Dimethyl Octenone DMO Aroma Chemical
CAS# 2550-11-0
Fruity, Citrus, Herbal, Fresh, Floral
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Dimethyl Octenone (DMO) is a synthetic fragrance molecule, notable for its own freshness and vibrancy. DMO plays an important role in creating realistic, contemporary citrus and fresh-fruity effects in modern fragrance formulas.
Created entirely in the laboratory, Dimethyl Octenone does not occur in nature. It was developed to deliver a distinctive odor note that natural materials often cannot reproduce in a stable and consistent way. In appearance, this compound is a colorless liquid, yet it carries an explosive citrus–fruity scent profile that is sharp, fresh, and accented by a subtle, refined bitterness.
Because of these characteristics, Dimethyl Octenone is used primarily in perfumery and consumer fragrances as a key to creating or amplifying citrus notes-especially realistic grapefruit effects-and juicy tropical fruit facets. Although the specific timeline of its introduction is not widely disclosed, Dimethyl Octenone is a representative example of a modern-generation ingredient developed to meet ongoing demand for novel, high-performance notes.
Description
Dimethyl Octenone is a standout in the Citrus and Fruity odor families. It is a “secret weapon” for top notes, functioning as a highly effective booster and modifier that delivers an immediate burst of energy and diffusion from the very first seconds.
Its odor is highly characteristic, vividly recreating the fresh, bitter zing of pink grapefruit peel. More detailed descriptions evoke freshly cut pineapple slices, blended with the juiciness of ripe citrus fruits and an unexpected, cool “green metallic” nuance. Its strength lies in relatively high intensity and good diffusion, bringing liveliness and a sparkling explosion to the opening. However, this brilliance is relatively short-lived, with an odor persistence of roughly 2 to 4 hours on a blotter.
It is a key component for building natural, realistic grapefruit accords, particularly for emphasizing grapefruit’s signature bitter edge. It is also used to ignite freshness and juiciness in tropical fruit profiles such as pineapple, mango, and passion fruit, and to give white floral notes a more modern “sheen.” Dimethyl Octenone performs well when combined with other fruity esters and aldehydes to weave complex fruity accords. Because its odor impact is very strong, perfumers often use it pre-diluted-e.g., at 10% or lower-to control dosage more easily and avoid overwhelming other components in the fragrance “orchestra.”
Applications
Dimethyl Octenone’s versatility allows it to shine across a wide range of consumer products. It brings freshness to fine fragrance; personal care products such as body wash, shampoo, lotions, and deodorants; and home-care products such as laundry detergent, fabric softener, scented candles, room sprays, and multi-purpose cleaners.
However, use of this powerful molecule is tightly controlled. The International Fragrance Association (IFRA) has restricted Dimethyl Octenone due to concerns about skin sensitization potential and systemic toxicity. Under the 51st Amendment, the maximum permitted level in fine fragrance is 1.9%, while in other products such as body lotion it is 0.48%, and in rinse-off products it is 1.5%. From a storage standpoint, it should be kept in a cool, well-ventilated place and away from heat or open flames, as it is a flammable liquid.
Although it is a flexible modifier found in many modern citrus- or fruit-forward fragrances and consumer products, Dimethyl Octenone is rarely promoted as a “hero” ingredient. DMO contributes to a fragrance’s success, and therefore there are no products that use DMO as the main featured component.
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Technical standards
Technical standards
Solubility @25˚C
Solubility @25˚C
| Solvent | Solubility (g/L) |
|---|---|
| ethanol | 2679.84 |
| methanol | 1958.39 |
| isopropanol | 3193.56 |
| water | 2.85 |
| ethyl acetate | 2499.75 |
| n-propanol | 2394.52 |
| acetone | 2616.04 |
| n-butanol | 2823.52 |
| acetonitrile | 2589.39 |
| DMF | 1796.95 |
| toluene | 1409.77 |
| isobutanol | 2319.61 |
| 1,4-dioxane | 3281.15 |
| methyl acetate | 1842.84 |
| THF | 3493.07 |
| 2-butanone | 2419.69 |
| n-pentanol | 1847.56 |
| sec-butanol | 3196.15 |
| n-hexane | 1432.4 |
| ethylene glycol | 228.57 |
| NMP | 1790.76 |
| cyclohexane | 1359.04 |
| DMSO | 1054.1 |
| n-butyl acetate | 2353.19 |
| n-octanol | 1266.51 |
| chloroform | 6681.41 |
| n-propyl acetate | 1442.35 |
| acetic acid | 1629.29 |
| dichloromethane | 4467.12 |
| cyclohexanone | 3229.27 |
| propylene glycol | 503.25 |
| isopropyl acetate | 1726.13 |
| DMAc | 1762.64 |
| 2-ethoxyethanol | 1408.94 |
| isopentanol | 2903.48 |
| n-heptane | 610.34 |
| ethyl formate | 1237.22 |
| 1,2-dichloroethane | 2388.51 |
| n-hexanol | 2513.04 |
| 2-methoxyethanol | 1866.81 |
| isobutyl acetate | 956.62 |
| tetrachloromethane | 1719.69 |
| n-pentyl acetate | 1431.36 |
| transcutol | 4076.37 |
| n-heptanol | 1200.59 |
| ethylbenzene | 1014.77 |
| MIBK | 1377.07 |
| 2-propoxyethanol | 2019.93 |
| tert-butanol | 4150.09 |
| MTBE | 3946.34 |
| 2-butoxyethanol | 1426.5 |
| propionic acid | 1408.77 |
| o-xylene | 990.2 |
| formic acid | 331.42 |
| diethyl ether | 2964.34 |
| m-xylene | 990.91 |
| p-xylene | 1360.61 |
| chlorobenzene | 1665.92 |
| dimethyl carbonate | 360.3 |
| n-octane | 247.47 |
| formamide | 444.26 |
| cyclopentanone | 2604.43 |
| 2-pentanone | 2134.87 |
| anisole | 1309.06 |
| cyclopentyl methyl ether | 2062.71 |
| gamma-butyrolactone | 2309.87 |
| 1-methoxy-2-propanol | 1613.11 |
| pyridine | 2584.43 |
| 3-pentanone | 1454.93 |
| furfural | 1960.47 |
| n-dodecane | 142.32 |
| diethylene glycol | 919.69 |
| diisopropyl ether | 1039.81 |
| tert-amyl alcohol | 3602.11 |
| acetylacetone | 1572.11 |
| n-hexadecane | 162.75 |
| acetophenone | 1067.76 |
| methyl propionate | 1170.17 |
| isopentyl acetate | 2116.34 |
| trichloroethylene | 4671.2 |
| n-nonanol | 1039.58 |
| cyclohexanol | 2604.67 |
| benzyl alcohol | 1022.75 |
| 2-ethylhexanol | 1645.54 |
| isooctanol | 997.41 |
| dipropyl ether | 1556.05 |
| 1,2-dichlorobenzene | 1366.45 |
| ethyl lactate | 469.36 |
| propylene carbonate | 1547.77 |
| n-methylformamide | 815.22 |
| 2-pentanol | 2462.01 |
| n-pentane | 972.09 |
| 1-propoxy-2-propanol | 1697.13 |
| 1-methoxy-2-propyl acetate | 1304.92 |
| 2-(2-methoxypropoxy) propanol | 1017.77 |
| mesitylene | 667.38 |
| ε-caprolactone | 2730.23 |
| p-cymene | 623.06 |
| epichlorohydrin | 2745.5 |
| 1,1,1-trichloroethane | 3869.12 |
| 2-aminoethanol | 704.95 |
| morpholine-4-carbaldehyde | 1999.84 |
| sulfolane | 1821.38 |
| 2,2,4-trimethylpentane | 419.93 |
| 2-methyltetrahydrofuran | 3880.97 |
| n-hexyl acetate | 2054.44 |
| isooctane | 318.83 |
| 2-(2-butoxyethoxy)ethanol | 1415.66 |
| sec-butyl acetate | 1206.18 |
| tert-butyl acetate | 1653.77 |
| decalin | 508.98 |
| glycerin | 496.72 |
| diglyme | 2388.95 |
| acrylic acid | 930.84 |
| isopropyl myristate | 635.59 |
| n-butyric acid | 2693.2 |
| acetyl acetate | 1204.8 |
| di(2-ethylhexyl) phthalate | 503.98 |
| ethyl propionate | 1145.2 |
| nitromethane | 1884.49 |
| 1,2-diethoxyethane | 1971.56 |
| benzonitrile | 1673.47 |
| trioctyl phosphate | 377.14 |
| 1-bromopropane | 2533.04 |
| gamma-valerolactone | 2865.08 |
| n-decanol | 676.4 |
| triethyl phosphate | 475.04 |
| 4-methyl-2-pentanol | 1279.63 |
| propionitrile | 2191.48 |
| vinylene carbonate | 1348.38 |
| 1,1,2-trichlorotrifluoroethane | 1674.13 |
| DMS | 843.76 |
| cumene | 684.1 |
| 2-octanol | 1003.97 |
| 2-hexanone | 1689.14 |
| octyl acetate | 766.62 |
| limonene | 1012.2 |
| 1,2-dimethoxyethane | 2526.27 |
| ethyl orthosilicate | 548.11 |
| tributyl phosphate | 492.98 |
| diacetone alcohol | 1415.79 |
| N,N-dimethylaniline | 886.61 |
| acrylonitrile | 1796.38 |
| aniline | 1486.16 |
| 1,3-propanediol | 1225.05 |
| bromobenzene | 1822.78 |
| dibromomethane | 3471.58 |
| 1,1,2,2-tetrachloroethane | 3993.17 |
| 2-methyl-cyclohexyl acetate | 999.01 |
| tetrabutyl urea | 551.25 |
| diisobutyl methanol | 825.5 |
| 2-phenylethanol | 1146.71 |
| styrene | 1134.88 |
| dioctyl adipate | 737.28 |
| dimethyl sulfate | 498.82 |
| ethyl butyrate | 1386.93 |
| methyl lactate | 464.3 |
| butyl lactate | 852.01 |
| diethyl carbonate | 798.06 |
| propanediol butyl ether | 1140.47 |
| triethyl orthoformate | 909.91 |
| p-tert-butyltoluene | 606.28 |
| methyl 4-tert-butylbenzoate | 907.64 |
| morpholine | 3724.23 |
| tert-butylamine | 3393.5 |
| n-dodecanol | 480.82 |
| dimethoxymethane | 1020.96 |
| ethylene carbonate | 1227.19 |
| cyrene | 731.43 |
| 2-ethoxyethyl acetate | 1356.3 |
| 2-ethylhexyl acetate | 1636.75 |
| 1,2,4-trichlorobenzene | 1556.5 |
| 4-methylpyridine | 3109.26 |
| dibutyl ether | 1593.69 |
| 2,6-dimethyl-4-heptanol | 825.5 |
| DEF | 1994.53 |
| dimethyl isosorbide | 1363.57 |
| tetrachloroethylene | 2840.4 |
| eugenol | 814.42 |
| triacetin | 1123.65 |
| span 80 | 1030.79 |
| 1,4-butanediol | 505.81 |
| 1,1-dichloroethane | 3947.28 |
| 2-methyl-1-pentanol | 1892.93 |
| methyl formate | 588.01 |
| 2-methyl-1-butanol | 2670.45 |
| n-decane | 282.23 |
| butyronitrile | 2943.47 |
| 3,7-dimethyl-1-octanol | 1147.73 |
| 1-chlorooctane | 929.01 |
| 1-chlorotetradecane | 316.54 |
| n-nonane | 310.89 |
| undecane | 191.56 |
| tert-butylcyclohexane | 508.05 |
| cyclooctane | 385.03 |
| cyclopentanol | 2068.98 |
| tetrahydropyran | 4090.37 |
| tert-amyl methyl ether | 2478.54 |
| 2,5,8-trioxanonane | 1314.8 |
| 1-hexene | 2691.45 |
| 2-isopropoxyethanol | 1212.22 |
| 2,2,2-trifluoroethanol | 461.57 |
| methyl butyrate | 1624.73 |
Scent© AI

Olfactory Pyramid
Notes
| Fruity |
| Citrus |
| Herbal |
| Fresh |
| Floral |
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
|
Category 1
Products applied to the lips
|
0.18 % |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
0.55 % |
|
Category 2
Products applied to the axillae
|
0.1 % |
Category 7B
Leave-on products applied to the hair with some hand contact
|
0.55 % |
|
Category 3
Products applied to the face/body using fingertips
|
0.37 % |
Category 8
Products with significant anogenital exposure
|
0.12 % |
|
Category 4
Products related to fine fragrance
|
1.9 % |
Category 9
Products with body and hand exposure, primarily rinse off
|
1.5 % |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
0.48 % |
Category 10A
Household care products with mostly hand contact
|
0.73 % |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
0.37 % |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
2.4 % |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
0.48 % |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
0.12 % |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
0.12 % |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
0.12 % |
|
Category 6
Products with oral and lip exposure
|
0.18 % |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |
Shipping & Returns
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You have 30 days from the date of receipt to initiate the return process.
Certificates of Quality
-
Certificate of Analysis (COA)
Provides information on the physical and chemical properties of the product.Download -
IFRA Certificate of Conformity
Sets safety standards and guidelines for the product in manufacturing.Download -
Safety Data Sheet (SDS)
Provides important safety guidelines for transporting, storing, and using the product.Download