Fluorescent brightener 367

Overview IFRA Request a quote

  • Identifiers

    CAS number
    5089-22-5

    Molecular formula
    C24H14N2O2

    SMILES
    C1=CC=C2C(=C1)C(=CC=C2C3=NC4=CC=CC=C4O3)C5=NC6=CC=CC=C6O5

    Safety labels

  • Odor profile

    Fragrance
    Floral 67.69%
    Fruity 51.28%
    Animal 43.28%
    Burnt 33.35%
    Pungent 30.83%
    Neroli 30.57%
    Earthy 29.52%
    Grape 28.57%
    Musty 28.0%
    Orange 26.65%

     

    Flavor
    Bitter 93.13%
    Very strong 20.69%
    Indole 20.27%
    Moth ball 19.49%
    Naphthelene 18.91%
    Cereal 18.82%
    Animal 17.96%
    Nitrile 17.94%
    Scallion 17.64%
    Rotten 17.43%

     

    Odor impact est.
    Low

  • Properties

    XLogP3-AA
    6.2

    pKa est.
    5.58 (weak acid)

    Molecular weight
    362.4 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Ultra slow

    Boiling point est.
    946°C

    Flash point

    • 268.45 ˚C est.

  • Synonyms

    • 5089-22-5
    • Fluorescent Brightener 367
    • 1,4-Bis(2-benzoxazolyl)naphthalene
    • Benzoxazole, 2,2'-(1,4-naphthalenediyl)bis-
    • Z945S0K4ZW
    • HOSTALUX KCB
    • 2,2'-(Naphthalene-1,4-diyl)bis(benzoxazole)
    • EINECS 225-803-5
    • LUMISIS B-1400
    • DTXSID6063698
    • 1,4-DI(2-BENZOXAZOLYL)NAPHTHALENE
    • BENZOXAZOLE, 2,2'-(1,4-NAPHTHYLENE)BIS-
    • RefChem:599386
    • DTXCID4040929
    • FLUORESCENT BRIGHTENER 367 [INCI]
    • 1,4-Bis(benzo[d]oxazol-2-yl)naphthalene
    • Fluorescent whitening agent KCB
    • 63310-10-1
    • 1,4-bis-Benzoxazolyl-naphthalene
    • C24H14N2O2
    • 1,4-Bis(benzoxazolyl-2-yl)naphthalene
    • MFCD00357168
    • 2-[4-(1,3-benzoxazol-2-yl)naphthalen-1-yl]-1,3-benzoxazole
    • F0909-0011
    • 2-[4-(1,3-benzoxazol-2-yl)-1-naphthyl]-1,3-benzoxazole
    • Fluorescent brightener-KCB
    • UNII-Z945S0K4ZW
    • C.I. Fluorescent Brightener 367
    • Oprea1_504830
    • SCHEMBL30682
    • CBDivE_007888
    • DIBENZOXAZOYL NAPHTHALENE
    • SCHEMBL29627559
    • SCHEMBL30096340
    • SMSSF-0613173
    • STK396696
    • 1,4-bis(2-benzoxazolyl) naphthalene
    • AKOS003614359
    • 1,4-Bis-(benzoxazol-2-yl)naphthalene
    • CS-W009783
    • FB40758
    • MSK163195-1000D
    • 1,4-Di(benzo[d]oxazol-2-yl)naphthalene
    • 2-(4-benzoxazol-2-ylnaphthyl)benzoxazole
    • AC-10393
    • AS-15983
    • B2728
    • NS00013564
    • ST50874339
    • 1,4-BIS-(2-BENZOXAZOLYL)-NAPHTHALENE
    • H10717
    • 2,2'-naphthalene-1,4-diylbis(1,3-benzoxazole)
    • A917575
    • F235754
    • 2,2'-(Naphthalene-1,4-diyl)bis(1,3-benzoxazole)
    • Q27295166
    • Fluorescent brightener 367 Solution in DMSO, 1000ug/mL
    • 1,4-BIS(BENZOXAZOLYL-2-YL)NAPHTHALENE;FLUORESCENT BRIGHTENER 367
    • 5089-22-5

  • Applications

    Fluorescent brightener 367 (CAS 5089-22-5) is a fluorescent whitening agent that brightens substrates by absorbing ultraviolet light and emitting blue light. Common applications include: (1) incorporation into plastics and polymer systems to improve product whiteness; (2) use in paper and coated papers to boost optical brightness; (3) addition to coatings and inks to enhance surface whiteness; (4) treatment of textiles to improve fabric whiteness; (5) inclusion in detergent and household cleaning formulations to increase brightness. Its use depends on formulation and substrate compatibility and is typically subject to local regulations and formulation limits.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 0.09
    methanol 0.07
    isopropanol 0.04
    water 0.0
    ethyl acetate 0.33
    n-propanol 0.1
    acetone 0.23
    n-butanol 0.14
    acetonitrile 0.07
    DMF 0.3
    toluene 0.32
    isobutanol 0.07
    1,4-dioxane 0.78
    methyl acetate 0.25
    THF 3.32
    2-butanone 0.43
    n-pentanol 0.19
    sec-butanol 0.1
    n-hexane 0.03
    ethylene glycol 0.02
    NMP 0.35
    cyclohexane 0.02
    DMSO 0.64
    n-butyl acetate 0.53
    n-octanol 0.3
    chloroform 1.89
    n-propyl acetate 0.37
    acetic acid 0.21
    dichloromethane 3.53
    cyclohexanone 0.63
    propylene glycol 0.03
    isopropyl acetate 0.39
    DMAc 1.02
    2-ethoxyethanol 0.51
    isopentanol 0.2
    n-heptane 0.05
    ethyl formate 0.25
    1,2-dichloroethane 1.16
    n-hexanol 0.22
    2-methoxyethanol 0.47
    isobutyl acetate 0.34
    tetrachloromethane 0.08
    n-pentyl acetate 1.1
    transcutol 3.41
    n-heptanol 0.31
    ethylbenzene 0.36
    MIBK 0.51
    2-propoxyethanol 0.84
    tert-butanol 0.06
    MTBE 0.2
    2-butoxyethanol 1.04
    propionic acid 0.14
    o-xylene 0.19
    formic acid 0.1
    diethyl ether 0.31
    m-xylene 0.2
    p-xylene 0.3
    chlorobenzene 0.24
    dimethyl carbonate 0.24
    n-octane 0.05
    formamide 0.17
    cyclopentanone 0.92
    2-pentanone 0.46
    anisole 0.73
    cyclopentyl methyl ether 0.51
    gamma-butyrolactone 0.84
    1-methoxy-2-propanol 0.38
    pyridine 1.26
    3-pentanone 0.35
    furfural 1.15
    n-dodecane 0.05
    diethylene glycol 0.36
    diisopropyl ether 0.13
    tert-amyl alcohol 0.14
    acetylacetone 0.79
    n-hexadecane 0.07
    acetophenone 0.71
    methyl propionate 0.28
    isopentyl acetate 0.8
    trichloroethylene 2.78
    n-nonanol 0.43
    cyclohexanol 0.13
    benzyl alcohol 0.43
    2-ethylhexanol 0.32
    isooctanol 0.36
    dipropyl ether 0.56
    1,2-dichlorobenzene 0.39
    ethyl lactate 0.28
    propylene carbonate 0.47
    n-methylformamide 0.13
    2-pentanol 0.12
    n-pentane 0.02
    1-propoxy-2-propanol 0.65
    1-methoxy-2-propyl acetate 0.96
    2-(2-methoxypropoxy) propanol 1.84
    mesitylene 0.12
    ε-caprolactone 0.74
    p-cymene 0.31
    epichlorohydrin 2.61
    1,1,1-trichloroethane 0.32
    2-aminoethanol 0.05
    morpholine-4-carbaldehyde 0.84
    sulfolane 1.16
    2,2,4-trimethylpentane 0.03
    2-methyltetrahydrofuran 0.88
    n-hexyl acetate 1.1
    isooctane 0.02
    2-(2-butoxyethoxy)ethanol 2.02
    sec-butyl acetate 0.43
    tert-butyl acetate 0.51
    decalin 0.04
    glycerin 0.1
    diglyme 3.76
    acrylic acid 0.17
    isopropyl myristate 0.82
    n-butyric acid 0.32
    acetyl acetate 0.28
    di(2-ethylhexyl) phthalate 0.9
    ethyl propionate 0.42
    nitromethane 0.35
    1,2-diethoxyethane 1.86
    benzonitrile 0.33
    trioctyl phosphate 0.49
    1-bromopropane 0.6
    gamma-valerolactone 1.53
    n-decanol 0.34
    triethyl phosphate 0.56
    4-methyl-2-pentanol 0.16
    propionitrile 0.13
    vinylene carbonate 0.47
    1,1,2-trichlorotrifluoroethane 1.18
    DMS 0.73
    cumene 0.29
    2-octanol 0.27
    2-hexanone 0.55
    octyl acetate 0.78
    limonene 0.28
    1,2-dimethoxyethane 1.41
    ethyl orthosilicate 0.66
    tributyl phosphate 0.59
    diacetone alcohol 0.62
    N,N-dimethylaniline 0.64
    acrylonitrile 0.2
    aniline 0.24
    1,3-propanediol 0.13
    bromobenzene 0.36
    dibromomethane 1.5
    1,1,2,2-tetrachloroethane 1.72
    2-methyl-cyclohexyl acetate 0.81
    tetrabutyl urea 1.1
    diisobutyl methanol 0.28
    2-phenylethanol 0.63
    styrene 0.3
    dioctyl adipate 1.36
    dimethyl sulfate 0.39
    ethyl butyrate 0.67
    methyl lactate 0.25
    butyl lactate 0.87
    diethyl carbonate 0.48
    propanediol butyl ether 0.61
    triethyl orthoformate 0.82
    p-tert-butyltoluene 0.27
    methyl 4-tert-butylbenzoate 1.6
    morpholine 0.63
    tert-butylamine 0.04
    n-dodecanol 0.27
    dimethoxymethane 0.61
    ethylene carbonate 0.32
    cyrene 1.05
    2-ethoxyethyl acetate 1.81
    2-ethylhexyl acetate 0.73
    1,2,4-trichlorobenzene 0.56
    4-methylpyridine 0.51
    dibutyl ether 1.03
    2,6-dimethyl-4-heptanol 0.28
    DEF 0.51
    dimethyl isosorbide 3.06
    tetrachloroethylene 0.99
    eugenol 1.78
    triacetin 1.21
    span 80 1.3
    1,4-butanediol 0.06
    1,1-dichloroethane 0.32
    2-methyl-1-pentanol 0.36
    methyl formate 0.15
    2-methyl-1-butanol 0.19
    n-decane 0.1
    butyronitrile 0.18
    3,7-dimethyl-1-octanol 0.43
    1-chlorooctane 0.4
    1-chlorotetradecane 0.2
    n-nonane 0.07
    undecane 0.07
    tert-butylcyclohexane 0.04
    cyclooctane 0.02
    cyclopentanol 0.12
    tetrahydropyran 0.56
    tert-amyl methyl ether 0.35
    2,5,8-trioxanonane 3.32
    1-hexene 0.14
    2-isopropoxyethanol 0.44
    2,2,2-trifluoroethanol 0.08
    methyl butyrate 0.5

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction