Perfluoro(methyl vinyl ether)

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  • Identifiers

    CAS number
    1187-93-5

    Molecular formula
    C3F6O

    SMILES
    C(=C(F)F)(OC(F)(F)F)F

    Safety labels

    Flammable
    Flammable

    Compressed Gas
    Compressed Gas

    Irritant
    Irritant

  • Odor profile

    Fragrance
    Odorless 54.29%
    Sweet 26.44%
    Savory 20.53%
    Fresh 19.68%
    Cooling 19.66%
    Clean 18.36%
    Sulfurous 16.99%
    Meaty 16.88%
    Balsamic 16.12%
    Mint 15.09%

     

    Flavor
    Odorless 46.94%
    Bitter 25.0%
    Mild 24.87%
    Bland 23.18%
    Sweet-like 20.24%
    Roasted 19.96%
    Scallion 19.1%
    Nitrile 18.84%
    Bouillon 18.8%
    Mousy 18.57%

     

    Odor impact est.
    High

  • Properties

    XLogP3-AA
    2.4

    pKa est.
    3.04 (weak acid)

    Molecular weight
    166.02 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Ultra fast

    Boiling point est.
    -26°C

    Flash point

    • -18.59 ˚C est.

  • Synonyms

    • Trifluoromethyl trifluorovinyl ether
    • 1187-93-5
    • Perfluoro(methyl vinyl ether)
    • Trifluoro(trifluoromethoxy)ethylene
    • Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)-
    • Ethene, trifluoro(trifluoromethoxy)-
    • 3-OXAPERFLUOROBUTENE
    • EINECS 214-703-7
    • UNII-6II375V3XG
    • BRN 1907457
    • 6II375V3XG
    • ETHER, TRIFLUOROMETHYL TRIFLUOROVINYL
    • trifluoromethoxytrifluoroethylene
    • DTXSID3051599
    • EC 214-703-7
    • TRIFLUOROMETHYL TRIFLUORVINYL ETHER
    • PERFLUOROVINYL PERFLUOROMETHYL ETHER
    • RefChem:171634
    • DTXCID1030151
    • 1,1,2-trifluoro-2-(trifluoromethoxy)ethene
    • MFCD00221780
    • Trifluoromethyltrifluorovinylether
    • perfluoromethyl vinyl ether
    • UN3153
    • CF3OCF=CF2
    • perfluoro(methylvinyl)ether
    • SCHEMBL36438
    • perfluoro (methyl vinyl ether)
    • perfluoromethyl perfluorovinyl ether
    • SBB087957
    • AKOS006228996
    • 1,2,2-trifluoro-1-(trifluoromethoxy)ethene
    • NS00011107
    • H62605
    • F007684
    • Q27264960
    • Perfluoro(methyl vinyl ether) [UN3153] [Flammable gas]
    • 1187-93-5

  • Applications

    Perfluoro(methyl vinyl ether) (CAS 1187-93-5) is a fluorinated monomer used primarily to copolymerize with vinylidene fluoride to produce high-performance fluoropolymers with chemical resistance and low-temperature flexibility. These polymers find applications in: linings and seals for chemical processing equipment, valves, and tubing; corrosion-resistant coatings on metal substrates in chemical, oil and gas, and related industries; extruded fluoropolymer tubing, wire and cable insulation, and molded or extruded parts for electronics and industrial applications; protective coatings for metal surfaces in harsh chemical environments; and fluoropolymer elastomeric materials used for seals and gaskets with high resilience.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 172.99
    methanol 337.66
    isopropanol 106.7
    water 113.18
    ethyl acetate 31.0
    n-propanol 99.8
    acetone 120.61
    n-butanol 72.26
    acetonitrile 56.58
    DMF 262.26
    toluene 19.41
    isobutanol 55.89
    1,4-dioxane 108.11
    methyl acetate 47.71
    THF 173.1
    2-butanone 62.5
    n-pentanol 52.45
    sec-butanol 80.21
    n-hexane 13.6
    ethylene glycol 79.88
    NMP 147.5
    cyclohexane 20.39
    DMSO 756.34
    n-butyl acetate 16.85
    n-octanol 30.69
    chloroform 22.32
    n-propyl acetate 22.29
    acetic acid 43.61
    dichloromethane 49.06
    cyclohexanone 40.2
    propylene glycol 40.61
    isopropyl acetate 21.94
    DMAc 234.6
    2-ethoxyethanol 144.79
    isopentanol 51.59
    n-heptane 15.79
    ethyl formate 35.41
    1,2-dichloroethane 52.35
    n-hexanol 35.0
    2-methoxyethanol 211.41
    isobutyl acetate 6.95
    tetrachloromethane 9.1
    n-pentyl acetate 18.8
    transcutol 98.28
    n-heptanol 28.76
    ethylbenzene 13.71
    MIBK 26.67
    2-propoxyethanol 76.28
    tert-butanol 123.37
    MTBE 82.37
    2-butoxyethanol 51.42
    propionic acid 28.85
    o-xylene 22.57
    formic acid 99.61
    diethyl ether 103.89
    m-xylene 14.66
    p-xylene 12.23
    chlorobenzene 6.5
    dimethyl carbonate 32.59
    n-octane 8.68
    formamide 206.08
    cyclopentanone 60.97
    2-pentanone 47.31
    anisole 39.58
    cyclopentyl methyl ether 65.18
    gamma-butyrolactone 58.02
    1-methoxy-2-propanol 114.48
    pyridine 51.6
    3-pentanone 44.58
    furfural 48.85
    n-dodecane 5.05
    diethylene glycol 78.23
    diisopropyl ether 25.52
    tert-amyl alcohol 97.96
    acetylacetone 39.9
    n-hexadecane 5.24
    acetophenone 28.5
    methyl propionate 42.03
    isopentyl acetate 11.61
    trichloroethylene 29.39
    n-nonanol 28.65
    cyclohexanol 44.84
    benzyl alcohol 29.74
    2-ethylhexanol 18.0
    isooctanol 20.81
    dipropyl ether 39.63
    1,2-dichlorobenzene 6.56
    ethyl lactate 17.83
    propylene carbonate 17.67
    n-methylformamide 140.36
    2-pentanol 52.26
    n-pentane 28.58
    1-propoxy-2-propanol 44.0
    1-methoxy-2-propyl acetate 22.78
    2-(2-methoxypropoxy) propanol 42.95
    mesitylene 11.93
    ε-caprolactone 31.29
    p-cymene 10.32
    epichlorohydrin 81.57
    1,1,1-trichloroethane 13.08
    2-aminoethanol 102.99
    morpholine-4-carbaldehyde 118.0
    sulfolane 94.59
    2,2,4-trimethylpentane 7.5
    2-methyltetrahydrofuran 88.38
    n-hexyl acetate 23.1
    isooctane 4.2
    2-(2-butoxyethoxy)ethanol 56.85
    sec-butyl acetate 12.82
    tert-butyl acetate 26.21
    decalin 5.37
    glycerin 57.3
    diglyme 111.09
    acrylic acid 25.85
    isopropyl myristate 12.66
    n-butyric acid 24.4
    acetyl acetate 14.15
    di(2-ethylhexyl) phthalate 10.45
    ethyl propionate 23.83
    nitromethane 102.55
    1,2-diethoxyethane 44.09
    benzonitrile 12.97
    trioctyl phosphate 9.95
    1-bromopropane 40.12
    gamma-valerolactone 68.51
    n-decanol 22.7
    triethyl phosphate 11.91
    4-methyl-2-pentanol 26.45
    propionitrile 38.11
    vinylene carbonate 14.43
    1,1,2-trichlorotrifluoroethane 43.99
    DMS 16.02
    cumene 10.41
    2-octanol 22.68
    2-hexanone 30.43
    octyl acetate 17.17
    limonene 15.66
    1,2-dimethoxyethane 198.28
    ethyl orthosilicate 12.58
    tributyl phosphate 8.79
    diacetone alcohol 44.36
    N,N-dimethylaniline 43.24
    acrylonitrile 40.98
    aniline 34.84
    1,3-propanediol 90.68
    bromobenzene 5.46
    dibromomethane 39.55
    1,1,2,2-tetrachloroethane 30.97
    2-methyl-cyclohexyl acetate 12.56
    tetrabutyl urea 20.63
    diisobutyl methanol 14.12
    2-phenylethanol 23.19
    styrene 14.86
    dioctyl adipate 14.55
    dimethyl sulfate 55.62
    ethyl butyrate 17.18
    methyl lactate 31.56
    butyl lactate 15.61
    diethyl carbonate 12.1
    propanediol butyl ether 33.44
    triethyl orthoformate 15.98
    p-tert-butyltoluene 10.21
    methyl 4-tert-butylbenzoate 29.98
    morpholine 134.97
    tert-butylamine 87.3
    n-dodecanol 17.73
    dimethoxymethane 194.77
    ethylene carbonate 14.48
    cyrene 33.91
    2-ethoxyethyl acetate 23.38
    2-ethylhexyl acetate 9.66
    1,2,4-trichlorobenzene 8.07
    4-methylpyridine 40.96
    dibutyl ether 24.65
    2,6-dimethyl-4-heptanol 14.12
    DEF 83.15
    dimethyl isosorbide 48.86
    tetrachloroethylene 28.88
    eugenol 30.35
    triacetin 18.79
    span 80 25.55
    1,4-butanediol 47.59
    1,1-dichloroethane 23.0
    2-methyl-1-pentanol 37.35
    methyl formate 83.5
    2-methyl-1-butanol 52.41
    n-decane 8.56
    butyronitrile 30.46
    3,7-dimethyl-1-octanol 20.07
    1-chlorooctane 14.27
    1-chlorotetradecane 6.89
    n-nonane 8.93
    undecane 6.51
    tert-butylcyclohexane 4.08
    cyclooctane 11.06
    cyclopentanol 53.9
    tetrahydropyran 70.27
    tert-amyl methyl ether 75.7
    2,5,8-trioxanonane 85.55
    1-hexene 23.29
    2-isopropoxyethanol 73.38
    2,2,2-trifluoroethanol 30.2
    methyl butyrate 28.22

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction