Hexahydro-4,7-methano-1H-indenyl acrylate

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  • Identifiers

    CAS number
    12542-30-2

    Molecular formula
    C13H16O2

    SMILES
    C=CC(=O)OC1C=CC2C1C3CCC2C3

    Safety labels

    Irritant
    Irritant

    Environmental Hazard
    Environmental

  • Odor profile

    Fragrance
    Green 78.08%
    Fruity 60.1%
    Woody 57.81%
    Herbal 46.18%
    Balsamic 31.14%
    Fresh 30.5%
    Oily 29.47%
    Spicy 28.16%
    Sweet 22.32%
    Jasmin 21.27%

     

    Flavor
    Bitter 65.87%
    Odorless 25.7%
    Cedarleaf 20.0%
    Nitrile 19.97%
    Sweet-like 19.82%
    Lovage 19.5%
    Shrimp 19.32%
    Alkaline 19.1%
    Oriental 18.98%
    Basil 18.93%

     

    Odor impact est.
    Medium

  • Properties

    XLogP3-AA
    3.2

    pKa est.
    6.86 (neutral)

    Molecular weight
    204.26 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Slow

    Boiling point est.
    258°C

    Flash point

    • 114.58 ˚C est.

  • Synonyms

    • Hexahydro-4,7-methano-1H-indenyl acrylate
    • EINECS 235-697-2
    • EC 235-697-2
    • 2-Propenoic acid, 3a,4,7,7a,?,?-hexahydro-4,7-methano-1H-indenyl ester
    • RefChem:786146
    • 235-697-2
    • Dihydrodicyclopentadienyl acrylate
    • 12542-30-2
    • 3-tricyclo[5.2.1.02,6]dec-4-enyl prop-2-enoate
    • SCHEMBL362397
    • NS00006083
    • 12542-30-2

  • Applications

    Hexahydro-4,7-methano-1H-indenyl acrylate is regarded as a reactive acrylate monomer suitable for radical polymerization, enabling the synthesis of specialty polymers with high rigidity and thermal stability. In practice, it finds use in UV-curable coatings and inks, in high-performance adhesives, and as a monomer component in polymers for electronics and optics (for example materials for photoresists and encapsulants). It is also evaluated for UV-curable resin systems and 3D-printing resins, and may appear in the industrial production of advanced polymers and materials, depending on local regulations and formulation limits.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 563.01
    methanol 676.93
    isopropanol 550.07
    water 0.6
    ethyl acetate 874.37
    n-propanol 514.19
    acetone 833.91
    n-butanol 574.99
    acetonitrile 489.44
    DMF 726.08
    toluene 674.05
    isobutanol 425.54
    1,4-dioxane 1299.4
    methyl acetate 624.82
    THF 1630.36
    2-butanone 758.01
    n-pentanol 284.36
    sec-butanol 408.11
    n-hexane 23.79
    ethylene glycol 80.11
    NMP 401.06
    cyclohexane 87.52
    DMSO 549.91
    n-butyl acetate 488.89
    n-octanol 105.41
    chloroform 1957.58
    n-propyl acetate 391.49
    acetic acid 438.24
    dichloromethane 1534.1
    cyclohexanone 881.85
    propylene glycol 132.26
    isopropyl acetate 655.76
    DMAc 507.14
    2-ethoxyethanol 421.65
    isopentanol 574.06
    n-heptane 13.99
    ethyl formate 399.76
    1,2-dichloroethane 901.05
    n-hexanol 335.41
    2-methoxyethanol 797.71
    isobutyl acetate 299.23
    tetrachloromethane 169.85
    n-pentyl acetate 216.16
    transcutol 2061.01
    n-heptanol 114.72
    ethylbenzene 207.77
    MIBK 538.31
    2-propoxyethanol 618.77
    tert-butanol 502.0
    MTBE 665.27
    2-butoxyethanol 278.23
    propionic acid 300.59
    o-xylene 266.47
    formic acid 144.82
    diethyl ether 875.02
    m-xylene 393.97
    p-xylene 255.14
    chlorobenzene 598.37
    dimethyl carbonate 289.44
    n-octane 8.07
    formamide 259.67
    cyclopentanone 864.19
    2-pentanone 749.83
    anisole 436.3
    cyclopentyl methyl ether 689.24
    gamma-butyrolactone 818.81
    1-methoxy-2-propanol 726.28
    pyridine 945.51
    3-pentanone 465.97
    furfural 680.22
    n-dodecane 10.07
    diethylene glycol 464.88
    diisopropyl ether 259.3
    tert-amyl alcohol 356.21
    acetylacetone 722.5
    n-hexadecane 12.02
    acetophenone 363.03
    methyl propionate 543.23
    isopentyl acetate 490.03
    trichloroethylene 1651.29
    n-nonanol 100.1
    cyclohexanol 458.2
    benzyl alcohol 336.3
    2-ethylhexanol 164.52
    isooctanol 108.12
    dipropyl ether 180.26
    1,2-dichlorobenzene 446.54
    ethyl lactate 172.32
    propylene carbonate 530.12
    n-methylformamide 382.31
    2-pentanol 397.91
    n-pentane 39.86
    1-propoxy-2-propanol 380.23
    1-methoxy-2-propyl acetate 546.83
    2-(2-methoxypropoxy) propanol 298.01
    mesitylene 222.87
    ε-caprolactone 663.45
    p-cymene 101.94
    epichlorohydrin 1175.41
    1,1,1-trichloroethane 728.91
    2-aminoethanol 194.71
    morpholine-4-carbaldehyde 638.38
    sulfolane 564.12
    2,2,4-trimethylpentane 31.82
    2-methyltetrahydrofuran 1030.39
    n-hexyl acetate 298.7
    isooctane 34.54
    2-(2-butoxyethoxy)ethanol 454.05
    sec-butyl acetate 335.91
    tert-butyl acetate 540.43
    decalin 41.78
    glycerin 194.43
    diglyme 756.65
    acrylic acid 249.93
    isopropyl myristate 114.19
    n-butyric acid 638.47
    acetyl acetate 462.22
    di(2-ethylhexyl) phthalate 119.8
    ethyl propionate 319.11
    nitromethane 654.1
    1,2-diethoxyethane 600.79
    benzonitrile 451.33
    trioctyl phosphate 78.28
    1-bromopropane 528.61
    gamma-valerolactone 979.26
    n-decanol 76.41
    triethyl phosphate 117.27
    4-methyl-2-pentanol 276.5
    propionitrile 445.57
    vinylene carbonate 515.08
    1,1,2-trichlorotrifluoroethane 580.69
    DMS 345.85
    cumene 137.78
    2-octanol 83.39
    2-hexanone 355.72
    octyl acetate 132.28
    limonene 128.72
    1,2-dimethoxyethane 722.76
    ethyl orthosilicate 119.58
    tributyl phosphate 108.08
    diacetone alcohol 470.22
    N,N-dimethylaniline 236.14
    acrylonitrile 475.08
    aniline 565.48
    1,3-propanediol 404.04
    bromobenzene 664.68
    dibromomethane 966.42
    1,1,2,2-tetrachloroethane 1243.29
    2-methyl-cyclohexyl acetate 209.6
    tetrabutyl urea 117.45
    diisobutyl methanol 126.3
    2-phenylethanol 330.61
    styrene 284.47
    dioctyl adipate 151.83
    dimethyl sulfate 248.48
    ethyl butyrate 280.59
    methyl lactate 242.68
    butyl lactate 185.79
    diethyl carbonate 199.09
    propanediol butyl ether 264.32
    triethyl orthoformate 191.82
    p-tert-butyltoluene 100.1
    methyl 4-tert-butylbenzoate 226.24
    morpholine 1258.8
    tert-butylamine 314.16
    n-dodecanol 60.85
    dimethoxymethane 802.62
    ethylene carbonate 475.11
    cyrene 235.45
    2-ethoxyethyl acetate 399.32
    2-ethylhexyl acetate 337.53
    1,2,4-trichlorobenzene 492.49
    4-methylpyridine 936.42
    dibutyl ether 170.32
    2,6-dimethyl-4-heptanol 126.3
    DEF 524.37
    dimethyl isosorbide 424.15
    tetrachloroethylene 735.72
    eugenol 234.18
    triacetin 295.2
    span 80 222.58
    1,4-butanediol 124.46
    1,1-dichloroethane 999.61
    2-methyl-1-pentanol 304.22
    methyl formate 312.71
    2-methyl-1-butanol 436.77
    n-decane 14.45
    butyronitrile 546.21
    3,7-dimethyl-1-octanol 153.22
    1-chlorooctane 80.15
    1-chlorotetradecane 36.27
    n-nonane 11.94
    undecane 11.78
    tert-butylcyclohexane 36.78
    cyclooctane 29.98
    cyclopentanol 391.56
    tetrahydropyran 1312.71
    tert-amyl methyl ether 361.37
    2,5,8-trioxanonane 477.0
    1-hexene 134.54
    2-isopropoxyethanol 316.17
    2,2,2-trifluoroethanol 178.49
    methyl butyrate 425.51

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction