Glyceryl Allyl Ether

Overview IFRA Request a quote

  • Identifiers

    CAS number
    123-34-2

    Molecular formula
    C6H12O3

    SMILES
    C=CCOCC(CO)O

    Safety labels

    Irritant
    Irritant

  • Odor profile

    Fragrance
    Fruity 38.06%
    Ethereal 33.57%
    Odorless 29.61%
    Pungent 26.2%
    Fresh 25.6%
    Alcoholic 23.58%
    Sweet 23.48%
    Sharp 23.3%
    Mushroom 21.91%
    Green 20.6%

     

    Flavor
    Odorless 45.61%
    Sweet 41.67%
    Musty 25.91%
    Sweet-like 25.08%
    Pungent 24.67%
    Bitter 24.11%
    Very slight 24.07%
    Buttery 22.03%
    Creamy 22.0%
    Cauliflower 21.46%

     

    Odor impact est.
    Medium

  • Properties

    XLogP3-AA
    -0.6

    pKa est.
    6.87 (neutral)

    Molecular weight
    132.16 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Very slow

    Boiling point est.
    243°C

    Flash point

    • 117.01 ˚C est.

  • Synonyms

    • 3-Allyloxy-1,2-propanediol
    • 123-34-2
    • 3-(Allyloxy)propane-1,2-diol
    • Glycerol 1-allylether
    • glyceryl allyl ether
    • 3-(Allyloxy)-1,2-propanediol
    • Glycerol alpha-monoallyl ether
    • Ether, allyl glyceryl
    • Glycerin 1-allyl ether
    • 3-(Allyloxy)propanediol
    • 1,2-Propanediol, 3-(2-propen-1-yloxy)-
    • 3-(2-Propenyloxy)-1,2-propanediol
    • 1-Allyloxy-2,3-propanediol
    • Glycerol alpha-allyl ether
    • 1,2-Propanediol, 3-(2-propenyloxy)-
    • Glycerol 1-allyl ether
    • alpha-Allyl glycerol ether
    • NSC 59722
    • Glycerol .alpha.-monoallyl ether
    • Glycerol 1-monoallyl ether
    • EINECS 204-620-4
    • BRN 1701144
    • 085RW4Y3PU
    • 1,2-Propanediol, 3-allyloxy-
    • DTXSID4044375
    • AI3-26697
    • 1,2-Propanediol, 3-(allyloxy)-
    • NSC-59722
    • 1-(ALLYLOXY)-2,3-PROPANEDIOL
    • DTXCID2024375
    • 4-01-00-02759 (Beilstein Handbook Reference)
    • GLYCERYL-.ALPHA.-MONOALLYLETHER
    • 1-ALLYLOXY-2,3-DIHYDROXYPROPANE
    • RefChem:663509
    • (+-)-GLYCERYL ALLYL ETHER
    • GLYCERYL ALLYL ETHER [INCI]
    • GLYCERYL-ALPHA-MONOALLYLETHER
    • GLYCERYL ALLYL ETHER, (+-)-
    • 3-prop-2-enoxypropane-1,2-diol
    • Glycerol-1-allyl ether
    • 3-allyloxypropane-1,2-diol
    • MFCD00004721
    • 3-Allyloxy-1,2 propanediol
    • 3-(prop-2-en-1-yloxy)propane-1,2-diol
    • UNII-085RW4Y3PU
    • 1-allylglycerin
    • 1, 3-(allyloxy)-
    • Allyl-alpha-glyceryl ether
    • Glycerol a-monoallyl ether
    • 3-allyloxy-1,2propanediol
    • 1, 3-(2-propenyloxy)-
    • SCHEMBL30534
    • .alpha.-Allyl glycerol ether
    • Allyl-.alpha.-glyceryl ether
    • Glycerol .alpha.-allyl ether
    • Glycerol-.alpha.-allyl ether
    • WLN: Q1YQ1O2U1
    • SCHEMBL9231667
    • CHEMBL3182656
    • 3-allyloxy-1,2-dihydroxypropane
    • PAKCOSURAUIXFG-UHFFFAOYSA-
    • NSC59722
    • Tox21_302125
    • (+/-)-GLYCERYL ALLYL ETHER
    • 3-Allyloxy-1 pound not2-propanediol
    • 3-Allyloxy-1,2-propanediol, 99%
    • AKOS015916380
    • SB44822
    • SB83910
    • GLYCERYL ALLYL ETHER, (+/-)-
    • NCGC00255725-01
    • 1394949-67-7
    • AS-63581
    • CAS-123-34-2
    • SY051624
    • CS-0130745
    • G0189
    • NS00021575
    • 3-[(Prop-2-en-1-yl)oxy]propane-1,2-diol
    • E78805
    • A890791
    • Q27236374
    • InChI=1/C6H12O3/c1-2-3-9-5-6(8)4-7/h2,6-8H,1,3-5H2
    • 123-34-2

  • Applications

    Glyceryl Allyl Ether (CAS 123-34-2) is primarily used as a reactive monomer and intermediate in polymer and coating chemistries. In industrial manufacturing, it can be employed as a crosslinking agent or reactive diluent in UV- and radical-cured coatings, inks, and adhesives, enabling network formation and formulation rheology control. It also serves as a precursor for glycerol-based specialty chemicals and polyol/polyether resins. Additionally, it may function as a processing aid or plasticizer in polymer formulations and can act as a solvent or co-solvent in certain formulation blends.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 782.43
    methanol 2120.29
    isopropanol 308.93
    water 410.42
    ethyl acetate 40.58
    n-propanol 408.35
    acetone 138.3
    n-butanol 280.23
    acetonitrile 102.85
    DMF 970.87
    toluene 5.48
    isobutanol 205.25
    1,4-dioxane 210.67
    methyl acetate 62.12
    THF 235.45
    2-butanone 63.24
    n-pentanol 128.27
    sec-butanol 192.14
    n-hexane 2.74
    ethylene glycol 916.31
    NMP 433.75
    cyclohexane 11.13
    DMSO 1400.94
    n-butyl acetate 43.28
    n-octanol 36.83
    chloroform 35.38
    n-propyl acetate 40.81
    acetic acid 1107.59
    dichloromethane 53.01
    cyclohexanone 122.69
    propylene glycol 570.88
    isopropyl acetate 20.19
    DMAc 442.45
    2-ethoxyethanol 430.7
    isopentanol 139.31
    n-heptane 7.63
    ethyl formate 112.46
    1,2-dichloroethane 39.91
    n-hexanol 101.8
    2-methoxyethanol 1007.48
    isobutyl acetate 21.22
    tetrachloromethane 9.47
    n-pentyl acetate 20.26
    transcutol 466.88
    n-heptanol 41.96
    ethylbenzene 4.85
    MIBK 25.82
    2-propoxyethanol 257.43
    tert-butanol 249.98
    MTBE 43.82
    2-butoxyethanol 121.82
    propionic acid 356.01
    o-xylene 9.64
    formic acid 1431.69
    diethyl ether 33.8
    m-xylene 7.13
    p-xylene 7.14
    chlorobenzene 11.65
    dimethyl carbonate 37.47
    n-octane 2.28
    formamide 1115.24
    cyclopentanone 152.34
    2-pentanone 44.85
    anisole 28.09
    cyclopentyl methyl ether 66.7
    gamma-butyrolactone 206.54
    1-methoxy-2-propanol 404.17
    pyridine 71.5
    3-pentanone 28.45
    furfural 240.64
    n-dodecane 1.91
    diethylene glycol 445.88
    diisopropyl ether 8.97
    tert-amyl alcohol 165.94
    acetylacetone 53.11
    n-hexadecane 2.0
    acetophenone 39.97
    methyl propionate 58.02
    isopentyl acetate 34.17
    trichloroethylene 63.67
    n-nonanol 30.23
    cyclohexanol 166.22
    benzyl alcohol 63.92
    2-ethylhexanol 45.36
    isooctanol 30.86
    dipropyl ether 35.5
    1,2-dichlorobenzene 14.75
    ethyl lactate 68.68
    propylene carbonate 96.63
    n-methylformamide 654.09
    2-pentanol 89.65
    n-pentane 4.82
    1-propoxy-2-propanol 155.82
    1-methoxy-2-propyl acetate 55.48
    2-(2-methoxypropoxy) propanol 105.52
    mesitylene 7.36
    ε-caprolactone 118.58
    p-cymene 9.9
    epichlorohydrin 146.29
    1,1,1-trichloroethane 14.72
    2-aminoethanol 961.41
    morpholine-4-carbaldehyde 428.79
    sulfolane 352.48
    2,2,4-trimethylpentane 3.98
    2-methyltetrahydrofuran 107.01
    n-hexyl acetate 34.15
    isooctane 2.43
    2-(2-butoxyethoxy)ethanol 152.21
    sec-butyl acetate 19.62
    tert-butyl acetate 26.55
    decalin 3.93
    glycerin 832.01
    diglyme 276.38
    acrylic acid 381.86
    isopropyl myristate 13.44
    n-butyric acid 292.06
    acetyl acetate 29.24
    di(2-ethylhexyl) phthalate 26.77
    ethyl propionate 28.24
    nitromethane 646.64
    1,2-diethoxyethane 56.6
    benzonitrile 35.48
    trioctyl phosphate 22.02
    1-bromopropane 16.0
    gamma-valerolactone 262.02
    n-decanol 22.11
    triethyl phosphate 27.5
    4-methyl-2-pentanol 36.07
    propionitrile 66.13
    vinylene carbonate 95.94
    1,1,2-trichlorotrifluoroethane 287.39
    DMS 30.95
    cumene 6.05
    2-octanol 19.51
    2-hexanone 32.95
    octyl acetate 21.34
    limonene 18.61
    1,2-dimethoxyethane 306.79
    ethyl orthosilicate 26.6
    tributyl phosphate 24.07
    diacetone alcohol 93.87
    N,N-dimethylaniline 29.73
    acrylonitrile 114.35
    aniline 44.24
    1,3-propanediol 830.5
    bromobenzene 6.94
    dibromomethane 29.66
    1,1,2,2-tetrachloroethane 54.2
    2-methyl-cyclohexyl acetate 35.45
    tetrabutyl urea 38.83
    diisobutyl methanol 25.29
    2-phenylethanol 49.37
    styrene 6.51
    dioctyl adipate 33.28
    dimethyl sulfate 91.39
    ethyl butyrate 38.95
    methyl lactate 117.57
    butyl lactate 47.36
    diethyl carbonate 26.99
    propanediol butyl ether 148.87
    triethyl orthoformate 36.51
    p-tert-butyltoluene 10.21
    methyl 4-tert-butylbenzoate 47.44
    morpholine 363.84
    tert-butylamine 101.48
    n-dodecanol 17.31
    dimethoxymethane 208.33
    ethylene carbonate 76.58
    cyrene 130.45
    2-ethoxyethyl acetate 34.56
    2-ethylhexyl acetate 23.46
    1,2,4-trichlorobenzene 21.09
    4-methylpyridine 45.31
    dibutyl ether 19.94
    2,6-dimethyl-4-heptanol 25.29
    DEF 149.9
    dimethyl isosorbide 127.24
    tetrachloroethylene 49.24
    eugenol 64.57
    triacetin 53.2
    span 80 99.42
    1,4-butanediol 359.07
    1,1-dichloroethane 17.87
    2-methyl-1-pentanol 76.63
    methyl formate 336.68
    2-methyl-1-butanol 153.95
    n-decane 2.67
    butyronitrile 65.67
    3,7-dimethyl-1-octanol 34.55
    1-chlorooctane 8.51
    1-chlorotetradecane 4.32
    n-nonane 2.59
    undecane 2.16
    tert-butylcyclohexane 3.25
    cyclooctane 3.91
    cyclopentanol 214.29
    tetrahydropyran 102.86
    tert-amyl methyl ether 38.23
    2,5,8-trioxanonane 202.38
    1-hexene 7.58
    2-isopropoxyethanol 173.81
    2,2,2-trifluoroethanol 323.71
    methyl butyrate 57.16

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction