Tolylfluanid

Overview IFRA Request a quote

  • Identifiers

    CAS number
    731-27-1

    Molecular formula
    C10H13Cl2FN2O2S2

    SMILES
    CC1=CC=C(C=C1)N(SC(F)(Cl)Cl)S(=O)(=O)N(C)C

    Safety labels

    Acute Toxic
    Acute Toxic

    Health Hazard
    Health

    Environmental Hazard
    Environmental

  • Odor profile

    Fragrance
    Odorless 46.8%
    Savory 28.01%
    Meaty 27.41%
    Cooked 26.11%
    Sulfurous 24.97%
    Citrus 21.94%
    Fresh 21.82%
    Grape 21.74%
    Roasted 21.56%
    Grapefruit 21.2%

     

    Flavor
    Bitter 53.49%
    Odorless 28.25%
    Bland 25.69%
    Mild 19.58%
    Nitrile 19.27%
    Scallion 18.63%
    Taco 18.41%
    Cedarleaf 18.26%
    Oriental 18.07%
    Bouillon 18.05%

     

    Odor impact est.
    Low

  • Properties

    XLogP3-AA
    3.9

    pKa est.
    6.8 (neutral)

    Molecular weight
    347.3 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Ultra slow

    Melting point expt.

    • 93 °C

    Boiling point

    • Decomposes on distillation

    Flash point

    • 145.58 ˚C est.

    Solubility expt.

    • Solubility in toluene: 0.9 g/mL (20 °C), 1.06 g/mL (25 °C), 1.2 g/mL (30 °C); hexane: 0.03 g/mL (20 °C), 0.05 g/mL (25 °C), 0.05 g/mL (30 °C); miscible in all proportions with acetone, ethanol, ethyl acetate, methylene chloride.
    • Solubility in heptane 54, dichloromethane >250, isopropanol 22, xylene 190 (all in g/L, 20 °C)
    • In water, 0.9 mg/L at 20 °C

  • Synonyms

    • TOLYLFLUANID
    • 731-27-1
    • Tolylfluanide
    • Tolyfluanide
    • Euparen M
    • Tolyfluanid
    • Dichlofluanid-methyl
    • Bayer 5712a
    • Bayer 49854
    • Euparen Multi
    • BAY 5712a
    • KUE 13183b
    • Tolylfluanid [BSI:ISO]
    • Tolylfluanid [ISO]
    • Tolylfluanide [ISO-French]
    • BAY 5212
    • BAY 49854
    • HSDB 6739
    • EINECS 211-986-9
    • BRN 2949607
    • TOLILFLUANIDE
    • CCRIS 9423
    • DTXSID8042478
    • FOLICUR MULTI
    • CHEBI:75182
    • MELODY MULTI
    • AI3-27470
    • 382277YXSG
    • N-dichlorofluoromethylthio-N',N'-dimethyl-N-p-tolylsulfamide
    • N'-Dichlorofluoromethylthio-N,N-dimethyl-N'-(4-tolyl)sulfamide
    • TOLYLFLUANID [HSDB]
    • N,N-Dimethyl-N-(4-tolyl)-N-(dichlorofluor-methylthio)-sulfamide
    • GORI-28
    • N-[dichloro(fluoro)methyl]sulfanyl-N-(dimethylsulfamoyl)-4-methylaniline
    • 1,1-Dichloro-N-((dimethylamino)sulfonyl)-1-fluoro-N-(4-methylphenyl)methanesulfenamide
    • Methanesulfanenamide, 1,1-dichloro-N-((dimethylamino)sulfonyl)-1-fluoro-N-(4-methylphenyl)-
    • DTXCID6022478
    • BAY-5712A
    • N-Dichlorofluoromethylthio-N',N'-dimethyl-N-p-tolylsulphamide
    • N,N-Dimethyl-N'-(4-tolyl)-N'-(dichlorfluormethylthio)-sulfamid
    • N-Dichlorofluoromethanesulphenyl-N',N'-dimethyl-N-p-tolylsulphamide
    • Dichloro-N-((dimethylamino)sulphonyl)fluoro-N-(p-tolyl)methanesulphenamide
    • N,N-Dimethyl-N'-(4-tolyl)-N'-(dichlorfluormethylthio)-sulfamid [German]
    • Sulfamide, N-((dichlorofluoromethyl)thio)-N',N'-dimethyl-N-(p-tolyl)-
    • Methanesulfenamide, 1,1-dichloro-N-((dimethylamino)sulfonyl)-1-fluoro-N-(4-methylphenyl)-
    • Methanesulfenamide, 1,1-dichloro-N-[(dimethylamino)sulfonyl]-1-fluoro-N-(4-methylphenyl)-
    • Tolyfluanid 100 microg/mL in Acetonitrile
    • Tolylfluanid 100 microg/mL in Cyclohexane
    • Tolylfluanide (ISO-French)
    • N'-DICHLOROFLUOROMETHYLTHIO-N,N-DIMETHYL-N'(P-TOLYL)SULFAMIDE
    • Dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl)methanesulphenamide
    • SULFAMIDE, N-((DICHLOROFLUOROMETHYL)THIO)-N',N'-DIMETHYL-N-P-TOLYL-
    • N-{[dichloro(fluoro)methyl]sulfanyl}-N',N'-dimethyl-N-(4-methylphenyl)sulfuric diamide
    • UNII-382277YXSG
    • Dichlofluanidmethyl
    • N-((dichloro(fluoro)methyl)sulfanyl)-N',N'-dimethyl-N-(4-methylphenyl)sulfuric diamide
    • (1,1-dichloro-N-
    • SCHEMBL21309
    • CHEMBL3189057
    • BCP18765
    • Tox21_301224
    • 1,1-Dichloro-N-((dimethylamino)sulfonyl)-1-fluoro-N-(4-methylphenyl)methanesulfenamide (9CI)
    • USEPA/OPP Pesticide Code: 309200
    • NCGC00256003-01
    • CAS-731-27-1
    • NS00000191
    • C18899
    • Tolylfluanid, PESTANAL(R), analytical standard
    • Q423824
    • NDichlorofluoromethylthioN',N'dimethylNptolylsulphamide
    • N'DichlorofluoromethylthioN,NdimethylN'(4tolyl)sulfamide
    • N,NDimethylN'(4tolyl)N'(dichlorfluormethylthio)sulfamid
    • N,NDimethylN(4tolyl)N(dichlorofluormethylthio)sulfamide
    • Tolylfluanid, certified reference material, TraceCERT(R)
    • NDichlorofluoromethanesulphenylN',N'dimethylNptolylsulphamide
    • Sulfamide, N((dichlorofluoromethyl)thio)N',N'dimethylN(ptolyl)
    • DichloroN((dimethylamino)sulphonyl)fluoroN(ptolyl)methanesulphenamide
    • Dichloro-N-[(dimethylamino)sulphonyl]fluoro-N-(p-tolyl) methanesulphenamide
    • 1,1-Dichloro-N-((dimethylamino)sulfonyl)-1-fluoro-N-(4-methylphenyl)methanesulfonamide
    • 1,1DichloroN((dimethylamino)sulfonyl)1fluoroN(4methylphenyl)methanesulfenamide
    • 1,1DichloroN((dimethylamino)sulfonyl)1fluoroN(4methylphenyl)methanesulfenamide (9CI)
    • Methanesulfanenamide, 1,1dichloroN((dimethylamino)sulfonyl)1fluoroN(4methylphenyl)
    • N-([Dichloro(fluoro)methyl]sulfanyl)-N',N'-dimethyl-N-(4-methylphenyl)sulfamide #
    • 211-986-9

  • Applications

    Tolylfluanid (CAS 731-27-1) is primarily used as a broad-spectrum agricultural fungicide to protect crops from fungal pathogens; it is also employed as a wood-preserving biocide to extend the life of timber; in coatings, inks, and related industrial products, it may function as a biocidal additive to inhibit mold and fungal growth on finished surfaces; in polymer and plastics formulations it can be evaluated as an antifungal or mold-resistant additive to improve durability; and in some regimes it is used or considered for seed treatments and post-harvest protection to reduce losses from fungal diseases, subject to local regulations and formulation limits.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 105.13
    methanol 117.51
    isopropanol 62.99
    water 0.42
    ethyl acetate 174.25
    n-propanol 74.46
    acetone 380.1
    n-butanol 65.18
    acetonitrile 287.92
    DMF 1045.83
    toluene 89.93
    isobutanol 50.69
    1,4-dioxane 207.07
    methyl acetate 237.4
    THF 447.37
    2-butanone 297.93
    n-pentanol 56.16
    sec-butanol 67.3
    n-hexane 1.05
    ethylene glycol 29.41
    NMP 750.16
    cyclohexane 3.96
    DMSO 453.31
    n-butyl acetate 119.77
    n-octanol 31.05
    chloroform 444.51
    n-propyl acetate 131.68
    acetic acid 178.57
    dichloromethane 422.96
    cyclohexanone 329.16
    propylene glycol 35.25
    isopropyl acetate 107.23
    DMAc 723.42
    2-ethoxyethanol 151.5
    isopentanol 57.33
    n-heptane 2.6
    ethyl formate 197.89
    1,2-dichloroethane 240.02
    n-hexanol 60.41
    2-methoxyethanol 248.68
    isobutyl acetate 64.37
    tetrachloromethane 30.89
    n-pentyl acetate 82.96
    transcutol 165.47
    n-heptanol 39.89
    ethylbenzene 41.78
    MIBK 100.45
    2-propoxyethanol 147.77
    tert-butanol 68.22
    MTBE 72.65
    2-butoxyethanol 99.95
    propionic acid 75.6
    o-xylene 52.41
    formic acid 124.31
    diethyl ether 67.6
    m-xylene 50.83
    p-xylene 58.7
    chlorobenzene 125.72
    dimethyl carbonate 136.11
    n-octane 1.59
    formamide 301.33
    cyclopentanone 488.23
    2-pentanone 201.69
    anisole 147.99
    cyclopentyl methyl ether 138.6
    gamma-butyrolactone 500.43
    1-methoxy-2-propanol 150.27
    pyridine 353.0
    3-pentanone 151.39
    furfural 576.16
    n-dodecane 1.66
    diethylene glycol 120.96
    diisopropyl ether 17.17
    tert-amyl alcohol 74.73
    acetylacetone 301.2
    n-hexadecane 1.94
    acetophenone 195.17
    methyl propionate 178.57
    isopentyl acetate 101.49
    trichloroethylene 717.69
    n-nonanol 29.9
    cyclohexanol 69.2
    benzyl alcohol 136.45
    2-ethylhexanol 41.27
    isooctanol 32.86
    dipropyl ether 37.21
    1,2-dichlorobenzene 124.07
    ethyl lactate 72.45
    propylene carbonate 264.1
    n-methylformamide 363.5
    2-pentanol 40.08
    n-pentane 1.9
    1-propoxy-2-propanol 93.51
    1-methoxy-2-propyl acetate 140.92
    2-(2-methoxypropoxy) propanol 96.0
    mesitylene 24.02
    ε-caprolactone 270.21
    p-cymene 30.2
    epichlorohydrin 542.58
    1,1,1-trichloroethane 189.14
    2-aminoethanol 58.67
    morpholine-4-carbaldehyde 561.4
    sulfolane 436.78
    2,2,4-trimethylpentane 1.69
    2-methyltetrahydrofuran 256.33
    n-hexyl acetate 79.53
    isooctane 0.96
    2-(2-butoxyethoxy)ethanol 105.86
    sec-butyl acetate 79.88
    tert-butyl acetate 110.13
    decalin 2.53
    glycerin 58.4
    diglyme 223.25
    acrylic acid 91.83
    isopropyl myristate 31.05
    n-butyric acid 113.65
    acetyl acetate 151.91
    di(2-ethylhexyl) phthalate 47.59
    ethyl propionate 110.25
    nitromethane 653.31
    1,2-diethoxyethane 79.13
    benzonitrile 195.28
    trioctyl phosphate 31.8
    1-bromopropane 83.05
    gamma-valerolactone 650.7
    n-decanol 22.62
    triethyl phosphate 51.76
    4-methyl-2-pentanol 25.96
    propionitrile 149.54
    vinylene carbonate 267.19
    1,1,2-trichlorotrifluoroethane 346.59
    DMS 95.98
    cumene 23.86
    2-octanol 28.38
    2-hexanone 134.62
    octyl acetate 45.19
    limonene 39.57
    1,2-dimethoxyethane 300.83
    ethyl orthosilicate 45.13
    tributyl phosphate 35.52
    diacetone alcohol 136.87
    N,N-dimethylaniline 111.2
    acrylonitrile 266.94
    aniline 127.76
    1,3-propanediol 75.94
    bromobenzene 120.19
    dibromomethane 222.92
    1,1,2,2-tetrachloroethane 409.77
    2-methyl-cyclohexyl acetate 82.12
    tetrabutyl urea 61.5
    diisobutyl methanol 21.85
    2-phenylethanol 120.74
    styrene 58.91
    dioctyl adipate 58.78
    dimethyl sulfate 214.44
    ethyl butyrate 96.2
    methyl lactate 102.63
    butyl lactate 70.99
    diethyl carbonate 72.16
    propanediol butyl ether 75.61
    triethyl orthoformate 62.1
    p-tert-butyltoluene 28.82
    methyl 4-tert-butylbenzoate 107.12
    morpholine 287.06
    tert-butylamine 33.87
    n-dodecanol 16.62
    dimethoxymethane 321.25
    ethylene carbonate 173.1
    cyrene 169.4
    2-ethoxyethyl acetate 127.36
    2-ethylhexyl acetate 79.55
    1,2,4-trichlorobenzene 167.29
    4-methylpyridine 380.27
    dibutyl ether 24.99
    2,6-dimethyl-4-heptanol 21.85
    DEF 280.07
    dimethyl isosorbide 201.0
    tetrachloroethylene 198.94
    eugenol 117.98
    triacetin 101.38
    span 80 72.93
    1,4-butanediol 39.22
    1,1-dichloroethane 205.98
    2-methyl-1-pentanol 58.37
    methyl formate 335.47
    2-methyl-1-butanol 60.66
    n-decane 2.59
    butyronitrile 145.19
    3,7-dimethyl-1-octanol 31.14
    1-chlorooctane 16.38
    1-chlorotetradecane 6.79
    n-nonane 2.08
    undecane 2.02
    tert-butylcyclohexane 2.08
    cyclooctane 1.22
    cyclopentanol 99.11
    tetrahydropyran 145.85
    tert-amyl methyl ether 69.87
    2,5,8-trioxanonane 154.66
    1-hexene 11.57
    2-isopropoxyethanol 94.25
    2,2,2-trifluoroethanol 98.19
    methyl butyrate 167.75

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction