
ethyl acetate 447.98
n-propanol 450.32
acetone 545.91
n-butanol 410.03
acetonitrile 496.9
DMF 682.33
toluene 482.22
isobutanol 434.86
1,4-dioxane 1002.5
methyl acetate 447.15
THF 1547.43
2-butanone 493.86
n-pentanol 253.52
sec-butanol 458.01
n-hexane 140.76
ethylene glycol 86.86
NMP 897.57
cyclohexane 315.36
DMSO 440.18
n-butyl acetate 519.15
n-octanol 306.35
chloroform 2333.82
n-propyl acetate 291.92
acetic acid 413.6
dichloromethane 1474.23
cyclohexanone 1112.26
propylene glycol 207.21
isopropyl acetate 334.71
DMAc 561.15
2-ethoxyethanol 209.1
isopentanol 387.88
n-heptane 127.51
ethyl formate 355.1
1,2-dichloroethane 724.8
n-hexanol 642.99
2-methoxyethanol 430.84
isobutyl acetate 261.25
tetrachloromethane 349.88
n-pentyl acetate 315.59
transcutol 814.39
n-heptanol 273.69
ethylbenzene 285.78
MIBK 321.17
2-propoxyethanol 556.92
tert-butanol 699.0
MTBE 528.07
2-butoxyethanol 299.23
propionic acid 417.71
o-xylene 354.91
formic acid 106.64
diethyl ether 378.51
m-xylene 369.95
p-xylene 410.97
chlorobenzene 647.15
dimethyl carbonate 165.65
n-octane 49.62
formamide 117.83
cyclopentanone 1056.21
2-pentanone 414.79
anisole 382.42
cyclopentyl methyl ether 649.23
gamma-butyrolactone 1088.65
1-methoxy-2-propanol 432.02
pyridine 756.83
3-pentanone 335.65
furfural 828.63
n-dodecane 43.35
diethylene glycol 317.0
diisopropyl ether 173.62
tert-amyl alcohol 526.72
acetylacetone 477.62
n-hexadecane 49.94
acetophenone 367.98
methyl propionate 348.0
isopentyl acetate 480.78
trichloroethylene 1454.6
n-nonanol 253.21
cyclohexanol 689.25
benzyl alcohol 308.38
2-ethylhexanol 373.54
isooctanol 221.84
dipropyl ether 324.64
1,2-dichlorobenzene 576.47
ethyl lactate 171.44
propylene carbonate 761.41
n-methylformamide 290.98
2-pentanol 319.93
n-pentane 122.59
1-propoxy-2-propanol 454.83
1-methoxy-2-propyl acetate 452.35
2-(2-methoxypropoxy) propanol 362.6
mesitylene 266.72
ε-caprolactone 902.91
p-cymene 234.73
epichlorohydrin 989.38
1,1,1-trichloroethane 974.18
2-aminoethanol 203.29
morpholine-4-carbaldehyde 732.18
sulfolane 1150.77
2,2,4-trimethylpentane 74.96
2-methyltetrahydrofuran 1016.0
n-hexyl acetate 547.1
isooctane 60.58
2-(2-butoxyethoxy)ethanol 406.28
sec-butyl acetate 235.45
tert-butyl acetate 392.49
decalin 122.57
glycerin 213.87
diglyme 615.78
acrylic acid 326.32
isopropyl myristate 232.66
n-butyric acid 601.11
acetyl acetate 364.38
di(2-ethylhexyl) phthalate 237.25
ethyl propionate 275.86
nitromethane 547.83
1,2-diethoxyethane 345.82
benzonitrile 540.09
trioctyl phosphate 188.04
1-bromopropane 575.65
gamma-valerolactone 1141.64
n-decanol 190.12
triethyl phosphate 186.9
4-methyl-2-pentanol 225.55
propionitrile 486.43
vinylene carbonate 662.72
1,1,2-trichlorotrifluoroethane 610.75
DMS 362.04
cumene 212.73
2-octanol 218.55
2-hexanone 324.33
octyl acetate 290.02
limonene 350.2
1,2-dimethoxyethane 463.91
ethyl orthosilicate 178.64
tributyl phosphate 213.06
diacetone alcohol 407.66
N,N-dimethylaniline 278.54
acrylonitrile 498.55
aniline 456.2
1,3-propanediol 287.87
bromobenzene 758.09
dibromomethane 1112.73
1,1,2,2-tetrachloroethane 1340.56
2-methyl-cyclohexyl acetate 370.63
tetrabutyl urea 255.35
diisobutyl methanol 204.13
2-phenylethanol 415.24
styrene 318.53
dioctyl adipate 320.33
dimethyl sulfate 275.97
ethyl butyrate 344.81
methyl lactate 211.09
butyl lactate 285.22
diethyl carbonate 241.36
propanediol butyl ether 347.93
triethyl orthoformate 247.87
p-tert-butyltoluene 240.69
methyl 4-tert-butylbenzoate 411.36
morpholine 965.13
tert-butylamine 515.1
n-dodecanol 149.31
dimethoxymethane 381.24
ethylene carbonate 567.4
cyrene 352.36
2-ethoxyethyl acetate 350.86
2-ethylhexyl acetate 403.83
1,2,4-trichlorobenzene 670.84
4-methylpyridine 839.17
dibutyl ether 293.87
2,6-dimethyl-4-heptanol 204.13
DEF 407.11
dimethyl isosorbide 675.36
tetrachloroethylene 774.97
eugenol 327.52
triacetin 416.29
span 80 417.09
1,4-butanediol 115.93
1,1-dichloroethane 927.43
2-methyl-1-pentanol 259.43
methyl formate 271.81
2-methyl-1-butanol 364.19
n-decane 69.13
butyronitrile 552.12
3,7-dimethyl-1-octanol 292.52
1-chlorooctane 238.4
1-chlorotetradecane 106.96
n-nonane 70.42
undecane 52.39
tert-butylcyclohexane 108.78
cyclooctane 101.98
cyclopentanol 692.75
tetrahydropyran 1058.31
tert-amyl methyl ether 362.27
2,5,8-trioxanonane 468.39
1-hexene 322.5
2-isopropoxyethanol 196.43
2,2,2-trifluoroethanol 161.27
methyl butyrate 360.74

Scent© AI

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  • CAS NUMBER

    88-41-5

  • FAMILIES

    Fruity

  • BRAND

    Scent.vn

  • EVAPORATION RATE

    Moderate

  • Odor impact

    High est.

  • FLASH POINT

    99.13 ˚C est.

heart
Woody
Fruity
Herbal
Floral
Green
Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
No restriction
Category 2
Products applied to the axillae
No restriction Category 7B
Leave-on products applied to the hair with some hand contact
No restriction
Category 3
Products applied to the face/body using fingertips
No restriction Category 8
Products with significant anogenital exposure
No restriction
Category 4
Products related to fine fragrance
No restriction Category 9
Products with body and hand exposure, primarily rinse off
No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
No restriction Category 10A
Household care products with mostly hand contact
No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
No restriction
Category 5D
Baby Creams, baby Oils and baby talc
No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
No restriction
Category 6
Products with oral and lip exposure
No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
No restriction
  • All orders will be processed within 1-2 business days from the time the order is confirmed.
  • Free shipping is available for orders valued at $500 or more.
  • Delivery time is 1-3 business days for local areas, 3-7 days for suburban and nationwide deliveries, and 1-4 weeks for international orders.
  • You have 30 days from the date of receipt to initiate the return process.
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  • Certificate of Analysis (COA)

    Provides information on the physical and chemical properties of the product.
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  • IFRA Certificate of Conformity

    Sets safety standards and guidelines for the product in manufacturing.
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  • Safety Data Sheet (SDS)

    Provides important safety guidelines for transporting, storing, and using the product.
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