Trichlorofluoromethane

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  • Identifiers

    CAS number
    75-69-4

    Molecular formula
    CCl3F

    SMILES
    C(F)(Cl)(Cl)Cl

    Safety labels

    Irritant
    Irritant

  • Odor profile

    Odorless 41.08%
    Floral 33.02%
    Sweet 29.79%
    Woody 23.45%
    Balsamic 22.66%
    Fishy 21.87%
    Fresh 21.04%
    Rose 19.34%
    Clean 18.8%
    Citrus 18.26%

    Scent© AI

    Odor threshold>

    • Odor Threshold Low: 200000.0 [mmHg]. Odor threshold is 200,000 ppm (20% by volume). [CHEMINFO] VP from HSDB
    • Low: 28.0 mg/cu m; High: 1170.4 mg/cu m

  • Properties

    XLogP3-AA
    2.5

    Molecular weight
    137.36 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Ultra fast

    Melting point expt.

    • -168 °F (NTP, 1992)
    • -110.44 °C
    • -111 °C
    • -168 °F

    Boiling point

    • 74.7 °F at 760 mmHg (NTP, 1992)
    • 23.7 °C
    • 24 °C
    • 75 °F

    Flash point est.
    -5.1 ˚C

    Solubility expt.

    • 10 to 50 mg/mL at 64 °F (NTP, 1992)
    • Insoluble in water
    • In water, 1,100 mg/L at 25 °C
    • In water, 1300 mg/L at 20 °C
    • Soluble in alcohol, ether, other organic solvents
    • Solubility in water, g/100ml at 20 °C: 0.1
    • (75 °F): 0.1%

  • Synonyms

    • Trichlorofluoromethane
    • Fluorotrichloromethane
    • 75-69-4
    • trichloro(fluoro)methane
    • Trichloromonofluoromethane
    • Fluorochloroform
    • Eskimon 11
    • Trichlorofluorocarbon
    • CFC-11
    • Refrigerant 11
    • Algofrene type 1
    • Freon MF
    • Arcton 9
    • FREON 11
    • Arcton 11
    • Monofluorotrichloromethane
    • Electro-CF 11
    • Methane, trichlorofluoro-
    • Fluorocarbon 11
    • Propellant 11
    • Freon HE
    • Chladone 11
    • Genetron 11SBA
    • Daiflon 11
    • Daiflon S 1
    • Isotron 11
    • Kaltron 11
    • Khladon 11
    • Frigen 11
    • Frigen 11A
    • Freon 11A
    • Dymel 11
    • Fluon 11
    • Halon 11
    • Ledon 11
    • Frigen S 11
    • Isceon 131
    • F 11 (halocarbon)
    • Trichloromethyl fluoride
    • Halocarbon 11
    • Genetron 11
    • Methane, fluorotrichloro-
    • Refrigerant R 11
    • Ucon flurocarbon 11
    • Ucon refrigerant 11
    • Freon 11B
    • CCl3F
    • Caswell No. 878
    • Fluorocarbon No. 11
    • R 11 (refrigerant)
    • FC 11 (halocarbon)
    • FKW 11
    • Fluorotrojchlorometan
    • F 11B
    • FC 11
    • CFCl3
    • CCRIS 604
    • Fluorotrojchlorometan [Polish]
    • CFC 11
    • HSDB 138
    • NCI-C04637
    • EINECS 200-892-3
    • EPA Pesticide Chemical Code 000013
    • BRN 1732469
    • Trichloromonofluoromethane [NF]
    • DTXSID5021384
    • F 11
    • R 11
    • CHEBI:48236
    • 990TYB331R
    • TRICHLORFLUOMETHANE
    • Freon 11 (TN)
    • CHLOROFLUOROCARBON 11
    • DTXCID701384
    • Trichloromonofluoromethane (NF)
    • TRICHLOROFLUOROMETHANE [MI]
    • 4-01-00-00054 (Beilstein Handbook Reference)
    • TRICHLOROFLUOROMETHANE [MART.]
    • TRICHLOROMONOFLUOROMETHANE [II]
    • TRICHLOROFLUOROMETHANE [WHO-DD]
    • TRICHLOROMONOFLUOROMETHANE [HSDB]
    • TRICHLOROMONOFLUOROMETHANE [VANDF]
    • Freon-11
    • FLUOROTROJCHLOROMETAN (POLISH)
    • TRICHLOROFLUOROMETHANE (MART.)
    • TRICHLOROMONOFLUOROMETHANE (II)
    • Aigofrene type 1
    • fluorocarbon no.11
    • RCRA waste no. U121
    • F-11
    • UNII-990TYB331R
    • Distillex DS6
    • Refrigerant R11
    • Freon II
    • Triclorofluormethane
    • ElectroCF 11
    • MFCD00000784
    • R 11, Halocarbon
    • FC 11, Halocarbon
    • Methane, fluorotrichloro
    • ASAHIFRON 11
    • ELECTRO CF 11
    • Fluorotrichloromethane 99%
    • ISCEON 11
    • SCHEMBL1320
    • Chlorofluoromethane (CCl3F)
    • FRON 11
    • UCON 11
    • Fluorotrichloromethane (OSHA)
    • CHEMBL348290
    • R 11SS
    • Trichlorofluoromethane, >=99.5%
    • Tox21_201190
    • Trichlorofluoromethane (ACGIH:OSHA)
    • InChI=1/CCl3F/c2-1(3,4)
    • AKOS007930402
    • CAS-75-69-4
    • NCGC00091043-01
    • NCGC00091043-02
    • NCGC00258742-01
    • Trichlorofluoromethane, analytical standard
    • DB-055980
    • DESFLURANE IMPURITY D [EP IMPURITY]
    • DESFLURANE IMPURITY F [EP IMPURITY]
    • NS00005110
    • D06220
    • Fluorotrichloromethane 100 microg/mL in Methanol
    • Trichlorofluoromethane 100 microg/mL in Methanol

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 333.85
    methanol 490.96
    isopropanol 289.12
    water 95.43
    ethyl acetate 150.69
    n-propanol 242.26
    acetone 410.84
    n-butanol 201.54
    acetonitrile 211.62
    DMF 1096.25
    toluene 92.24
    isobutanol 179.53
    1,4-dioxane 282.95
    methyl acetate 175.47
    THF 521.55
    2-butanone 223.91
    n-pentanol 150.94
    sec-butanol 215.08
    n-hexane 72.19
    ethylene glycol 214.72
    NMP 678.29
    cyclohexane 80.79
    DMSO 1102.82
    n-butyl acetate 109.89
    n-octanol 122.79
    chloroform 209.73
    n-propyl acetate 130.18
    acetic acid 259.05
    dichloromethane 228.88
    cyclohexanone 220.69
    propylene glycol 155.9
    isopropyl acetate 126.73
    DMAc 740.24
    2-ethoxyethanol 313.22
    isopentanol 165.49
    n-heptane 72.82
    ethyl formate 149.21
    1,2-dichloroethane 186.96
    n-hexanol 126.38
    2-methoxyethanol 485.52
    isobutyl acetate 81.56
    tetrachloromethane 77.1
    n-pentyl acetate 105.44
    transcutol 411.27
    n-heptanol 102.54
    ethylbenzene 66.83
    MIBK 155.57
    2-propoxyethanol 262.15
    tert-butanol 328.25
    MTBE 229.05
    2-butoxyethanol 175.89
    propionic acid 150.41
    o-xylene 101.08
    formic acid 233.13
    diethyl ether 259.75
    m-xylene 88.8
    p-xylene 80.03
    chlorobenzene 72.9
    dimethyl carbonate 144.51
    n-octane 37.68
    formamide 368.12
    cyclopentanone 312.97
    2-pentanone 218.38
    anisole 146.5
    cyclopentyl methyl ether 246.67
    gamma-butyrolactone 298.45
    1-methoxy-2-propanol 395.1
    pyridine 209.8
    3-pentanone 187.08
    furfural 285.7
    n-dodecane 27.97
    diethylene glycol 288.5
    diisopropyl ether 111.6
    tert-amyl alcohol 232.16
    acetylacetone 220.51
    n-hexadecane 29.82
    acetophenone 149.3
    methyl propionate 179.2
    isopentyl acetate 92.55
    trichloroethylene 206.17
    n-nonanol 110.46
    cyclohexanol 173.33
    benzyl alcohol 131.46
    2-ethylhexanol 92.63
    isooctanol 86.98
    dipropyl ether 177.85
    1,2-dichlorobenzene 76.6
    ethyl lactate 110.89
    propylene carbonate 140.37
    n-methylformamide 416.46
    2-pentanol 173.62
    n-pentane 104.82
    1-propoxy-2-propanol 210.88
    1-methoxy-2-propyl acetate 137.89
    2-(2-methoxypropoxy) propanol 169.99
    mesitylene 76.51
    ε-caprolactone 173.07
    p-cymene 71.15
    epichlorohydrin 256.08
    1,1,1-trichloroethane 142.72
    2-aminoethanol 255.17
    morpholine-4-carbaldehyde 524.51
    sulfolane 457.95
    2,2,4-trimethylpentane 44.65
    2-methyltetrahydrofuran 270.52
    n-hexyl acetate 126.87
    isooctane 36.4
    2-(2-butoxyethoxy)ethanol 200.73
    sec-butyl acetate 91.23
    tert-butyl acetate 144.52
    decalin 34.48
    glycerin 229.45
    diglyme 383.0
    acrylic acid 164.21
    isopropyl myristate 82.44
    n-butyric acid 153.24
    acetyl acetate 99.4
    di(2-ethylhexyl) phthalate 69.74
    ethyl propionate 128.18
    nitromethane 391.98
    1,2-diethoxyethane 181.17
    benzonitrile 108.63
    trioctyl phosphate 64.12
    1-bromopropane 151.7
    gamma-valerolactone 335.15
    n-decanol 91.04
    triethyl phosphate 75.72
    4-methyl-2-pentanol 112.89
    propionitrile 154.69
    vinylene carbonate 128.58
    1,1,2-trichlorotrifluoroethane 253.81
    DMS 108.84
    cumene 60.16
    2-octanol 91.65
    2-hexanone 158.32
    octyl acetate 93.51
    limonene 98.77
    1,2-dimethoxyethane 465.41
    ethyl orthosilicate 79.99
    tributyl phosphate 67.68
    diacetone alcohol 197.9
    N,N-dimethylaniline 181.89
    acrylonitrile 184.03
    aniline 129.97
    1,3-propanediol 236.32
    bromobenzene 64.03
    dibromomethane 182.43
    1,1,2,2-tetrachloroethane 205.4
    2-methyl-cyclohexyl acetate 90.42
    tetrabutyl urea 118.73
    diisobutyl methanol 87.4
    2-phenylethanol 106.79
    styrene 76.95
    dioctyl adipate 100.63
    dimethyl sulfate 248.02
    ethyl butyrate 114.07
    methyl lactate 163.28
    butyl lactate 103.71
    diethyl carbonate 78.27
    propanediol butyl ether 170.35
    triethyl orthoformate 98.62
    p-tert-butyltoluene 72.72
    methyl 4-tert-butylbenzoate 160.73
    morpholine 352.88
    tert-butylamine 244.18
    n-dodecanol 78.21
    dimethoxymethane 535.76
    ethylene carbonate 113.01
    cyrene 181.75
    2-ethoxyethyl acetate 118.0
    2-ethylhexyl acetate 78.56
    1,2,4-trichlorobenzene 91.03
    4-methylpyridine 196.26
    dibutyl ether 127.36
    2,6-dimethyl-4-heptanol 87.4
    DEF 339.28
    dimethyl isosorbide 241.24
    tetrachloroethylene 164.83
    eugenol 160.57
    triacetin 129.69
    span 80 153.67
    1,4-butanediol 133.94
    1,1-dichloroethane 165.71
    2-methyl-1-pentanol 117.99
    methyl formate 301.23
    2-methyl-1-butanol 154.14
    n-decane 42.0
    butyronitrile 144.14
    3,7-dimethyl-1-octanol 107.26
    1-chlorooctane 80.16
    1-chlorotetradecane 46.24
    n-nonane 43.84
    undecane 32.91
    tert-butylcyclohexane 33.92
    cyclooctane 40.87
    cyclopentanol 217.12
    tetrahydropyran 241.94
    tert-amyl methyl ether 209.28
    2,5,8-trioxanonane 293.94
    1-hexene 120.84
    2-isopropoxyethanol 213.83
    2,2,2-trifluoroethanol 169.72
    methyl butyrate 157.99

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction