(E)-2-(3-Hexenyloxy)-1,3-dioxolane

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  • Identifiers

    CAS number
    93919-13-2

    Molecular formula
    C9H16O3

    SMILES
    CC/C=C/CCOC1OCCO1

    Safety labels

  • Odor profile

    Fragrance
    Green 90.39%
    Fresh 57.95%
    Fruity 50.94%
    Sweet 47.44%
    Leafy 45.96%
    Apple 43.95%
    Vegetable 42.94%
    Herbal 41.39%
    Melon 39.32%
    Tropical 36.63%

     

    Flavor
    Green 49.13%
    Tropical 36.47%
    Fatty 31.96%
    Fruity 31.47%
    Oily 30.81%
    Waxy 28.66%
    Fresh 28.61%
    Vegetable 27.82%
    Metallic 26.85%
    Floral 25.56%

     

    Odor impact est.
    High

  • Properties

    XLogP3-AA
    1.6

    pKa est.
    7.06 (neutral)

    Molecular weight
    172.22 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Moderately slow

    Boiling point est.
    227°C

    Flash point

    • 87.03 ˚C est.

  • Synonyms

    • (E)-2-(3-Hexenyloxy)-1,3-dioxolane
    • 93919-13-2
    • EINECS 299-997-5
    • OEGZLVQKMGBRDZ-ONEGZZNKSA-N
    • DTXSID501283840
    • NS00065200
    • 1,3-Dioxolane, 2-(3-hexenyloxy)-, (E)-
    • 2-{[(3E)-Hex-3-en-1-yl]oxy}-1,3-dioxolane
    • 93919-13-2

  • Applications

    (E)-2-(3-Hexenyloxy)-1,3-dioxolane (CAS 93919-13-2) is used as a synthetic intermediate in organic synthesis, owing to its protected carbonyl-like 1,3-dioxolane ring and its vinyl-containing 3-hexenyl side chain that enables polymerization or crosslinking. It can be employed as a monomer or comonomer in specialty polymers and plastics, and as a reactive diluent or processing additive in coatings and UV-curable inks or adhesives. In perfumery and cosmetics, the compound may serve as a fragrance ingredient or aroma chemical with green, fresh notes. It may also find utility as an additive in industrial formulations, subject to local regulations and formulation limits.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 1686.53
    methanol 1798.78
    isopropanol 1098.4
    water 1.4
    ethyl acetate 1289.92
    n-propanol 1102.74
    acetone 1588.87
    n-butanol 1061.65
    acetonitrile 1311.95
    DMF 1139.04
    toluene 530.49
    isobutanol 846.55
    1,4-dioxane 1409.19
    methyl acetate 910.56
    THF 1815.74
    2-butanone 1029.35
    n-pentanol 768.34
    sec-butanol 925.0
    n-hexane 193.82
    ethylene glycol 310.39
    NMP 966.8
    cyclohexane 286.14
    DMSO 2406.2
    n-butyl acetate 872.33
    n-octanol 343.58
    chloroform 3514.38
    n-propyl acetate 797.1
    acetic acid 2117.51
    dichloromethane 3393.02
    cyclohexanone 1279.34
    propylene glycol 377.76
    isopropyl acetate 829.82
    DMAc 1020.11
    2-ethoxyethanol 1076.97
    isopentanol 969.63
    n-heptane 101.84
    ethyl formate 606.92
    1,2-dichloroethane 1932.32
    n-hexanol 656.62
    2-methoxyethanol 1432.73
    isobutyl acetate 534.07
    tetrachloromethane 517.44
    n-pentyl acetate 506.96
    transcutol 2812.24
    n-heptanol 283.5
    ethylbenzene 282.91
    MIBK 645.72
    2-propoxyethanol 1000.15
    tert-butanol 1351.34
    MTBE 1161.48
    2-butoxyethanol 528.41
    propionic acid 934.13
    o-xylene 332.25
    formic acid 634.56
    diethyl ether 1522.88
    m-xylene 372.46
    p-xylene 368.05
    chlorobenzene 712.49
    dimethyl carbonate 376.09
    n-octane 46.4
    formamide 696.92
    cyclopentanone 1298.97
    2-pentanone 1042.4
    anisole 576.5
    cyclopentyl methyl ether 1033.58
    gamma-butyrolactone 1404.89
    1-methoxy-2-propanol 1080.36
    pyridine 1270.53
    3-pentanone 752.68
    furfural 1094.88
    n-dodecane 43.89
    diethylene glycol 715.97
    diisopropyl ether 413.82
    tert-amyl alcohol 1026.1
    acetylacetone 1053.75
    n-hexadecane 49.14
    acetophenone 570.34
    methyl propionate 795.03
    isopentyl acetate 721.87
    trichloroethylene 3145.36
    n-nonanol 297.31
    cyclohexanol 894.0
    benzyl alcohol 497.39
    2-ethylhexanol 406.49
    isooctanol 250.4
    dipropyl ether 530.33
    1,2-dichlorobenzene 673.33
    ethyl lactate 344.31
    propylene carbonate 823.99
    n-methylformamide 670.66
    2-pentanol 825.16
    n-pentane 199.12
    1-propoxy-2-propanol 712.01
    1-methoxy-2-propyl acetate 632.1
    2-(2-methoxypropoxy) propanol 547.96
    mesitylene 268.34
    ε-caprolactone 1071.68
    p-cymene 196.85
    epichlorohydrin 1668.38
    1,1,1-trichloroethane 1635.84
    2-aminoethanol 595.75
    morpholine-4-carbaldehyde 1060.4
    sulfolane 1573.0
    2,2,4-trimethylpentane 114.09
    2-methyltetrahydrofuran 1383.85
    n-hexyl acetate 715.66
    isooctane 91.59
    2-(2-butoxyethoxy)ethanol 747.16
    sec-butyl acetate 558.16
    tert-butyl acetate 840.92
    decalin 138.47
    glycerin 495.58
    diglyme 1250.02
    acrylic acid 809.28
    isopropyl myristate 264.41
    n-butyric acid 1407.86
    acetyl acetate 895.85
    di(2-ethylhexyl) phthalate 247.08
    ethyl propionate 634.16
    nitromethane 1942.03
    1,2-diethoxyethane 962.92
    benzonitrile 648.01
    trioctyl phosphate 182.56
    1-bromopropane 1329.64
    gamma-valerolactone 1264.89
    n-decanol 218.22
    triethyl phosphate 264.46
    4-methyl-2-pentanol 442.18
    propionitrile 899.51
    vinylene carbonate 778.62
    1,1,2-trichlorotrifluoroethane 1398.22
    DMS 508.03
    cumene 212.81
    2-octanol 220.13
    2-hexanone 722.72
    octyl acetate 324.7
    limonene 309.31
    1,2-dimethoxyethane 1322.43
    ethyl orthosilicate 266.34
    tributyl phosphate 246.92
    diacetone alcohol 740.57
    N,N-dimethylaniline 408.63
    acrylonitrile 948.45
    aniline 636.46
    1,3-propanediol 851.78
    bromobenzene 869.15
    dibromomethane 2397.06
    1,1,2,2-tetrachloroethane 2424.97
    2-methyl-cyclohexyl acetate 429.81
    tetrabutyl urea 296.88
    diisobutyl methanol 246.44
    2-phenylethanol 453.55
    styrene 387.63
    dioctyl adipate 375.82
    dimethyl sulfate 571.48
    ethyl butyrate 575.84
    methyl lactate 407.97
    butyl lactate 373.7
    diethyl carbonate 398.5
    propanediol butyl ether 546.98
    triethyl orthoformate 382.71
    p-tert-butyltoluene 192.23
    methyl 4-tert-butylbenzoate 456.94
    morpholine 1663.61
    tert-butylamine 918.16
    n-dodecanol 167.89
    dimethoxymethane 996.97
    ethylene carbonate 675.22
    cyrene 460.56
    2-ethoxyethyl acetate 626.35
    2-ethylhexyl acetate 553.78
    1,2,4-trichlorobenzene 773.3
    4-methylpyridine 1105.06
    dibutyl ether 490.15
    2,6-dimethyl-4-heptanol 246.44
    DEF 1007.65
    dimethyl isosorbide 717.31
    tetrachloroethylene 1635.13
    eugenol 435.73
    triacetin 649.45
    span 80 503.53
    1,4-butanediol 402.82
    1,1-dichloroethane 1880.14
    2-methyl-1-pentanol 689.23
    methyl formate 498.54
    2-methyl-1-butanol 884.82
    n-decane 69.2
    butyronitrile 1027.16
    3,7-dimethyl-1-octanol 360.53
    1-chlorooctane 264.38
    1-chlorotetradecane 112.72
    n-nonane 70.55
    undecane 52.29
    tert-butylcyclohexane 128.8
    cyclooctane 98.84
    cyclopentanol 797.89
    tetrahydropyran 1549.33
    tert-amyl methyl ether 775.09
    2,5,8-trioxanonane 865.43
    1-hexene 586.96
    2-isopropoxyethanol 769.59
    2,2,2-trifluoroethanol 532.0
    methyl butyrate 815.26

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction