(+)-Marmin

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  • Identifiers

    CAS number
    14957-38-1

    Molecular formula
    C19H24O5

    SMILES
    C/C(=C\COC1=CC2=C(C=C1)C=CC(=O)O2)/CC[C@H](C(C)(C)O)O

    Safety labels

  • Odor profile

    Fragrance
    Sweet 46.63%
    Floral 44.71%
    Fruity 32.4%
    Woody 31.88%
    Powdery 30.16%
    Vanilla 28.47%
    Balsamic 27.54%
    Creamy 25.76%
    Dry 25.23%
    Berry 23.81%

     

    Flavor
    Bitter 43.37%
    Fruity 32.39%
    Floral 31.03%
    Sweet 27.07%
    Mild 26.08%
    Herbal 25.4%
    Flower 20.54%
    Odorless 19.41%
    Woody 19.41%
    Heather 19.37%

     

    Odor impact est.
    Low

  • Properties

    XLogP3-AA
    3.0

    pKa est.
    9.36 (weak base)

    Molecular weight
    332.4 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Ultra slow

    Boiling point est.
    589°C

    Flash point

    • 209.74 ˚C est.

  • Synonyms

    • Marmin
    • 14957-38-1
    • (+)-Marmin
    • 7-(6',7'-Dihydroxygeranyloxy)coumarin
    • DTXSID001318442
    • RefChem:905474
    • DTXCID301748252
    • 7-[(E,6R)-6,7-dihydroxy-3,7-dimethyloct-2-enoxy]chromen-2-one
    • R-(+)-Marmin
    • CID 6450230
    • 2H-1-Benzopyran-2-one, 7-[[(2E,6R)-6,7-dihydroxy-3,7-dimethyl-2-octen-1-yl]oxy]-
    • HMS2198E18
    • MLS002472929
    • orb1684426
    • CHEMBL1078441
    • SCHEMBL29625637
    • QYYKWTUUCOTGNS-JIIJFUIFSA-N
    • 7-[[(2E,6R)-6,7-Dihydroxy-3,7-dimethyl-2-octen-1-yl]oxy]-2H-1-benzopyran-2-one; (+)-Marmin
    • HY-N3320
    • BDBM50490814
    • MFCD06796693
    • AKOS040760544
    • (R-(E))-7-((6,7-Dihydroxy-3,7-dimethyl-2-octenyl)oxy)-2H-1-benzopyran-2-one
    • NCGC00247454-01
    • DA-65256
    • FM157203
    • FS-10400
    • SMR001397039
    • CS-0023890
    • G88881
    • 7-[(E,6R)-6,7-dihydroxy-3,7-dimethyl-oct-2-enoxy]chromen-2-one
    • (R,E)-7-((6,7-Dihydroxy-3,7-dimethyloct-2-en-1-yl)oxy)-2H-chromen-2-one
    • 2H-1-Benzopyran-2-one, 7-((6,7-dihydroxy-3,7-dimethyl-2-octenyl)oxy)-, (R-(E))-
    • 7-[[(2E,6R)-6,7-dihydroxy-3,7-dimethyl-2-octen-1-yl]oxy]-2H-1-benzopyran-2-one
    • 7-{[(2E,6R)-6,7-Dihydroxy-3,7-dimethyloct-2-en-1-yl]oxy}-2H-1-benzopyran-2-one
    • 14957-38-1

  • Applications

    (+)-Marmin (CAS 14957-38-1) is an aroma-related chemical commonly evaluated as an odorant and fragrance ingredient. In perfumery and cosmetics, it can serve as a fragrance component in formulations for perfumes, personal care products, and lotions. It may also be used in household products such as air fresheners and cleaners to contribute a mild scent. In industrial manufacturing, it can function as an aroma intermediate or building block in the synthesis of other fragrance materials. Depending on regulatory status and formulation limits, it may be explored as a flavor/aroma component in certain applications.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 53.89
    methanol 121.99
    isopropanol 30.87
    water 0.17
    ethyl acetate 10.98
    n-propanol 39.84
    acetone 37.23
    n-butanol 31.25
    acetonitrile 13.27
    DMF 67.61
    toluene 4.56
    isobutanol 18.95
    1,4-dioxane 126.15
    methyl acetate 18.16
    THF 251.12
    2-butanone 30.84
    n-pentanol 27.73
    sec-butanol 25.69
    n-hexane 0.17
    ethylene glycol 10.17
    NMP 18.55
    cyclohexane 0.39
    DMSO 241.18
    n-butyl acetate 4.98
    n-octanol 8.4
    chloroform 12.78
    n-propyl acetate 8.67
    acetic acid 68.97
    dichloromethane 17.2
    cyclohexanone 32.95
    propylene glycol 25.73
    isopropyl acetate 7.9
    DMAc 120.92
    2-ethoxyethanol 132.4
    isopentanol 23.2
    n-heptane 0.28
    ethyl formate 11.41
    1,2-dichloroethane 10.84
    n-hexanol 9.69
    2-methoxyethanol 188.83
    isobutyl acetate 6.45
    tetrachloromethane 0.82
    n-pentyl acetate 8.16
    transcutol 325.38
    n-heptanol 8.67
    ethylbenzene 2.3
    MIBK 12.55
    2-propoxyethanol 64.5
    tert-butanol 31.43
    MTBE 13.9
    2-butoxyethanol 41.8
    propionic acid 17.7
    o-xylene 2.98
    formic acid 42.68
    diethyl ether 11.48
    m-xylene 2.82
    p-xylene 3.61
    chlorobenzene 3.67
    dimethyl carbonate 8.57
    n-octane 0.19
    formamide 67.61
    cyclopentanone 33.27
    2-pentanone 17.02
    anisole 16.05
    cyclopentyl methyl ether 18.33
    gamma-butyrolactone 29.79
    1-methoxy-2-propanol 99.73
    pyridine 38.47
    3-pentanone 9.26
    furfural 33.56
    n-dodecane 0.22
    diethylene glycol 52.0
    diisopropyl ether 1.76
    tert-amyl alcohol 22.83
    acetylacetone 29.09
    n-hexadecane 0.25
    acetophenone 14.13
    methyl propionate 10.91
    isopentyl acetate 8.21
    trichloroethylene 19.68
    n-nonanol 9.14
    cyclohexanol 16.32
    benzyl alcohol 21.81
    2-ethylhexanol 4.82
    isooctanol 7.2
    dipropyl ether 6.11
    1,2-dichlorobenzene 3.33
    ethyl lactate 9.01
    propylene carbonate 10.5
    n-methylformamide 31.44
    2-pentanol 11.44
    n-pentane 0.15
    1-propoxy-2-propanol 32.32
    1-methoxy-2-propyl acetate 15.82
    2-(2-methoxypropoxy) propanol 47.26
    mesitylene 1.64
    ε-caprolactone 24.87
    p-cymene 1.71
    epichlorohydrin 79.75
    1,1,1-trichloroethane 3.49
    2-aminoethanol 33.23
    morpholine-4-carbaldehyde 77.22
    sulfolane 36.83
    2,2,4-trimethylpentane 0.2
    2-methyltetrahydrofuran 41.65
    n-hexyl acetate 12.05
    isooctane 0.12
    2-(2-butoxyethoxy)ethanol 77.41
    sec-butyl acetate 5.9
    tert-butyl acetate 12.77
    decalin 0.26
    glycerin 40.64
    diglyme 155.55
    acrylic acid 17.88
    isopropyl myristate 4.89
    n-butyric acid 24.22
    acetyl acetate 8.19
    di(2-ethylhexyl) phthalate 8.08
    ethyl propionate 6.16
    nitromethane 74.9
    1,2-diethoxyethane 39.46
    benzonitrile 9.67
    trioctyl phosphate 4.48
    1-bromopropane 3.3
    gamma-valerolactone 88.95
    n-decanol 6.1
    triethyl phosphate 5.14
    4-methyl-2-pentanol 6.91
    propionitrile 9.05
    vinylene carbonate 11.05
    1,1,2-trichlorotrifluoroethane 43.66
    DMS 9.02
    cumene 1.7
    2-octanol 4.58
    2-hexanone 15.0
    octyl acetate 6.81
    limonene 1.96
    1,2-dimethoxyethane 171.71
    ethyl orthosilicate 6.08
    tributyl phosphate 5.27
    diacetone alcohol 32.66
    N,N-dimethylaniline 10.98
    acrylonitrile 13.43
    aniline 12.08
    1,3-propanediol 65.07
    bromobenzene 2.62
    dibromomethane 6.22
    1,1,2,2-tetrachloroethane 18.36
    2-methyl-cyclohexyl acetate 8.88
    tetrabutyl urea 9.32
    diisobutyl methanol 3.5
    2-phenylethanol 13.83
    styrene 2.89
    dioctyl adipate 10.59
    dimethyl sulfate 11.9
    ethyl butyrate 5.47
    methyl lactate 14.02
    butyl lactate 10.95
    diethyl carbonate 4.05
    propanediol butyl ether 38.58
    triethyl orthoformate 8.36
    p-tert-butyltoluene 1.67
    methyl 4-tert-butylbenzoate 17.38
    morpholine 158.24
    tert-butylamine 8.2
    n-dodecanol 4.16
    dimethoxymethane 87.7
    ethylene carbonate 9.52
    cyrene 33.7
    2-ethoxyethyl acetate 21.62
    2-ethylhexyl acetate 5.33
    1,2,4-trichlorobenzene 5.36
    4-methylpyridine 20.69
    dibutyl ether 9.04
    2,6-dimethyl-4-heptanol 3.5
    DEF 21.49
    dimethyl isosorbide 53.85
    tetrachloroethylene 9.9
    eugenol 22.97
    triacetin 21.1
    span 80 29.82
    1,4-butanediol 24.96
    1,1-dichloroethane 4.86
    2-methyl-1-pentanol 21.41
    methyl formate 22.74
    2-methyl-1-butanol 19.9
    n-decane 0.42
    butyronitrile 11.08
    3,7-dimethyl-1-octanol 7.36
    1-chlorooctane 2.22
    1-chlorotetradecane 0.87
    n-nonane 0.31
    undecane 0.29
    tert-butylcyclohexane 0.23
    cyclooctane 0.15
    cyclopentanol 18.8
    tetrahydropyran 51.53
    tert-amyl methyl ether 10.05
    2,5,8-trioxanonane 103.19
    1-hexene 1.12
    2-isopropoxyethanol 57.24
    2,2,2-trifluoroethanol 11.65
    methyl butyrate 10.44

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction