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Phenethyl Acetate a.k.a Phenyl Ethyl Acetate Aroma Chemical
CAS# 103-45-7

Floral, Sweet, Fruity, Rose, Balsamic

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Among the countless essences that shape the fragrant world of blending artistry, Phenethyl Acetate always shines like a radiant crystal-celebrated under elegant names such as 2-Phenylethyl Acetate, Phenylethyl Acetate, or Benzyl Carbinyl Acetate. Appearing as a perfectly colorless, transparent liquid, this material carries both the magic of nature and the triumph of science. In nature, it threads through the essential oils of countless flowers and juicy fruits, found most abundantly in rose, jasmine, hyacinth, apple, banana, and sweet raspberry. Yet to meet the massive needs of modern industry, it is produced mainly by chemical synthesis, typically via esterification of Phenethyl Alcohol with Acetic Anhydride, ensuring reliable supply at the most stable cost. History records Phenethyl Acetate as one of the long-famous classical esters in organic chemistry and perfumery. The discovery of this molecule as a naturally occurring constituent in rose oil helped inspire scientists to synthesize it-opening a new era in which the scent of this “queen of flowers” could be recreated far more economically, without relying entirely on precious drops of the original essential oil.

Description

Belonging to the floral–fruity family and carrying a pronounced rose-and-honey aura, Phenethyl Acetate excels as a heart note and a remarkably skillful modifier. Its scent unfolds with an unusually gentle sweetness and warmth, painting the impression of dried velvet rose petals touched by honeyed nectar, alongside a hint of juicy raspberry or peach. Compared with Phenethyl Alcohol-a cornerstone material for rose notes-this ester often feels greener and more leafy, noticeably sweeter, and far less sharp or rough around the edges. With medium intensity and moderate diffusion, its aroma typically lingers on a blotter from a few hours to roughly a day. Even so, it is a crucial puzzle piece for completing rose and jasmine accords, while also lending berry notes (strawberry, raspberry) an irresistibly fruity sweetness. Thanks to its excellent ability to thicken and “round out” a composition, it brings a warm, natural, lively body to many floral themes. In perfumery craft, the classic pairing of Phenethyl Acetate with Phenethyl Alcohol, Citronellol, and Geraniol can weave a complete rose-where the honeyed sweetness of the flower’s heart is made to glow. Beyond that, combined with Phenylacetaldehyde, it can revive a proud hyacinth effect; and when partnered with other esters, it can cleverly transform into crisp apple or plump peach nuances. Owing to its excellent stability as a liquid, artisans often use it neat (undiluted); it dissolves easily in alcohol and common solvents such as DEP or DPG.

Applications

Because of these qualities, Phenethyl Acetate is widely used across floral perfumes, especially those centered on rose and white flowers. Its influence reaches iconic creations such as Jean Patou’s classic Joy, where rose and jasmine are pushed to a peak by honeyed sweetness, or the bright modern rose of Chloé Eau de Parfum. It is also a standout in cosmetics and personal care-bar soaps, shower gels, body creams-thanks to its very high chemical stability, resisting off-odors and discoloration that many temperamental materials can cause. In the food industry, it helps build appealing fruity and honey-like flavors for countless candies, baked goods, and beverages. Another valuable advantage: Phenethyl Acetate is generally recognized as safe, tends to be low-irritancy, and is not assigned a specific IFRA maximum concentration for toxicity or allergy concerns. Even so, manufacturers must still follow strict purity standards to remove unwanted trace impurities. Depending on creative intent, a perfumer may use anywhere from a few percent to above 10% in a fragrance compound, while storing it confidently in sealed containers in a cool, dry place-without the fussy requirements often needed for aldehydes or citrus oils.

Finally, Steffen Arctander summarized it with particular finesse in entry No. 2515 (Volume II) of his 1969 work. Under the name Phenylethyl Acetate, he described an intensely sweet odor with fruity, rose, and honey facets and moderate tenacity. In his perception, it is somewhat greener and more leafy than the Alcohol. He emphasized its wide use in perfume formulas as an ideal sweetener and modifier for rose, violet, Keora, primrose (Cyclamen), hyacinth, magnolia, and even honey bases. Notably, he asserted it is preferred over the Alcohol in soap perfumery thanks to superior stability and much lower water solubility.

56 total reviews

Technical standards

Physical appearance Transparent liquid Conform
Color Colorless Conform
Specific Gravity @20˚C 1.03 → 1.034 1.0333
Refractive Index @20˚C 1.496 → 1.502 1.4972
Purity ≥ 98.0% 99.7%

Solubility @25˚C

Solvent Solubility (g/L)
ethanol 403.3
methanol 528.46
isopropanol 214.84
water 3.44
ethyl acetate 275.87
n-propanol 244.06
acetone 345.04
n-butanol 176.51
acetonitrile 312.52
DMF 771.92
toluene 90.97
isobutanol 136.15
1,4-dioxane 779.64
methyl acetate 282.65
THF 440.51
2-butanone 239.79
n-pentanol 140.71
sec-butanol 159.32
n-hexane 10.79
ethylene glycol 157.16
NMP 455.73
cyclohexane 13.84
DMSO 926.26
n-butyl acetate 113.97
n-octanol 34.37
chloroform 776.1
n-propyl acetate 118.15
acetic acid 471.69
dichloromethane 641.65
cyclohexanone 278.85
propylene glycol 183.28
isopropyl acetate 122.63
DMAc 800.22
2-ethoxyethanol 355.34
isopentanol 130.58
n-heptane 5.37
ethyl formate 128.58
1,2-dichloroethane 395.65
n-hexanol 92.33
2-methoxyethanol 555.88
isobutyl acetate 76.47
tetrachloromethane 47.93
n-pentyl acetate 50.01
transcutol 1333.68
n-heptanol 30.83
ethylbenzene 45.55
MIBK 94.98
2-propoxyethanol 229.42
tert-butanol 236.96
MTBE 162.16
2-butoxyethanol 95.75
propionic acid 259.54
o-xylene 62.67
formic acid 271.89
diethyl ether 250.72
m-xylene 56.09
p-xylene 58.96
chlorobenzene 152.82
dimethyl carbonate 115.72
n-octane 2.08
formamide 429.39
cyclopentanone 319.4
2-pentanone 154.39
anisole 182.76
cyclopentyl methyl ether 180.9
gamma-butyrolactone 407.8
1-methoxy-2-propanol 311.89
pyridine 433.98
3-pentanone 154.77
furfural 404.92
n-dodecane 2.33
diethylene glycol 263.44
diisopropyl ether 44.85
tert-amyl alcohol 177.24
acetylacetone 243.66
n-hexadecane 2.69
acetophenone 144.77
methyl propionate 226.57
isopentyl acetate 109.27
trichloroethylene 764.48
n-nonanol 32.89
cyclohexanol 132.85
benzyl alcohol 139.03
2-ethylhexanol 51.54
isooctanol 26.88
dipropyl ether 74.13
1,2-dichlorobenzene 148.94
ethyl lactate 75.25
propylene carbonate 185.63
n-methylformamide 334.27
2-pentanol 86.43
n-pentane 6.95
1-propoxy-2-propanol 137.78
1-methoxy-2-propyl acetate 163.33
2-(2-methoxypropoxy) propanol 171.56
mesitylene 32.63
ε-caprolactone 249.23
p-cymene 27.21
epichlorohydrin 529.15
1,1,1-trichloroethane 239.67
2-aminoethanol 259.39
morpholine-4-carbaldehyde 588.57
sulfolane 497.17
2,2,4-trimethylpentane 6.65
2-methyltetrahydrofuran 301.66
n-hexyl acetate 87.2
isooctane 4.15
2-(2-butoxyethoxy)ethanol 237.88
sec-butyl acetate 83.02
tert-butyl acetate 147.0
decalin 12.18
glycerin 266.87
diglyme 468.43
acrylic acid 245.53
isopropyl myristate 36.99
n-butyric acid 233.42
acetyl acetate 166.07
di(2-ethylhexyl) phthalate 49.21
ethyl propionate 117.1
nitromethane 730.94
1,2-diethoxyethane 247.0
benzonitrile 145.93
trioctyl phosphate 25.8
1-bromopropane 153.61
gamma-valerolactone 500.12
n-decanol 24.98
triethyl phosphate 64.19
4-methyl-2-pentanol 50.27
propionitrile 187.32
vinylene carbonate 194.3
1,1,2-trichlorotrifluoroethane 407.38
DMS 149.89
cumene 33.57
2-octanol 19.48
2-hexanone 114.48
octyl acetate 44.84
limonene 40.43
1,2-dimethoxyethane 474.68
ethyl orthosilicate 61.9
tributyl phosphate 44.97
diacetone alcohol 174.6
N,N-dimethylaniline 115.79
acrylonitrile 253.11
aniline 185.85
1,3-propanediol 273.06
bromobenzene 152.2
dibromomethane 349.57
1,1,2,2-tetrachloroethane 624.1
2-methyl-cyclohexyl acetate 85.55
tetrabutyl urea 58.78
diisobutyl methanol 33.49
2-phenylethanol 96.43
styrene 71.49
dioctyl adipate 75.38
dimethyl sulfate 217.53
ethyl butyrate 95.25
methyl lactate 122.53
butyl lactate 61.92
diethyl carbonate 80.22
propanediol butyl ether 119.93
triethyl orthoformate 81.88
p-tert-butyltoluene 26.73
methyl 4-tert-butylbenzoate 104.43
morpholine 800.03
tert-butylamine 121.94
n-dodecanol 19.12
dimethoxymethane 357.15
ethylene carbonate 162.16
cyrene 153.39
2-ethoxyethyl acetate 126.34
2-ethylhexyl acetate 87.75
1,2,4-trichlorobenzene 195.44
4-methylpyridine 303.18
dibutyl ether 65.72
2,6-dimethyl-4-heptanol 33.49
DEF 278.51
dimethyl isosorbide 250.91
tetrachloroethylene 359.45
eugenol 114.6
triacetin 153.45
span 80 114.37
1,4-butanediol 109.47
1,1-dichloroethane 311.1
2-methyl-1-pentanol 113.18
methyl formate 193.95
2-methyl-1-butanol 128.97
n-decane 3.67
butyronitrile 155.52
3,7-dimethyl-1-octanol 44.85
1-chlorooctane 21.97
1-chlorotetradecane 10.02
n-nonane 3.29
undecane 2.84
tert-butylcyclohexane 11.36
cyclooctane 4.11
cyclopentanol 127.06
tetrahydropyran 378.2
tert-amyl methyl ether 125.76
2,5,8-trioxanonane 356.98
1-hexene 53.85
2-isopropoxyethanol 179.08
2,2,2-trifluoroethanol 142.32
methyl butyrate 145.06

Scent© AI

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  • CAS NUMBER

    103-45-7

  • FAMILIES

    Floral

  • BRAND

    Scent.vn

  • EVAPORATION RATE

    Moderately slow

  • Odor impact

    Medium est.

  • FLASH POINT

    380.5 ˚C est.

heart
Floral
Sweet
Fruity
Rose
Balsamic
Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
No restriction
Category 2
Products applied to the axillae
No restriction Category 7B
Leave-on products applied to the hair with some hand contact
No restriction
Category 3
Products applied to the face/body using fingertips
No restriction Category 8
Products with significant anogenital exposure
No restriction
Category 4
Products related to fine fragrance
No restriction Category 9
Products with body and hand exposure, primarily rinse off
No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
No restriction Category 10A
Household care products with mostly hand contact
No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
No restriction
Category 5D
Baby Creams, baby Oils and baby talc
No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
No restriction
Category 6
Products with oral and lip exposure
No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
No restriction
  • All orders will be processed within 1-2 business days from the time the order is confirmed.
  • Free shipping is available for orders valued at $200 or more.
  • Delivery time is 1-3 business days for local areas, 3-7 days for suburban and nationwide deliveries, and 1-4 weeks for international orders.
  • You have 30 days from the date of receipt to initiate the return process.
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  • Certificate of Analysis (COA)

    Provides information on the physical and chemical properties of the product.
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  • IFRA Certificate of Conformity

    Sets safety standards and guidelines for the product in manufacturing.
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  • Safety Data Sheet (SDS)

    Provides important safety guidelines for transporting, storing, and using the product.
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