Phenyl Acetaldehyde Dimethyl Acetal PADMA Aroma Chemical
CAS# 101-48-4
Green, Floral, Rose, Hyacinth, Earthy
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Phenyl Acetaldehyde Dimethyl Acetal, commonly known by the abbreviation PADMA or the trade name Viridine, is a synthetic ingredient that plays an important role in the fragrance industry. It was introduced in the mid-20th century to address the instability of Phenylacetaldehyde, a material with a very beautiful odor but a strong tendency to polymerize. By converting it into its acetal form, chemists created a material that preserves its vivid green note while remaining highly stable in alkaline environments. In its physical form, PADMA is a clear, colorless liquid belonging to the green fragrance family, with a floral-green character.
Description
Its scent is sharp and fresh, reminiscent of rose leaves and hyacinth, interwoven with earthy and mushroom-like nuances. Functioning from the top note to the middle note range and serving as an effective modifier, this ingredient has strong odor impact, very good diffusion, and moderate substantivity, lasting from 24 to 48 hours on a blotter. In fragrance compositions, it helps build hyacinth, lily-of-the-valley, and rose-leaf notes, while also enhancing freshness and bringing a more natural realism to the overall accord. Perfumers often combine it with Phenyl Ethyl Alcohol, Geraniol, Citronellol, Galbanum, and Benzyl Acetate to create lush green floral accords. Because of its strong odor intensity, it is often diluted in DPG to make dosage control easier.
Applications
In terms of applications, this ingredient is widely used in fine fragrance, scented candles, leave-on cosmetics, rinse-off products, and is especially favored in soap and laundry detergents because of its excellent stability. Unlike the parent aldehyde, PADMA is considered much safer and is not subject to strict IFRA restrictions for toxicity, allowing flexible use typically at levels ranging from 0.1% to 5%. Users generally do not need to be concerned about severe allergy risk, phototoxicity, or mandatory allergen labeling requirements in Europe. However, storage still requires care: it should be kept tightly sealed, stored in a cool, dry place, and especially protected from highly acidic environments to prevent reverse hydrolysis. Many green floral perfumes and hyacinth-themed bath soap products make use of this material. Its value was ultimately affirmed in Perfume and Flavor Chemicals, where expert Steffen Arctander described Phenylacetaldehyde dimethyl acetal as having a powerful green odor with earthy and sweet floral undertones reminiscent of rose leaves. He emphasized its superior stability in soap compared with phenylacetaldehyde and also noted its broad usefulness in creating green notes for floral fragrance bases.
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Technical standards
Technical standards
Solubility @25˚C
Solubility @25˚C
| Solvent | Solubility (g/L) |
|---|---|
| ethanol | 727.04 |
| methanol | 687.96 |
| isopropanol | 510.81 |
| water | 6.16 |
| ethyl acetate | 579.38 |
| n-propanol | 575.34 |
| acetone | 326.97 |
| n-butanol | 474.7 |
| acetonitrile | 650.97 |
| DMF | 440.86 |
| toluene | 278.32 |
| isobutanol | 394.64 |
| 1,4-dioxane | 1326.98 |
| methyl acetate | 485.13 |
| THF | 689.69 |
| 2-butanone | 341.16 |
| n-pentanol | 313.52 |
| sec-butanol | 442.73 |
| n-hexane | 61.61 |
| ethylene glycol | 233.38 |
| NMP | 287.46 |
| cyclohexane | 193.87 |
| DMSO | 540.26 |
| n-butyl acetate | 242.98 |
| n-octanol | 111.48 |
| chloroform | 3048.91 |
| n-propyl acetate | 268.45 |
| acetic acid | 860.91 |
| dichloromethane | 2367.81 |
| cyclohexanone | 496.09 |
| propylene glycol | 274.6 |
| isopropyl acetate | 217.69 |
| DMAc | 379.45 |
| 2-ethoxyethanol | 568.07 |
| isopentanol | 326.82 |
| n-heptane | 66.66 |
| ethyl formate | 404.84 |
| 1,2-dichloroethane | 1052.51 |
| n-hexanol | 307.33 |
| 2-methoxyethanol | 783.97 |
| isobutyl acetate | 159.55 |
| tetrachloromethane | 427.36 |
| n-pentyl acetate | 126.76 |
| transcutol | 787.98 |
| n-heptanol | 130.25 |
| ethylbenzene | 141.73 |
| MIBK | 139.95 |
| 2-propoxyethanol | 405.95 |
| tert-butanol | 638.53 |
| MTBE | 378.69 |
| 2-butoxyethanol | 225.38 |
| propionic acid | 526.59 |
| o-xylene | 174.79 |
| formic acid | 284.22 |
| diethyl ether | 567.69 |
| m-xylene | 155.12 |
| p-xylene | 182.42 |
| chlorobenzene | 402.99 |
| dimethyl carbonate | 132.96 |
| n-octane | 24.37 |
| formamide | 353.73 |
| cyclopentanone | 391.54 |
| 2-pentanone | 240.52 |
| anisole | 280.39 |
| cyclopentyl methyl ether | 334.65 |
| gamma-butyrolactone | 567.91 |
| 1-methoxy-2-propanol | 442.72 |
| pyridine | 806.01 |
| 3-pentanone | 231.96 |
| furfural | 628.95 |
| n-dodecane | 19.11 |
| diethylene glycol | 362.06 |
| diisopropyl ether | 108.11 |
| tert-amyl alcohol | 427.18 |
| acetylacetone | 247.48 |
| n-hexadecane | 21.23 |
| acetophenone | 224.13 |
| methyl propionate | 329.96 |
| isopentyl acetate | 197.76 |
| trichloroethylene | 1852.02 |
| n-nonanol | 99.79 |
| cyclohexanol | 445.97 |
| benzyl alcohol | 261.51 |
| 2-ethylhexanol | 173.9 |
| isooctanol | 97.89 |
| dipropyl ether | 241.08 |
| 1,2-dichlorobenzene | 343.55 |
| ethyl lactate | 149.77 |
| propylene carbonate | 375.92 |
| n-methylformamide | 324.67 |
| 2-pentanol | 273.61 |
| n-pentane | 77.91 |
| 1-propoxy-2-propanol | 264.04 |
| 1-methoxy-2-propyl acetate | 203.03 |
| 2-(2-methoxypropoxy) propanol | 180.75 |
| mesitylene | 98.62 |
| ε-caprolactone | 453.61 |
| p-cymene | 87.1 |
| epichlorohydrin | 789.98 |
| 1,1,1-trichloroethane | 1047.22 |
| 2-aminoethanol | 414.17 |
| morpholine-4-carbaldehyde | 498.38 |
| sulfolane | 500.54 |
| 2,2,4-trimethylpentane | 37.22 |
| 2-methyltetrahydrofuran | 568.84 |
| n-hexyl acetate | 169.01 |
| isooctane | 24.02 |
| 2-(2-butoxyethoxy)ethanol | 246.88 |
| sec-butyl acetate | 164.27 |
| tert-butyl acetate | 202.89 |
| decalin | 59.47 |
| glycerin | 330.79 |
| diglyme | 529.92 |
| acrylic acid | 453.8 |
| isopropyl myristate | 76.2 |
| n-butyric acid | 588.63 |
| acetyl acetate | 317.1 |
| di(2-ethylhexyl) phthalate | 79.83 |
| ethyl propionate | 231.14 |
| nitromethane | 803.23 |
| 1,2-diethoxyethane | 301.45 |
| benzonitrile | 301.41 |
| trioctyl phosphate | 56.46 |
| 1-bromopropane | 612.23 |
| gamma-valerolactone | 547.15 |
| n-decanol | 73.99 |
| triethyl phosphate | 122.19 |
| 4-methyl-2-pentanol | 123.21 |
| propionitrile | 502.13 |
| vinylene carbonate | 416.78 |
| 1,1,2-trichlorotrifluoroethane | 726.93 |
| DMS | 159.26 |
| cumene | 95.38 |
| 2-octanol | 77.5 |
| 2-hexanone | 197.54 |
| octyl acetate | 93.1 |
| limonene | 133.55 |
| 1,2-dimethoxyethane | 681.24 |
| ethyl orthosilicate | 123.34 |
| tributyl phosphate | 71.37 |
| diacetone alcohol | 217.39 |
| N,N-dimethylaniline | 180.66 |
| acrylonitrile | 543.7 |
| aniline | 405.69 |
| 1,3-propanediol | 490.37 |
| bromobenzene | 427.33 |
| dibromomethane | 1487.76 |
| 1,1,2,2-tetrachloroethane | 1520.51 |
| 2-methyl-cyclohexyl acetate | 162.31 |
| tetrabutyl urea | 86.7 |
| diisobutyl methanol | 101.95 |
| 2-phenylethanol | 195.77 |
| styrene | 193.99 |
| dioctyl adipate | 115.67 |
| dimethyl sulfate | 188.42 |
| ethyl butyrate | 230.71 |
| methyl lactate | 175.34 |
| butyl lactate | 112.87 |
| diethyl carbonate | 185.84 |
| propanediol butyl ether | 158.75 |
| triethyl orthoformate | 173.7 |
| p-tert-butyltoluene | 84.02 |
| methyl 4-tert-butylbenzoate | 169.46 |
| morpholine | 1281.51 |
| tert-butylamine | 451.22 |
| n-dodecanol | 60.51 |
| dimethoxymethane | 338.28 |
| ethylene carbonate | 360.31 |
| cyrene | 197.29 |
| 2-ethoxyethyl acetate | 183.42 |
| 2-ethylhexyl acetate | 156.58 |
| 1,2,4-trichlorobenzene | 401.43 |
| 4-methylpyridine | 543.57 |
| dibutyl ether | 155.48 |
| 2,6-dimethyl-4-heptanol | 101.95 |
| DEF | 373.47 |
| dimethyl isosorbide | 276.56 |
| tetrachloroethylene | 1029.14 |
| eugenol | 178.78 |
| triacetin | 195.05 |
| span 80 | 166.95 |
| 1,4-butanediol | 212.33 |
| 1,1-dichloroethane | 1134.99 |
| 2-methyl-1-pentanol | 231.96 |
| methyl formate | 276.87 |
| 2-methyl-1-butanol | 342.8 |
| n-decane | 30.5 |
| butyronitrile | 477.35 |
| 3,7-dimethyl-1-octanol | 103.8 |
| 1-chlorooctane | 99.15 |
| 1-chlorotetradecane | 42.86 |
| n-nonane | 30.91 |
| undecane | 23.09 |
| tert-butylcyclohexane | 49.27 |
| cyclooctane | 52.95 |
| cyclopentanol | 364.15 |
| tetrahydropyran | 967.77 |
| tert-amyl methyl ether | 252.38 |
| 2,5,8-trioxanonane | 346.21 |
| 1-hexene | 197.05 |
| 2-isopropoxyethanol | 322.94 |
| 2,2,2-trifluoroethanol | 308.64 |
| methyl butyrate | 323.53 |
Scent© AI

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CAS NUMBER
101-48-4
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FAMILIES
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BRAND
Scent.vn
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EVAPORATION RATE
Moderate
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Odor impact
Medium est.
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FLASH POINT
83.51 ˚C est.
Olfactory Pyramid
Notes
| Green |
| Floral |
| Rose |
| Hyacinth |
| Earthy |
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
|
Category 1
Products applied to the lips
|
No restriction |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
No restriction |
|
Category 2
Products applied to the axillae
|
No restriction |
Category 7B
Leave-on products applied to the hair with some hand contact
|
No restriction |
|
Category 3
Products applied to the face/body using fingertips
|
No restriction |
Category 8
Products with significant anogenital exposure
|
No restriction |
|
Category 4
Products related to fine fragrance
|
No restriction |
Category 9
Products with body and hand exposure, primarily rinse off
|
No restriction |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
No restriction |
Category 10A
Household care products with mostly hand contact
|
No restriction |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
No restriction |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
No restriction |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
No restriction |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
No restriction |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
No restriction |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
No restriction |
|
Category 6
Products with oral and lip exposure
|
No restriction |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |
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Certificates of Quality
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Certificate of Analysis (COA)
Provides information on the physical and chemical properties of the product.Download -
IFRA Certificate of Conformity
Sets safety standards and guidelines for the product in manufacturing.Download -
Safety Data Sheet (SDS)
Provides important safety guidelines for transporting, storing, and using the product.Download