C.I. Basic Green 1

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  • Identifiers

    CAS number
    633-03-4

    Molecular formula
    C27H34N2O4S

    SMILES
    CCN(CC)C1=CC=C(C=C1)C(=C2C=CC(=[N+](CC)CC)C=C2)C3=CC=CC=C3.OS(=O)(=O)[O-]

    Safety labels

    Corrosive
    Corrosive

    Acute Toxic
    Acute Toxic

    Irritant
    Irritant

    Environmental Hazard
    Environmental

  • Odor profile

    Fragrance
    Fruity 47.89%
    Floral 41.44%
    Fresh 32.56%
    Spicy 29.18%
    Herbal 25.56%
    Woody 24.72%
    Animal 23.98%
    Citrus 23.6%
    Grapefruit 23.04%
    Sweet 22.37%

     

    Flavor
    Bitter 45.54%
    Herbal 28.75%
    Lovage 19.57%
    Nitrile 19.52%
    Oriental 19.47%
    Cedarleaf 19.41%
    Heather 18.93%
    Basil 18.8%
    Diterpene 18.54%
    Genet 18.53%

     

    Odor impact est.
    Low

  • Properties

    pKa est.
    8.69 (weak base)

    Molecular weight
    482.6 g/mol

    Melting point expt.

    • 210 °C, decomposes.

    Flash point

    • 228.5 ˚C est.

    Solubility expt.

    • 40 mg/ml in water; 60 mg/ml in 2-methoxyethanol; 50 mg/ml in ethanol

  • Synonyms

    • Brilliant green
    • 633-03-4
    • Basic green 1
    • Malachite Green G
    • C.I. Basic Green 1
    • Diamond Green G
    • Fast Green J
    • Solid Green
    • Basic Brilliant Green
    • Basic Green V
    • Green EN
    • Brilliant Green B
    • Brilliant Green G
    • Brilliant Green P
    • Brilliant Green Y
    • Fast Green JJO
    • Basic Bright Green
    • Brilliant Green GX
    • Brilliant Green YN
    • Deorlene Green JJO
    • Brilliant Green BPC
    • Brilliant Green DSC
    • Brilliant Green Lake
    • Brilliant Green YNS
    • Hidaco Brilliant Green
    • Astrazon Green D
    • Brilliant Green Aseptic
    • Brilliant Green Special
    • Brilliant Green Sulfate
    • Brilliant Lake Green Y
    • Aizen Diamond Green GH
    • Astra Diamond Green GX
    • Brilliant Green Crystals
    • Avon Green A-4379
    • Aizen Malachite Green GH
    • 12415 Green
    • Mitsui Brilliant Green GX
    • Basic Bright Green Sulfate
    • Brilliant Green Crystals H
    • Zelen brilantni
    • Brilliant-grun
    • Calcozine Brilliant Green G
    • Brilliant Green BP Crystals
    • Brilliant Green WP Crystals
    • Zelen smaragdova
    • ADC Brilliant Green Crystals
    • Brilliant Green B.P.
    • Tertrophene Brilliant Green G
    • Tokyo Aniline Brilliant Green
    • Brilliant-grun [German]
    • Zelen brilantni [Czech]
    • Zelen zasadita 1
    • Zelen smaragdova [Czech]
    • Zelen malachitova G
    • Zelen zasadita 1 [Czech]
    • NSC-5011
    • Zelen malachitova G [Czech]
    • C.I. 42040
    • CCRIS 1209
    • HSDB 6403
    • Brilliant Tungstate Green Toner GT-288
    • NSC 5011
    • EINECS 211-190-1
    • DTXSID1048700
    • CHEBI:88173
    • G0L543D370
    • BRILLIANT GREEN [MI]
    • CI 42040
    • N,N,N',N'-Tetraaethyl-monoaminofuchsoniumhydrogensulfat
    • (4-(4-(Diethylamino)benzhydrylene)cyclohexa-2,5-dien-1-ylidene)diethylammonium hydrogen sulphate
    • BRILLIANT GREEN [VANDF]
    • BRILLIANT GREEN [MART.]
    • DTXCID4028626
    • NSC5011
    • C.I. BASIC GREEN 1 [HSDB]
    • (4-(4-(Diethylamino)benzhydrylene)cyclohexa-2,5-dien-1-ylidene)diethylammonium hydrogen sulfate
    • Ethanaminium, N-[4-[[4-(diethylamino)phenyl]phenylmethylene]-2,5-cyclohexadien-1-ylidene]-N-ethyl-, sulfate (1:1)
    • Brilliant-grun (German)
    • BRILLIANT GREEN CI 42040 [WHO-DD]
    • [4-[[4-(diethylamino)phenyl]-phenylmethylidene]cyclohexa-2,5-dien-1-ylidene]-diethylazanium;hydrogen sulfate
    • Ammonium, (4-(p-(diethylamino)-alpha-phenylbenzylidene)-2,5-cyclohexadien-1-ylidene) diethyl-,sulfate (1:1)
    • Ethanaminium, N-(4-((4-(diethylamino)phenyl)phenylmethylene)-2,5-cyclohexadien-1-ylidene)-N-ethyl-, sulfate (1:1)
    • N-(4-((4-(Diethylamino)phenyl)phenylmethylene)-2,5-cyclohexadien-1-ylidene)-N-ethylethanaminium sulfate (1:1)
    • BRILLIANT GREEN (MART.)
    • [4-[4-(Diethylamino)benzhydrylene]cyclohexa-2,5-dien-1-ylidene]diethylammonium hydrogen sulphate
    • 4-{[4-(diethylamino)phenyl](phenyl)methylidene}-N,N-diethylcyclohexa-2,5-dien-1-iminium hydrogen sulfate
    • N-(4-((4-(diethylamino)phenyl)(phenyl)methylene)cyclohexa-2,5-dien-1-ylidene)-N-ethylethanaminium hydrogen sulfate
    • NCGC00166123-01
    • Brilliantgrun
    • Verde brilhante
    • Vert Brilliant
    • Verde Brilliante
    • UNII-G0L543D370
    • 4-((4-(diethylamino)phenyl)(phenyl)methylidene)-N,N-diethylcyclohexa-2,5-dien-1-iminium hydrogen sulfate
    • Brillant green YNS
    • brilliant green (dye)
    • Avon Green A4379
    • Mitsui brillant green GX
    • Brilliant Green Certified
    • Basic Green 1 100 microg/mL in Acetonitrile
    • CI basic green 1, sulfate
    • SCHEMBL49148
    • Brilliant green CI 42040
    • (4-(p-(diethylamino)-alpha-phenylbenzylidene)-2,5-cyclohexadien-1-ylidene)diethylammonium sulfate
    • MLS006010016
    • BASIC GREEN 1 [INCI]
    • CHEMBL1790039
    • C.I. Basic Green 1 (8CI)
    • NNBFNNNWANBMTI-UHFFFAOYSA-M
    • HY-D0008
    • Brilliant Green, analytical standard
    • Tox21_113095
    • Bright green indicator (0.0-2.6)
    • AKOS000282984
    • Brilliant Green, Dye content ~90 %
    • Brilliant Tungstate Green Toner GT288
    • FB33241
    • CAS-633-03-4
    • DA-71736
    • LS-15197
    • PD060969
    • SMR004701091
    • A5106
    • B0789
    • CS-0009903
    • CS-0169058
    • D88692
    • SBI-0653846.0001

  • Applications

    C.I. Basic Green 1 (CAS number: 633-03-4) is a cationic dye used as a colorant for textiles, notably acrylic and certain synthetic fibers; it is also used as a color for paper, inks and coatings, and as a staining dye in microbiology and histology for light microscopy, while also serving as a color probe or indicator in controlled analytical workflows.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 5.81
    methanol 3.85
    isopropanol 4.21
    water 0.01
    ethyl acetate 67.99
    n-propanol 10.0
    acetone 43.6
    n-butanol 11.43
    acetonitrile 10.84
    DMF 67.99
    toluene 100.04
    isobutanol 9.4
    1,4-dioxane 73.14
    methyl acetate 56.64
    THF 158.61
    2-butanone 73.15
    n-pentanol 13.97
    sec-butanol 9.22
    n-hexane 14.12
    ethylene glycol 0.83
    NMP 185.46
    cyclohexane 18.84
    DMSO 42.56
    n-butyl acetate 79.1
    n-octanol 5.62
    chloroform 567.07
    n-propyl acetate 57.37
    acetic acid 16.45
    dichloromethane 615.49
    cyclohexanone 139.55
    propylene glycol 1.66
    isopropyl acetate 51.77
    DMAc 185.19
    2-ethoxyethanol 27.66
    isopentanol 12.96
    n-heptane 8.56
    ethyl formate 27.14
    1,2-dichloroethane 299.62
    n-hexanol 16.4
    2-methoxyethanol 20.27
    isobutyl acetate 46.67
    tetrachloromethane 68.82
    n-pentyl acetate 41.24
    transcutol 76.55
    n-heptanol 8.06
    ethylbenzene 43.12
    MIBK 43.16
    2-propoxyethanol 45.06
    tert-butanol 6.58
    MTBE 34.24
    2-butoxyethanol 22.76
    propionic acid 18.34
    o-xylene 54.21
    formic acid 3.48
    diethyl ether 59.14
    m-xylene 52.03
    p-xylene 54.79
    chlorobenzene 155.8
    dimethyl carbonate 40.96
    n-octane 3.05
    formamide 6.49
    cyclopentanone 169.07
    2-pentanone 63.25
    anisole 69.93
    cyclopentyl methyl ether 115.16
    gamma-butyrolactone 147.27
    1-methoxy-2-propanol 20.76
    pyridine 115.61
    3-pentanone 91.45
    furfural 119.43
    n-dodecane 1.81
    diethylene glycol 15.88
    diisopropyl ether 22.71
    tert-amyl alcohol 12.25
    acetylacetone 83.14
    n-hexadecane 2.22
    acetophenone 75.76
    methyl propionate 73.66
    isopentyl acetate 74.25
    trichloroethylene 564.21
    n-nonanol 7.18
    cyclohexanol 23.53
    benzyl alcohol 35.41
    2-ethylhexanol 20.75
    isooctanol 8.82
    dipropyl ether 57.67
    1,2-dichlorobenzene 161.68
    ethyl lactate 23.21
    propylene carbonate 80.68
    n-methylformamide 17.55
    2-pentanol 10.28
    n-pentane 8.51
    1-propoxy-2-propanol 35.54
    1-methoxy-2-propyl acetate 89.97
    2-(2-methoxypropoxy) propanol 34.77
    mesitylene 28.07
    ε-caprolactone 120.39
    p-cymene 25.85
    epichlorohydrin 247.53
    1,1,1-trichloroethane 258.21
    2-aminoethanol 2.75
    morpholine-4-carbaldehyde 123.19
    sulfolane 180.65
    2,2,4-trimethylpentane 6.49
    2-methyltetrahydrofuran 117.78
    n-hexyl acetate 35.6
    isooctane 2.86
    2-(2-butoxyethoxy)ethanol 31.66
    sec-butyl acetate 50.46
    tert-butyl acetate 55.5
    decalin 12.5
    glycerin 3.48
    diglyme 88.63
    acrylic acid 16.15
    isopropyl myristate 19.48
    n-butyric acid 32.7
    acetyl acetate 54.69
    di(2-ethylhexyl) phthalate 22.61
    ethyl propionate 62.54
    nitromethane 40.48
    1,2-diethoxyethane 70.87
    benzonitrile 43.38
    trioctyl phosphate 12.21
    1-bromopropane 159.52
    gamma-valerolactone 170.25
    n-decanol 5.64
    triethyl phosphate 51.8
    4-methyl-2-pentanol 8.88
    propionitrile 20.38
    vinylene carbonate 74.91
    1,1,2-trichlorotrifluoroethane 117.88
    DMS 69.34
    cumene 28.42
    2-octanol 5.82
    2-hexanone 57.86
    octyl acetate 21.71
    limonene 38.04
    1,2-dimethoxyethane 70.85
    ethyl orthosilicate 49.59
    tributyl phosphate 21.11
    diacetone alcohol 33.9
    N,N-dimethylaniline 55.39
    acrylonitrile 22.27
    aniline 58.7
    1,3-propanediol 5.7
    bromobenzene 216.93
    dibromomethane 374.38
    1,1,2,2-tetrachloroethane 423.61
    2-methyl-cyclohexyl acetate 65.27
    tetrabutyl urea 29.98
    diisobutyl methanol 13.61
    2-phenylethanol 36.25
    styrene 57.32
    dioctyl adipate 37.12
    dimethyl sulfate 79.76
    ethyl butyrate 75.56
    methyl lactate 21.54
    butyl lactate 25.48
    diethyl carbonate 52.96
    propanediol butyl ether 10.2
    triethyl orthoformate 64.35
    p-tert-butyltoluene 22.13
    methyl 4-tert-butylbenzoate 52.1
    morpholine 76.11
    tert-butylamine 6.34
    n-dodecanol 4.76
    dimethoxymethane 66.61
    ethylene carbonate 64.16
    cyrene 49.62
    2-ethoxyethyl acetate 72.28
    2-ethylhexyl acetate 77.67
    1,2,4-trichlorobenzene 196.91
    4-methylpyridine 116.08
    dibutyl ether 26.77
    2,6-dimethyl-4-heptanol 13.61
    DEF 105.17
    dimethyl isosorbide 97.29
    tetrachloroethylene 261.89
    eugenol 39.45
    triacetin 56.1
    span 80 23.89
    1,4-butanediol 3.96
    1,1-dichloroethane 219.07
    2-methyl-1-pentanol 18.91
    methyl formate 18.22
    2-methyl-1-butanol 15.36
    n-decane 3.41
    butyronitrile 21.42
    3,7-dimethyl-1-octanol 10.05
    1-chlorooctane 14.61
    1-chlorotetradecane 6.3
    n-nonane 3.09
    undecane 2.35
    tert-butylcyclohexane 9.24
    cyclooctane 7.99
    cyclopentanol 22.75
    tetrahydropyran 96.77
    tert-amyl methyl ether 44.07
    2,5,8-trioxanonane 63.24
    1-hexene 35.91
    2-isopropoxyethanol 26.85
    2,2,2-trifluoroethanol 11.49
    methyl butyrate 71.11

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction