Cis-3-Hexenyl Salicylate (CAS number: 65405-77-8), also known as leaf salicylate, is a highly versatile ester that serves as a crucial foundation in the modern flavor and fragrance industry. By combining the crisp, refreshing characteristics of leaf alcohol with the deep, smooth, and long-lasting qualities of the salicylate family, this compound delivers a refined olfactory experience. Physically, it exists as a clear, colorless to pale yellow oily liquid.
The most outstanding feature of cis-3-Hexenyl Salicylate is its complex, multi-layered scent profile and impressive tenacity. Upon initial contact, it evokes the sharp and fresh notes of newly cut grass, green leaves, and herbs, accompanied by a subtle metallic nuance. As the scent develops, it softens into smooth floral notes reminiscent of lily of the valley and orchid, grounded by a warm, balsamic base. Notably, this material has an exceptional substantivity that can last for over 200 hours on a smelling strip, acting as a superb fixative to help maintain fresh green notes throughout a fragrance's lifecycle.
In perfumery and cosmetics, this compound is widely utilized due to its ability to blend harmoniously with various other raw materials. It is a key ingredient for creating natural-smelling white floral accords (such as jasmine and tuberose), and it contributes to the development of long-lasting "solar" and "marine" fragrance families. Beyond fine fragrances, cis-3-Hexenyl Salicylate is incorporated into numerous personal care items (such as shampoos, body washes, lotions, and deodorants) and home care products to provide a natural, clean atmosphere. Significantly, this ingredient has become a perfect and elegant substitute for benzyl salicylate—a substance currently facing multiple regulatory restrictions in the fragrance industry.
Technically, cis-3-Hexenyl Salicylate demonstrates excellent stability across a variety of product formulas. It performs exceptionally well in scented candles, fabric softeners, shampoos, acid cleaners, and soaps. However, formulators should avoid using this chemical in highly alkaline or strongly oxidative environments, such as bleach or powder detergents, because its ester bond is susceptible to hydrolysis, which can alter the original scent. The compound is insoluble in water but highly soluble in alcohol and many other organic solvents.
Finally, regarding its safety and origins, cis-3-Hexenyl Salicylate is a "nature-identical" compound, found in trace amounts in carnation flowers, mangoes, and witch hazel. This product has low toxicity and fully complies with the safety standards of the International Fragrance Association (IFRA). Beyond its use in fragrances, it is approved by the US Food and Drug Administration (FDA) and the European Union (EU) as a food additive at very low concentrations to impart fresh vegetable and tropical fruit flavors. Additionally, it has agricultural applications as a Green Leaf Volatile (GLV), acting as a safe biological attractant or repellent for insects.
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