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Florhydral Aroma Chemical
CAS# 125109-85-5

Green, Floral, Fresh, Aldehydic, Leafy

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Florhydral is Givaudan’s proprietary trade name for a floral aldehyde synthesized in the laboratory. Chemically, this material is known as 3-(3-isopropylphenyl)butanal. Florhydral emerged from Givaudan chemists’ efforts to find a new muguet (lily-of-the-valley) note that would be fresher, more powerful, and distinctly greener than classic materials such as hydroxycitronellal or Lilial. It represents a generation of modern floral molecules with extremely high diffusive power. Introduced and commercialized by Givaudan in the second half of the 20th century, this clear liquid-ranging from colorless to very pale yellow-quickly became a valuable tool for perfumers. As safety regulations have tightened around older muguet odorants, Florhydral has offered a way to create an explosive effect of freshness and naturalness in floral bouquets.

Description

Belonging to the floral, green, and marine families, Florhydral performs from the top through the heart of a composition and acts as an excellent booster. Its scent is very strong, sharp, and fresh, with a lily-of-the-valley character-yet not in a powdery/waxy direction; instead, it evokes flowers soaked with dew or just after a rain shower. Its marine facet and ozonic “sea-breeze” character are particularly pronounced, creating a very airy, open space. With very high odor intensity and exceptional diffusion, even a small amount of Florhydral can brighten an entire formula. Although its longevity is only moderate-lasting on a blotter for a few days-it is widely used to bring a fresh, wet effect to floral accords such as rose, jasmine, and peony. It is an important building block for modern muguet and marine styles, and it also functions as a “lift” ingredient that helps a fragrance project farther into the air. When combined with Precyclemone B, it produces a clean-air, sea-breeze, modern aldehydic effect. Paired with Floralozone, the marine and white-floral character is significantly amplified. When blended with Ambroxan, the fragrance retains freshness while gaining long-lasting, elegant diffusion and substantivity. Because the neat material is very strong, perfumers commonly pre-dilute Florhydral to 10% in DPG or ethanol to control dosage more easily and avoid harshness or excessive sharpness.

Applications

Florhydral has broad applications across multiple categories. In fine fragrance, it is especially common in summer and sporty styles, green-floral fragrances, and marine/aquatic compositions. In cosmetics and personal care, it is used in shampoos and shower gels to create a refreshing sensation. In laundry products-detergents and fabric softeners in particular-Florhydral is highly important because it performs strongly on damp fabric, giving a “clean laundry” impression as if clothes have just been sun-dried. From a safety standpoint, Florhydral is restricted by IFRA due to potential skin sensitization. The maximum permitted level in Category 4 fragrances is often below 1%, and users should consult the latest IFRA amendment (such as IFRA 51) for an exact figure. In practice, given its strength, trace to very low levels are usually sufficient to achieve the desired effect; overdosing can increase the risk of irritation. As an aldehyde, Florhydral should be stored in tightly sealed containers in a cool, dry, well-ventilated place, protected from light and high temperatures to limit oxidation. Finally, because it is a modern perfumery material developed and popularized by Givaudan after 1969, it does not appear in Steffen Arctander’s Perfume and Flavor Chemicals.

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Technical standards

Physical appearance Transparent liquid Conform
Color Clear to pale yellow Conform
Specific Gravity @20˚C 0.947 → 0.952 0.9487
Refractive Index @20˚C 1.503 → 1.507 1.5051
Acid value (mgKOH/g) ≤ 5.0 0.3
Purity ≥ 98.0% 98.4%

Solubility @25˚C

Solvent Solubility (g/L)
ethanol 1603.04
methanol 910.89
isopropanol 1346.55
water 0.2
ethyl acetate 1861.48
n-propanol 1500.41
acetone 2484.2
n-butanol 1139.12
acetonitrile 2310.2
DMF 2007.86
toluene 807.01
isobutanol 908.78
1,4-dioxane 2644.89
methyl acetate 1813.8
THF 2509.72
2-butanone 2136.51
n-pentanol 668.24
sec-butanol 910.64
n-hexane 168.85
ethylene glycol 96.85
NMP 1075.73
cyclohexane 235.57
DMSO 1263.53
n-butyl acetate 1268.02
n-octanol 239.29
chloroform 3583.11
n-propyl acetate 957.84
acetic acid 537.9
dichloromethane 3900.36
cyclohexanone 2259.52
propylene glycol 245.01
isopropyl acetate 849.7
DMAc 987.36
2-ethoxyethanol 655.74
isopentanol 763.48
n-heptane 84.29
ethyl formate 1034.02
1,2-dichloroethane 2668.34
n-hexanol 923.16
2-methoxyethanol 1135.22
isobutyl acetate 520.61
tetrachloromethane 472.31
n-pentyl acetate 411.74
transcutol 1717.63
n-heptanol 256.23
ethylbenzene 411.57
MIBK 644.98
2-propoxyethanol 1059.93
tert-butanol 1141.31
MTBE 1256.1
2-butoxyethanol 413.37
propionic acid 747.69
o-xylene 369.96
formic acid 93.28
diethyl ether 1773.52
m-xylene 449.67
p-xylene 464.21
chlorobenzene 986.24
dimethyl carbonate 331.84
n-octane 37.17
formamide 245.32
cyclopentanone 2244.28
2-pentanone 1523.36
anisole 720.62
cyclopentyl methyl ether 1146.61
gamma-butyrolactone 2050.38
1-methoxy-2-propanol 859.52
pyridine 1968.99
3-pentanone 1076.4
furfural 1224.6
n-dodecane 25.02
diethylene glycol 434.35
diisopropyl ether 332.36
tert-amyl alcohol 742.98
acetylacetone 1032.56
n-hexadecane 30.17
acetophenone 540.8
methyl propionate 1202.53
isopentyl acetate 929.49
trichloroethylene 3797.02
n-nonanol 203.18
cyclohexanol 827.2
benzyl alcohol 491.91
2-ethylhexanol 423.9
isooctanol 207.86
dipropyl ether 707.12
1,2-dichlorobenzene 686.99
ethyl lactate 251.86
propylene carbonate 1038.19
n-methylformamide 964.45
2-pentanol 664.25
n-pentane 117.59
1-propoxy-2-propanol 759.82
1-methoxy-2-propyl acetate 805.74
2-(2-methoxypropoxy) propanol 325.27
mesitylene 235.82
ε-caprolactone 1529.11
p-cymene 194.24
epichlorohydrin 2540.03
1,1,1-trichloroethane 2023.19
2-aminoethanol 328.22
morpholine-4-carbaldehyde 1191.26
sulfolane 1463.21
2,2,4-trimethylpentane 48.06
2-methyltetrahydrofuran 2002.82
n-hexyl acetate 552.49
isooctane 44.17
2-(2-butoxyethoxy)ethanol 499.41
sec-butyl acetate 536.15
tert-butyl acetate 676.55
decalin 97.52
glycerin 194.2
diglyme 1042.04
acrylic acid 453.22
isopropyl myristate 198.76
n-butyric acid 1139.5
acetyl acetate 632.17
di(2-ethylhexyl) phthalate 162.62
ethyl propionate 753.49
nitromethane 1311.44
1,2-diethoxyethane 900.05
benzonitrile 785.84
trioctyl phosphate 123.72
1-bromopropane 1567.52
gamma-valerolactone 2159.89
n-decanol 154.73
triethyl phosphate 203.3
4-methyl-2-pentanol 303.19
propionitrile 1687.42
vinylene carbonate 873.84
1,1,2-trichlorotrifluoroethane 906.81
DMS 421.42
cumene 236.12
2-octanol 183.38
2-hexanone 989.41
octyl acetate 255.29
limonene 292.85
1,2-dimethoxyethane 1488.98
ethyl orthosilicate 202.35
tributyl phosphate 162.92
diacetone alcohol 613.21
N,N-dimethylaniline 360.24
acrylonitrile 1608.9
aniline 802.66
1,3-propanediol 536.63
bromobenzene 1006.65
dibromomethane 2578.55
1,1,2,2-tetrachloroethane 2596.76
2-methyl-cyclohexyl acetate 394.65
tetrabutyl urea 199.94
diisobutyl methanol 217.3
2-phenylethanol 479.48
styrene 538.35
dioctyl adipate 273.75
dimethyl sulfate 385.87
ethyl butyrate 726.49
methyl lactate 293.86
butyl lactate 285.95
diethyl carbonate 413.32
propanediol butyl ether 330.99
triethyl orthoformate 372.76
p-tert-butyltoluene 179.42
methyl 4-tert-butylbenzoate 343.93
morpholine 2948.42
tert-butylamine 730.95
n-dodecanol 117.41
dimethoxymethane 1126.36
ethylene carbonate 840.91
cyrene 323.83
2-ethoxyethyl acetate 559.28
2-ethylhexyl acetate 679.05
1,2,4-trichlorobenzene 748.23
4-methylpyridine 1826.28
dibutyl ether 450.19
2,6-dimethyl-4-heptanol 217.3
DEF 1328.7
dimethyl isosorbide 621.19
tetrachloroethylene 1517.02
eugenol 315.66
triacetin 407.73
span 80 294.69
1,4-butanediol 192.73
1,1-dichloroethane 2861.68
2-methyl-1-pentanol 487.23
methyl formate 694.03
2-methyl-1-butanol 709.06
n-decane 48.5
butyronitrile 1618.81
3,7-dimethyl-1-octanol 237.65
1-chlorooctane 231.45
1-chlorotetradecane 80.09
n-nonane 49.72
undecane 33.67
tert-butylcyclohexane 93.21
cyclooctane 64.36
cyclopentanol 822.12
tetrahydropyran 2730.5
tert-amyl methyl ether 652.35
2,5,8-trioxanonane 594.5
1-hexene 774.64
2-isopropoxyethanol 469.83
2,2,2-trifluoroethanol 158.12
methyl butyrate 1157.36

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  • CAS NUMBER

    125109-85-5

  • FAMILIES

    Floral

  • BRAND

    Givaudan

  • EVAPORATION RATE

    Slow

  • Odor impact

    High est.

  • FLASH POINT

    390.9 ˚C est.

heart base
Green
Floral
Fresh
Aldehydic
Leafy
Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
No restriction
Category 2
Products applied to the axillae
No restriction Category 7B
Leave-on products applied to the hair with some hand contact
No restriction
Category 3
Products applied to the face/body using fingertips
No restriction Category 8
Products with significant anogenital exposure
No restriction
Category 4
Products related to fine fragrance
No restriction Category 9
Products with body and hand exposure, primarily rinse off
No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
No restriction Category 10A
Household care products with mostly hand contact
No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
No restriction
Category 5D
Baby Creams, baby Oils and baby talc
No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
No restriction
Category 6
Products with oral and lip exposure
No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
No restriction
  • All orders will be processed within 1-2 business days from the time the order is confirmed.
  • Free shipping is available for orders valued at $200 or more.
  • Delivery time is 1-3 business days for local areas, 3-7 days for suburban and nationwide deliveries, and 1-4 weeks for international orders.
  • You have 30 days from the date of receipt to initiate the return process.
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  • Certificate of Analysis (COA)

    Provides information on the physical and chemical properties of the product.
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  • IFRA Certificate of Conformity

    Sets safety standards and guidelines for the product in manufacturing.
    Download  
  • Safety Data Sheet (SDS)

    Provides important safety guidelines for transporting, storing, and using the product.
    Download  
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