Thiacloprid

Overview IFRA Request a quote

  • Identifiers

    CAS number
    111988-49-9

    Molecular formula
    C10H9ClN4S

    SMILES
    C1CSC(=NC#N)N1CC2=CN=C(C=C2)Cl

    Safety labels

    Acute Toxic
    Acute Toxic

    Health Hazard
    Health

    Environmental Hazard
    Environmental

  • Odor profile

    Roasted 46.9%
    Nutty 45.16%
    Meaty 41.5%
    Popcorn 36.58%
    Odorless 29.26%
    Cooked 27.87%
    Savory 22.9%
    Beefy 22.67%
    Sweet 21.69%
    Burnt 21.32%

    Scent© AI

  • Properties

    XLogP3-AA
    2.2

    Molecular weight
    252.72 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Ultra slow

    Melting point expt.

    • 136 °C

    Boiling point

    • decomp >270 °C

    Flash point est.
    201.76 ˚C

    Solubility expt.

    • In water, 185 mg/L at 20 °C
    • At 20 °C, in: n-hexane, <0.1 g/L; xylene, 0.30 g/L; dichloromethane, 160 g/L; n-octanol, 1.4 g/L; n-propanol, 3.0 g/L; acetone, 64 g/L; ethyl acetate, 9.4 g/L; polyethylene glycol, 42 g/L; acetonitrile, 52 g/L; and DMSO, 150 g/L

  • Synonyms

    • Thiacloprid
    • 111988-49-9
    • Calypso
    • (3-((6-Chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)cyanamide
    • Calypso 70WG
    • (Z)-thiacloprid
    • Thiacloprid [ISO:BSI]
    • HSDB 7268
    • [3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene]cyanamide
    • 1119449-18-1
    • DSV3A944A4
    • DTXSID7034961
    • ({3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene}amino)formonitrile
    • THIACLOPRID [MI]
    • THIACLOPRID [ISO]
    • THIACLOPRID [HSDB]
    • Cyanamide, [3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]-
    • {(2Z)-3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene}cyanamide
    • CHEMBL451432
    • DTXCID5014961
    • CHEBI:39175
    • CHEBI:39176
    • {3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene}cyanamide
    • [3-(6-Chloro-3-pyridinylmethyl)-2-thiazolidinylidene]cyanamide
    • 3-((6-chloro-3-pyridinyl)methyl)-2-thiazolidinylidene cyanamide
    • (Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide
    • Cyanamide, (3-((6-chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)-
    • [3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]cyanamide
    • N-(3-((6-Chloropyridin-3-yl)methyl)thiazolidin-2-ylidene)cyanamide
    • (Z)-(3-((6-CHLORO-3-PYRIDINYL)METHYL)-2-THIAZOLIDINYLIDENE)CYANAMIDE
    • UNII-DSV3A944A4
    • (3-((6-chloropyridin-3-yl)methyl)-1,3-thiazolidin-2-ylidene)cyanamide
    • (Z)-[3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]cyanamide
    • (E)-thiacloprid
    • (((2Z)-3-((6-chloropyridin-3-yl)methyl)-1,3-thiazolidin-2-ylidene)amino)formonitrile
    • ((2Z)-3-((6-chloropyridin-3-yl)methyl)-1,3-thiazolidin-2-ylidene)cyanamide
    • ((3-((6-chloropyridin-3-yl)methyl)-1,3-thiazolidin-2-ylidene)amino)formonitrile
    • {[(2Z)-3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene]amino}formonitrile
    • thiacloprid (ISO);(Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide;((2Z)-3-((6-chloropyridin-3-yl)methyl)-1,3-thiazolidin-2-ylidene)cyanamide
    • thiacloprid (ISO);(Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide;{(2Z)-3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene}cyanamide
    • SCHEMBL26490
    • SCHEMBL26491
    • SCHEMBL237347
    • DTXSID60861210
    • 3c84
    • HOKKPVIRMVDYPB-UHFFFAOYSA-N
    • HOKKPVIRMVDYPB-UVTDQMKNSA-N
    • HY-B1953
    • MSK20335
    • Tox21_300697
    • BDBM50251868
    • MFCD09028056
    • AKOS015897524
    • DB08620
    • NCGC00164441-01
    • NCGC00164441-02
    • NCGC00164441-03
    • NCGC00164441-04
    • NCGC00254605-01
    • AS-35094
    • FC157422
    • Thiacloprid 10 microg/mL in Acetonitrile
    • DB-017476
    • CAS-111988-49-9
    • CS-0014056
    • NS00000448
    • T2967
    • C18512
    • Thiacloprid, PESTANAL(R), analytical standard
    • (2Z)-3-
    • A802461
    • EN300-11689967
    • Q416283
    • 3-(2-Chlor-5-pyridylmethyl)-2-cyaniminothiazolidin
    • Q63408702
    • Thiacloprid, certified reference material, TraceCERT(R)
    • Z2044749895
    • (3((6Chloro3pyridinyl)methyl)2thiazolidinylidene)cyanamide
    • Cyanamide, (3((6chloro3pyridinyl)methyl)2thiazolidinylidene)
    • [3-[(6-chloranylpyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene]cyanamide
    • N-(3-(6-chloro-pyridin-3-ylmethyl)-thiazolidin-2-ylidene)-cyanamide
    • Thiacloprid, (Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide
    • 601-147-9
    • 966-711-1

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 28.55
    methanol 71.5
    isopropanol 13.67
    water 1.47
    ethyl acetate 55.65
    n-propanol 16.1
    acetone 399.46
    n-butanol 7.67
    acetonitrile 127.85
    DMF 1394.93
    toluene 25.76
    isobutanol 9.95
    1,4-dioxane 137.58
    methyl acetate 131.4
    THF 239.46
    2-butanone 192.13
    n-pentanol 12.27
    sec-butanol 8.83
    n-hexane 0.14
    ethylene glycol 61.17
    NMP 743.18
    cyclohexane 0.38
    DMSO 1601.71
    n-butyl acetate 33.63
    n-octanol 5.26
    chloroform 243.48
    n-propyl acetate 52.69
    acetic acid 220.02
    dichloromethane 351.08
    cyclohexanone 167.28
    propylene glycol 45.81
    isopropyl acetate 28.08
    DMAc 1125.26
    2-ethoxyethanol 104.94
    isopentanol 7.6
    n-heptane 0.44
    ethyl formate 110.0
    1,2-dichloroethane 162.74
    n-hexanol 9.92
    2-methoxyethanol 162.1
    isobutyl acetate 31.08
    tetrachloromethane 12.98
    n-pentyl acetate 30.41
    transcutol 190.73
    n-heptanol 8.15
    ethylbenzene 6.89
    MIBK 27.67
    2-propoxyethanol 72.18
    tert-butanol 13.09
    MTBE 9.62
    2-butoxyethanol 47.34
    propionic acid 66.41
    o-xylene 12.01
    formic acid 245.85
    diethyl ether 8.38
    m-xylene 13.76
    p-xylene 15.65
    chlorobenzene 78.91
    dimethyl carbonate 97.13
    n-octane 0.23
    formamide 395.47
    cyclopentanone 348.58
    2-pentanone 60.58
    anisole 43.54
    cyclopentyl methyl ether 29.43
    gamma-butyrolactone 372.46
    1-methoxy-2-propanol 80.55
    pyridine 302.29
    3-pentanone 59.23
    furfural 573.81
    n-dodecane 0.3
    diethylene glycol 112.05
    diisopropyl ether 2.43
    tert-amyl alcohol 10.23
    acetylacetone 166.9
    n-hexadecane 0.36
    acetophenone 95.81
    methyl propionate 81.69
    isopentyl acetate 28.42
    trichloroethylene 577.03
    n-nonanol 5.7
    cyclohexanol 10.12
    benzyl alcohol 71.37
    2-ethylhexanol 7.05
    isooctanol 6.99
    dipropyl ether 8.05
    1,2-dichlorobenzene 78.29
    ethyl lactate 50.47
    propylene carbonate 148.06
    n-methylformamide 415.71
    2-pentanol 4.13
    n-pentane 0.14
    1-propoxy-2-propanol 41.12
    1-methoxy-2-propyl acetate 61.54
    2-(2-methoxypropoxy) propanol 56.53
    mesitylene 6.33
    ε-caprolactone 115.96
    p-cymene 6.89
    epichlorohydrin 412.23
    1,1,1-trichloroethane 89.01
    2-aminoethanol 52.64
    morpholine-4-carbaldehyde 527.72
    sulfolane 547.35
    2,2,4-trimethylpentane 0.2
    2-methyltetrahydrofuran 58.45
    n-hexyl acetate 25.09
    isooctane 0.16
    2-(2-butoxyethoxy)ethanol 68.47
    sec-butyl acetate 23.78
    tert-butyl acetate 26.69
    decalin 0.41
    glycerin 100.99
    diglyme 177.62
    acrylic acid 136.09
    isopropyl myristate 9.9
    n-butyric acid 47.82
    acetyl acetate 63.64
    di(2-ethylhexyl) phthalate 25.2
    ethyl propionate 34.67
    nitromethane 808.23
    1,2-diethoxyethane 38.05
    benzonitrile 123.21
    trioctyl phosphate 13.76
    1-bromopropane 17.89
    gamma-valerolactone 534.88
    n-decanol 4.77
    triethyl phosphate 22.14
    4-methyl-2-pentanol 3.95
    propionitrile 52.56
    vinylene carbonate 197.08
    1,1,2-trichlorotrifluoroethane 468.56
    DMS 69.73
    cumene 4.82
    2-octanol 4.69
    2-hexanone 54.45
    octyl acetate 16.09
    limonene 7.48
    1,2-dimethoxyethane 160.72
    ethyl orthosilicate 16.3
    tributyl phosphate 16.67
    diacetone alcohol 49.75
    N,N-dimethylaniline 30.59
    acrylonitrile 165.81
    aniline 55.95
    1,3-propanediol 43.72
    bromobenzene 75.38
    dibromomethane 112.22
    1,1,2,2-tetrachloroethane 304.47
    2-methyl-cyclohexyl acetate 27.53
    tetrabutyl urea 27.64
    diisobutyl methanol 4.44
    2-phenylethanol 45.2
    styrene 12.96
    dioctyl adipate 26.32
    dimethyl sulfate 274.55
    ethyl butyrate 29.81
    methyl lactate 88.18
    butyl lactate 38.56
    diethyl carbonate 26.67
    propanediol butyl ether 52.23
    triethyl orthoformate 21.88
    p-tert-butyltoluene 6.25
    methyl 4-tert-butylbenzoate 51.1
    morpholine 152.48
    tert-butylamine 3.93
    n-dodecanol 3.78
    dimethoxymethane 193.62
    ethylene carbonate 115.02
    cyrene 106.8
    2-ethoxyethyl acetate 71.21
    2-ethylhexyl acetate 21.63
    1,2,4-trichlorobenzene 126.56
    4-methylpyridine 199.27
    dibutyl ether 5.65
    2,6-dimethyl-4-heptanol 4.44
    DEF 120.88
    dimethyl isosorbide 100.81
    tetrachloroethylene 155.02
    eugenol 63.31
    triacetin 72.37
    span 80 42.16
    1,4-butanediol 35.03
    1,1-dichloroethane 95.91
    2-methyl-1-pentanol 10.25
    methyl formate 384.01
    2-methyl-1-butanol 6.73
    n-decane 0.37
    butyronitrile 33.33
    3,7-dimethyl-1-octanol 6.34
    1-chlorooctane 2.96
    1-chlorotetradecane 1.55
    n-nonane 0.28
    undecane 0.33
    tert-butylcyclohexane 0.34
    cyclooctane 0.17
    cyclopentanol 24.36
    tetrahydropyran 37.19
    tert-amyl methyl ether 7.6
    2,5,8-trioxanonane 116.51
    1-hexene 1.22
    2-isopropoxyethanol 59.51
    2,2,2-trifluoroethanol 137.99
    methyl butyrate 58.79

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction