Ziram

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  • Identifiers

    CAS number
    137-30-4

    Molecular formula
    C6H12N2S4Zn

    SMILES
    CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Zn+2]

    Safety labels

    Corrosive
    Corrosive

    Acute Toxic
    Acute Toxic

    Health Hazard
    Health

    Environmental Hazard
    Environmental

  • Odor profile

    Sulfurous 54.57%
    Odorless 43.12%
    Cheesy 38.07%
    Onion 27.92%
    Meaty 27.42%
    Savory 25.83%
    Pungent 25.81%
    Ripe 24.34%
    Garlic 23.31%
    Roasted 22.51%

    Scent© AI

  • Properties

    Molecular weight
    305.8 g/mol

    Melting point expt.

    • 482 °F (NTP, 1992)
    • 246 °C
    • MP: 250 °C (crystals); 148 °C (dust).
    • MP: 240-244 °C /Technical/
    • 240-250 °C

    Flash point est.
    96.37 ˚C

    Flash point expt.

    • 200 °F (NTP, 1992)

    Solubility expt.

    • less than 1 mg/mL at 70 °F (NTP, 1992)
    • Soluble in carbon disulfide, chloroform, dilute alkalies, and concentrated HCl.
    • In alcohol: less than 0.2 g/100 ml @ 25 °C; in acetone: less than 0.5 g/100 ml @ 25 °C; in benzene: less than 0.5 g/100 ml @ 25 °C; in carbon tetrachloride: less than 0.2 g/100 ml @ 25 °C; in ether: less than 0.2 g/100 ml @ 25 °C; in naphtha: 0.5 g/100 ml @ 25 °C. sol in diluted caustic soln.
    • Soluble in alkali.
    • In water, 65 mg/l @ 25 °C
    • Solubility in water: very poor

  • Synonyms

    • ZIRAM
    • Zinc dimethyldithiocarbamate
    • 137-30-4
    • Dimethyldithiocarbamic acid zinc salt
    • Zinc Bis(dimethyldithiocarbamate)
    • Ziram [ISO]
    • Zirame [ISO-French]
    • Zinc, bis(dimethyldithiocarbamato)-
    • THIONIC
    • POMARSOL Z
    • Zinc, bis(dimethylcarbamodithioato-S,S')-, (T-4)-
    • zinc bis(dimethylcarbamodithioate)
    • ZIRAM [HSDB]
    • ZIRAM [IARC]
    • ZIRAM [MI]
    • Carbazinc
    • DTXSID0021464
    • Zerlate
    • CHEBI:79736
    • Milbam
    • NSC-737
    • 73D8UA974J
    • Cuman L
    • Bis(N,N-dimetil-ditiocarbammato) di zinco [Italian]
    • Zirame (ISO-French)
    • Crittam
    • Fuclasin
    • Methazate
    • Triscabol
    • Zarlate
    • Aazira
    • Cymate
    • Mezene
    • Tsimat
    • Zimate
    • Methyl cymate
    • ZIRAM (ZINC DIMETHYLDITHIOCARBAMATE)
    • ZIRAM (IARC)
    • Ziram (VAN)
    • Ziram [BSI:ISO]
    • CARBAMODITHIOIC ACID, N,N-DIMETHYL-, ZINC SALT (2:1)
    • mycr onil
    • (T-4)-BIS(N,N-DIMETHYLCARBAMODITHIOATO-.KAPPA.S,.KAPPA.S')ZINC
    • DTXCID301464
    • bis((dimethylcarbamothioyl)sulfanyl)zinc
    • bis[(dimethylcarbamothioyl)sulfanyl]zinc
    • Zinc dimethyl dithiocarbamate
    • CCRIS 625
    • Zinc bis dimethyldithiocarbamate
    • HSDB 1788
    • ENT 988
    • NSC 737
    • Ziram W7 6
    • NCI-C50442
    • EINECS 205-288-3
    • RCRA waste no. P205
    • EPA Pesticide Chemical Code 034805
    • BIS(N,N-DIMETIL-DITIOCARBAMMATO) DI ZINCO (ITALIAN)
    • Dimethyldithiocarbamate, Zinc
    • Fuclasinultra
    • UNII-73D8UA974J
    • Pomarzol Zforte
    • AI3-00988
    • ZCSpray
    • Zink-(N,N-dimethyl-dithiocarbamat) [German]
    • Bis(dimethyldithiocarbama to)zinc
    • ZC spray
    • (T-4)-bis(dimethylcarbamodithioato-kappaS,kappaS')zinc
    • Zink-(N,N-dimethyl-dithiocarbamat)
    • Vancide MA96
    • Vancide MZ96
    • AAPROTEC
    • FULASIN
    • Bis(dimethylcarbamodithiato-S,S')-zinc
    • SANCELER PZ
    • zinc bis(dimethyldithiocarbamoyl)disulfide
    • Bis(N,N-dimetil-ditiocarbammato) di zinco
    • Zinc, bis(dimethylcarbamodithioato-S,S')-
    • Zink dimethyldithiocarbamate
    • EC 205-288-3
    • Zarlate;Carbamodithioic acid
    • (T-4)-bis(dimethylcarbamodithioato-S,S')-zinc
    • (SP-4-1)-bis(dimethylcarbamodithioato-S,S')-zinc
    • carbamic acid, dimethyldithio-, z inc salt (2:1)
    • Zinc N,Ndimethyldithiocarbamate
    • NSC737
    • Zinc dimethyldithiocarbamic acid
    • Zink(N,Ndimethyldithiocarbamat)
    • zinc dimethylcarbamodithioic acid
    • CHEMBL1519327
    • Zinc, bis(dimethylcarbamodithioato-S,S')-, (beta-4)-
    • zinc(II) dimethylcarbamodithioate
    • Bisdimethyldithiocarbamate de zinc
    • Zinkbis(N,Ndimethyldithiocarbamat)
    • Zinc, bis(dimethylcarbamodithioato-kappaS,kappaS')-, (T-4)-
    • Zinc, bis(dimethyldithiocarbamato)
    • Zinkbis(N,Ndimethyldithiocarbamaat)
    • Zinc, bis(dimethylcarbamodithioato-.kappa.S,.kappa.S')-, (T-4)-
    • Bis(dimethylcarbamodithioatoS,S')zinc
    • AKOS015907829
    • Bis(N,Ndimetilditiocarbammato) di zinco
    • Zinc, bis(dimethylcarbamodithioatoS,S')
    • NCGC00091941-01
    • NCGC00164456-01
    • (T4)Bis(dimethyldithiocarbamatoS,S')zinc
    • Carbamodithioic acid, dimethyl, zinc salt
    • ZINC, BIS(DIMETHLDITHIOCARBAMATO)-
    • DB-042386
    • D0717
    • NS00075582
    • (T-4)-bis (dimethyldithiocarbamate-S,S)zinc
    • (T-4)-bis(Dimethylcarbamodithioato-S,S')zinc
    • Zinc, bis(dimethylcarbamodithioatoS,S'), (T4)
    • (T4)Bis(dimethyldithiocarbamatoS,S')zinc (9CI)
    • Carbamic acid, dimethyldithio, zinc salt (2:1)
    • Q205562
    • Zinc, bis(dimethylcarbamodithioatoS,S'), (beta4)
    • ZINC, (BIS(DIMETHYLCARBAMODITHIOATO-S,S)-T-4)-
    • Zinc, bis(dimethylcarbamodithioatokappaS,kappaS'), (T4)
    • ZINC, BIS(DIMETHYLCARBAMODITHIOATO-S-S')-, (T-4)-
    • (T-4)-BIS(N,N-DIMETHYLCARBAMODITHIOATO-KAPPAS,KAPPAS')ZINC
    • 205-288-3

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 11.16
    methanol 27.28
    isopropanol 4.1
    water 11.69
    ethyl acetate 2.86
    n-propanol 5.73
    acetone 5.9
    n-butanol 2.9
    acetonitrile 5.67
    DMF 76.31
    toluene 0.35
    isobutanol 2.83
    1,4-dioxane 9.09
    methyl acetate 6.51
    THF 13.12
    2-butanone 5.09
    n-pentanol 2.29
    sec-butanol 2.97
    n-hexane 0.07
    ethylene glycol 15.43
    NMP 94.32
    cyclohexane 0.18
    DMSO 105.34
    n-butyl acetate 3.09
    n-octanol 1.8
    chloroform 12.6
    n-propyl acetate 2.59
    acetic acid 22.27
    dichloromethane 14.56
    cyclohexanone 6.44
    propylene glycol 6.83
    isopropyl acetate 1.23
    DMAc 92.46
    2-ethoxyethanol 18.74
    isopentanol 1.73
    n-heptane 0.2
    ethyl formate 8.27
    1,2-dichloroethane 6.75
    n-hexanol 2.66
    2-methoxyethanol 40.18
    isobutyl acetate 1.13
    tetrachloromethane 2.65
    n-pentyl acetate 3.0
    transcutol 22.1
    n-heptanol 2.66
    ethylbenzene 0.4
    MIBK 0.91
    2-propoxyethanol 15.98
    tert-butanol 4.09
    MTBE 1.27
    2-butoxyethanol 10.65
    propionic acid 9.97
    o-xylene 0.83
    formic acid 63.91
    diethyl ether 1.6
    m-xylene 0.37
    p-xylene 0.6
    chlorobenzene 1.18
    dimethyl carbonate 4.62
    n-octane 0.11
    formamide 95.21
    cyclopentanone 12.97
    2-pentanone 1.81
    anisole 2.06
    cyclopentyl methyl ether 2.41
    gamma-butyrolactone 27.59
    1-methoxy-2-propanol 16.0
    pyridine 7.65
    3-pentanone 2.46
    furfural 33.85
    n-dodecane 0.08
    diethylene glycol 24.2
    diisopropyl ether 0.27
    tert-amyl alcohol 3.32
    acetylacetone 3.61
    n-hexadecane 0.09
    acetophenone 4.91
    methyl propionate 5.32
    isopentyl acetate 2.41
    trichloroethylene 14.38
    n-nonanol 1.89
    cyclohexanol 2.2
    benzyl alcohol 4.13
    2-ethylhexanol 1.69
    isooctanol 1.98
    dipropyl ether 1.67
    1,2-dichlorobenzene 2.4
    ethyl lactate 6.03
    propylene carbonate 10.21
    n-methylformamide 38.79
    2-pentanol 1.18
    n-pentane 0.1
    1-propoxy-2-propanol 9.19
    1-methoxy-2-propyl acetate 5.91
    2-(2-methoxypropoxy) propanol 10.85
    mesitylene 0.3
    ε-caprolactone 9.64
    p-cymene 0.97
    epichlorohydrin 18.77
    1,1,1-trichloroethane 3.27
    2-aminoethanol 16.26
    morpholine-4-carbaldehyde 53.52
    sulfolane 50.48
    2,2,4-trimethylpentane 0.07
    2-methyltetrahydrofuran 5.1
    n-hexyl acetate 2.93
    isooctane 0.03
    2-(2-butoxyethoxy)ethanol 11.22
    sec-butyl acetate 1.04
    tert-butyl acetate 1.43
    decalin 0.09
    glycerin 21.28
    diglyme 24.4
    acrylic acid 14.17
    isopropyl myristate 1.21
    n-butyric acid 6.41
    acetyl acetate 2.49
    di(2-ethylhexyl) phthalate 3.14
    ethyl propionate 2.48
    nitromethane 43.26
    1,2-diethoxyethane 4.31
    benzonitrile 3.13
    trioctyl phosphate 2.01
    1-bromopropane 1.65
    gamma-valerolactone 28.14
    n-decanol 1.34
    triethyl phosphate 4.13
    4-methyl-2-pentanol 0.63
    propionitrile 3.59
    vinylene carbonate 10.43
    1,1,2-trichlorotrifluoroethane 39.68
    DMS 4.93
    cumene 0.46
    2-octanol 1.35
    2-hexanone 1.98
    octyl acetate 1.95
    limonene 1.15
    1,2-dimethoxyethane 19.37
    ethyl orthosilicate 3.39
    tributyl phosphate 2.41
    diacetone alcohol 5.25
    N,N-dimethylaniline 3.16
    acrylonitrile 8.02
    aniline 2.48
    1,3-propanediol 13.03
    bromobenzene 0.83
    dibromomethane 6.34
    1,1,2,2-tetrachloroethane 12.83
    2-methyl-cyclohexyl acetate 3.65
    tetrabutyl urea 4.23
    diisobutyl methanol 0.94
    2-phenylethanol 4.89
    styrene 0.43
    dioctyl adipate 3.14
    dimethyl sulfate 17.81
    ethyl butyrate 2.88
    methyl lactate 9.79
    butyl lactate 5.85
    diethyl carbonate 3.15
    propanediol butyl ether 7.44
    triethyl orthoformate 3.3
    p-tert-butyltoluene 0.97
    methyl 4-tert-butylbenzoate 7.95
    morpholine 15.11
    tert-butylamine 1.74
    n-dodecanol 0.94
    dimethoxymethane 15.24
    ethylene carbonate 6.44
    cyrene 21.34
    2-ethoxyethyl acetate 6.08
    2-ethylhexyl acetate 2.09
    1,2,4-trichlorobenzene 3.88
    4-methylpyridine 4.38
    dibutyl ether 1.03
    2,6-dimethyl-4-heptanol 0.94
    DEF 9.9
    dimethyl isosorbide 20.99
    tetrachloroethylene 11.29
    eugenol 11.07
    triacetin 7.3
    span 80 7.61
    1,4-butanediol 5.8
    1,1-dichloroethane 2.77
    2-methyl-1-pentanol 1.59
    methyl formate 24.29
    2-methyl-1-butanol 2.03
    n-decane 0.13
    butyronitrile 2.09
    3,7-dimethyl-1-octanol 1.38
    1-chlorooctane 0.63
    1-chlorotetradecane 0.27
    n-nonane 0.11
    undecane 0.1
    tert-butylcyclohexane 0.08
    cyclooctane 0.07
    cyclopentanol 4.83
    tetrahydropyran 2.84
    tert-amyl methyl ether 1.38
    2,5,8-trioxanonane 18.33
    1-hexene 0.25
    2-isopropoxyethanol 7.97
    2,2,2-trifluoroethanol 22.84
    methyl butyrate 3.74

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction