Zineb

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  • Identifiers

    CAS number
    12122-67-7

    Molecular formula
    C4H6N2S4Zn

    SMILES
    C(CNC(=S)[S-])NC(=S)[S-].[Zn+2]

    Safety labels

    Irritant
    Irritant

  • Odor profile

    Odorless 64.63%
    Sulfurous 41.31%
    Meaty 30.14%
    Savory 27.01%
    Pungent 23.08%
    Cooked 21.66%
    Fishy 21.16%
    Garlic 20.43%
    Onion 19.9%
    Roasted 19.67%

    Scent© AI

  • Properties

    Molecular weight
    275.8 g/mol

    Melting point expt.

    • 157 °C (decomposes)
    • 314.6 °F

    Boiling point

    • decomposes

    Flash point est.
    141.66 ˚C

    Flash point expt.

    • 90 °C
    • 194 °F

    Solubility expt.

    • less than 1 mg/mL at 77 °F (NTP, 1992)
    • Soluble in carbon disulfide, pyridine
    • Soluble in chloroform
    • Soluble in benzene
    • Practically insoluble in common organic solvents. Dissolves in some chelating agents, for example salts of ethylediaminetetra-acetic acid, from which it cannot be recovered.
    • In water, about 10 mg/L at 25 °C
    • Solubility in water: none

  • Synonyms

    • ZINEB
    • METIRAM
    • 12122-67-7
    • 9006-42-2
    • Tritoftorol
    • Tsineb [Russian]
    • Parzate
    • Zinc ethylenebisthiocarbamate
    • Zineb [ISO]
    • Lonacol [discontinued]
    • Zinosan [discontinued]
    • Zinebe [ISO-French]
    • Metiram-zinc
    • Ethylenebis(dithiocarbamato)zinc
    • CHEBI:52498
    • Zinc Ethylenebis(dithiocarbamate)
    • X1FSB1OZPT
    • ZINEB [IARC]
    • ENT-14874
    • ZINEB [MI]
    • Zinc, (ethylenebis(dithiocarbamato))-
    • zinc ethane-1,2-diylbis(dithiocarbamate)
    • Zinc, ((1,2-ethanediylbis(carbamodithioato))(2-))-
    • Cynkotox
    • DTXSID5021465
    • Novozir
    • Cineb
    • Tsineb (Russian)
    • Zink-(N,N'-aethylen-bis(dithiocarbamat)) [German]
    • NSC-49513
    • zinc ethane-1,2-diyldicarbamodithioate
    • Lonacol (discontinued)
    • Zinebe (ISO-French)
    • Zinosan (discontinued)
    • Clortocaffaro
    • Metriram (>90%)
    • Aaphytora
    • Aphytora
    • Asporum
    • Blightox
    • Blizene
    • Bombardier
    • Carbadine
    • Crittox
    • Deikusol
    • Devizeb
    • Dithane Z-78
    • Ditiamina
    • Hexathane
    • Kupratsin
    • Lipotan
    • Lirotan
    • Lonacol
    • Perosin
    • Perozin
    • Perozine
    • Taloberg
    • Tanazon
    • Thiodow
    • Tiezene
    • Zebenide
    • Zinosan
    • Daisen
    • Dipher
    • Discon
    • Funjeb
    • Kypzin
    • Micide
    • Phytox
    • Tiazin
    • Unizeb
    • Zebtox
    • Aspor
    • Zidan
    • Zipar
    • Parzate zineb
    • Fungo-pulvit
    • ZINEB (IARC)
    • Crystal Zineb
    • Dithane Z
    • Novosir N
    • Novozir N
    • Parzate C
    • Sperlox-Z
    • Thionic M
    • Discon-Z
    • Pamosol 2 forte
    • Pilzol SZ
    • CHEM zineb
    • Zineb-R
    • ZINEB (ZINC ETHYLENEBIS-DITHIOCARBAMATE)
    • Fitodith 80
    • Perozine 75B
    • Dithane 65
    • Perosin 75B
    • [ethane-1,2-diylbiscarbamodithioato(2-)-kappaS]zinc
    • Micide 55
    • Zinc, [[1,2-ethanediylbis[carbamodithioato]](2-)]-
    • Novozin N 50
    • Novozir N 50
    • Parzate; zineb 80
    • Zineb 75
    • Zineb 80
    • Caswell No. 930
    • Zineb [BSI:ISO]
    • Metiram, technical grade (with 2% added ethylenethiourea)
    • Zineb 75 WP
    • Polikarbatsin
    • Carbatene
    • Amarex
    • Tsineb
    • Zinebe
    • Metirame zinc
    • Zinc metiram
    • [{2-[(sulfanylcarbothioyl)amino]ethyl}carbamodithioato(2-)-kappa(2)S,S']zinc
    • ETHYLENEBIS[DITHIOCARBAMATO]ZINC
    • zinc(2+) ion ({2-[(sulfanidylmethanethioyl)amino]ethyl}carbamothioyl)sulfanide
    • ZINC ETHYLENEBIS[DITHIOCARBAMATE]
    • Zincethylenebisdithiocarbamate
    • Shaughnessy Number 014506
    • Zinc ethylenebisdithiocarbamate
    • CCRIS 2503
    • Zinc ethylene bisdithiocarbamate
    • ZINC, [ETHYLENEBIS[DITHIOCARBAMATO]]-
    • HSDB 1787
    • Caswell No. 041A
    • Metirame zinc [French]
    • Polikarbatsin [Russian]

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 3.69
    methanol 6.8
    isopropanol 1.92
    water 0.56
    ethyl acetate 3.66
    n-propanol 2.76
    acetone 9.66
    n-butanol 1.85
    acetonitrile 4.81
    DMF 117.06
    toluene 0.56
    isobutanol 1.61
    1,4-dioxane 5.31
    methyl acetate 6.23
    THF 12.2
    2-butanone 7.81
    n-pentanol 1.98
    sec-butanol 1.84
    n-hexane 0.06
    ethylene glycol 6.31
    NMP 96.26
    cyclohexane 0.08
    DMSO 101.47
    n-butyl acetate 4.65
    n-octanol 1.88
    chloroform 3.83
    n-propyl acetate 4.0
    acetic acid 7.68
    dichloromethane 5.31
    cyclohexanone 9.09
    propylene glycol 3.95
    isopropyl acetate 2.24
    DMAc 121.45
    2-ethoxyethanol 12.89
    isopentanol 1.38
    n-heptane 0.15
    ethyl formate 6.96
    1,2-dichloroethane 4.01
    n-hexanol 2.55
    2-methoxyethanol 21.67
    isobutyl acetate 1.71
    tetrachloromethane 0.6
    n-pentyl acetate 3.9
    transcutol 15.27
    n-heptanol 2.11
    ethylbenzene 0.54
    MIBK 2.13
    2-propoxyethanol 14.41
    tert-butanol 2.1
    MTBE 1.34
    2-butoxyethanol 8.52
    propionic acid 5.2
    o-xylene 0.75
    formic acid 11.77
    diethyl ether 1.53
    m-xylene 0.48
    p-xylene 0.73
    chlorobenzene 1.1
    dimethyl carbonate 6.47
    n-octane 0.09
    formamide 23.49
    cyclopentanone 17.89
    2-pentanone 4.5
    anisole 2.79
    cyclopentyl methyl ether 3.08
    gamma-butyrolactone 22.86
    1-methoxy-2-propanol 13.47
    pyridine 7.44
    3-pentanone 4.02
    furfural 30.0
    n-dodecane 0.08
    diethylene glycol 18.42
    diisopropyl ether 0.31
    tert-amyl alcohol 2.22
    acetylacetone 7.98
    n-hexadecane 0.1
    acetophenone 6.36
    methyl propionate 6.87
    isopentyl acetate 3.29
    trichloroethylene 7.58
    n-nonanol 1.97
    cyclohexanol 1.69
    benzyl alcohol 5.05
    2-ethylhexanol 1.73
    isooctanol 1.62
    dipropyl ether 1.98
    1,2-dichlorobenzene 1.8
    ethyl lactate 6.8
    propylene carbonate 9.73
    n-methylformamide 26.32
    2-pentanol 1.0
    n-pentane 0.06
    1-propoxy-2-propanol 9.84
    1-methoxy-2-propyl acetate 8.22
    2-(2-methoxypropoxy) propanol 10.1
    mesitylene 0.33
    ε-caprolactone 9.87
    p-cymene 0.89
    epichlorohydrin 16.42
    1,1,1-trichloroethane 1.74
    2-aminoethanol 6.71
    morpholine-4-carbaldehyde 53.13
    sulfolane 50.78
    2,2,4-trimethylpentane 0.05
    2-methyltetrahydrofuran 4.92
    n-hexyl acetate 3.8
    isooctane 0.02
    2-(2-butoxyethoxy)ethanol 10.18
    sec-butyl acetate 1.84
    tert-butyl acetate 2.26
    decalin 0.07
    glycerin 12.69
    diglyme 18.88
    acrylic acid 7.52
    isopropyl myristate 1.55
    n-butyric acid 4.86
    acetyl acetate 2.64
    di(2-ethylhexyl) phthalate 3.79
    ethyl propionate 3.5
    nitromethane 25.52
    1,2-diethoxyethane 4.44
    benzonitrile 4.55
    trioctyl phosphate 2.58
    1-bromopropane 1.35
    gamma-valerolactone 32.02
    n-decanol 1.58
    triethyl phosphate 3.32
    4-methyl-2-pentanol 0.61
    propionitrile 3.62
    vinylene carbonate 9.97
    1,1,2-trichlorotrifluoroethane 27.7
    DMS 5.45
    cumene 0.52
    2-octanol 1.3
    2-hexanone 3.86
    octyl acetate 2.58
    limonene 1.2
    1,2-dimethoxyethane 18.94
    ethyl orthosilicate 2.68
    tributyl phosphate 2.79
    diacetone alcohol 6.83
    N,N-dimethylaniline 3.49
    acrylonitrile 7.63
    aniline 2.63
    1,3-propanediol 5.93
    bromobenzene 0.78
    dibromomethane 2.58
    1,1,2,2-tetrachloroethane 7.34
    2-methyl-cyclohexyl acetate 3.83
    tetrabutyl urea 5.55
    diisobutyl methanol 0.91
    2-phenylethanol 5.24
    styrene 0.67
    dioctyl adipate 3.76
    dimethyl sulfate 23.93
    ethyl butyrate 4.04
    methyl lactate 11.8
    butyl lactate 6.79
    diethyl carbonate 3.05
    propanediol butyl ether 7.73
    triethyl orthoformate 3.4
    p-tert-butyltoluene 0.82
    methyl 4-tert-butylbenzoate 8.06
    morpholine 10.84
    tert-butylamine 0.9
    n-dodecanol 1.17
    dimethoxymethane 20.25
    ethylene carbonate 6.51
    cyrene 18.21
    2-ethoxyethyl acetate 7.27
    2-ethylhexyl acetate 2.64
    1,2,4-trichlorobenzene 2.78
    4-methylpyridine 6.57
    dibutyl ether 1.28
    2,6-dimethyl-4-heptanol 0.91
    DEF 16.13
    dimethyl isosorbide 17.18
    tetrachloroethylene 4.44
    eugenol 10.86
    triacetin 7.44
    span 80 7.43
    1,4-butanediol 3.79
    1,1-dichloroethane 1.99
    2-methyl-1-pentanol 1.53
    methyl formate 18.05
    2-methyl-1-butanol 1.54
    n-decane 0.14
    butyronitrile 2.75
    3,7-dimethyl-1-octanol 1.54
    1-chlorooctane 0.7
    1-chlorotetradecane 0.32
    n-nonane 0.12
    undecane 0.1
    tert-butylcyclohexane 0.06
    cyclooctane 0.04
    cyclopentanol 3.44
    tetrahydropyran 2.52
    tert-amyl methyl ether 1.49
    2,5,8-trioxanonane 15.06
    1-hexene 0.29
    2-isopropoxyethanol 7.43
    2,2,2-trifluoroethanol 8.54
    methyl butyrate 5.56

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction