1-Methyl-4-(1-methylvinyl)cyclohexan-1-ol

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  • Identifiers

    CAS number
    7299-41-4

    Molecular formula
    C10H18O

    SMILES
    CC(=C)C1CCC(CC1)(C)O

    Safety labels

    Irritant
    Irritant

    Retention indicies (RI)

    • DB5: 1144.0
    • Carbowax: 1588.0

  • Odor profile

    Woody 69.78%
    Sweet 67.98%
    Herbal 67.76%
    Floral 58.15%
    Citrus 54.59%
    Camphoreous 50.98%
    Fresh 50.42%
    Earthy 48.47%
    Pine 47.97%
    Terpenic 47.9%

    Scent© AI

  • Properties

    XLogP3-AA
    2.5

    pKa est.
    10.36 (weak base)

    Molecular weight
    154.25 g/mol

    Vapor pressure est.

    • hPa @ 20°C
    • hPa @ 25°C

    Evaporation rate
    Moderate

    Boiling point est.
    210°C

    Flash point est.
    87.55 ˚C

  • Synonyms

    • BETA-TERPINEOL
    • 138-87-4
    • cis-beta-Terpineol
    • trans-beta-Terpineol
    • p-Menth-8-en-1-ol
    • Cyclohexanol, 1-methyl-4-(1-methylethenyl)-
    • trans-|A-Terpineol
    • 1-Methyl-4-(1-methylethenyl)cyclohexanol
    • cis-.beta.-Terpineol
    • 1-Methyl-4-(1-methylvinyl)cyclohexan-1-ol
    • trans-.beta.-terpineol
    • 1-Methyl-4-isopropenylcyclohexan-1-ol
    • 4-Isopropenyl-1-methyl-1-cyclohexanol
    • 1-methyl-4-(prop-1-en-2-yl)cyclohexan-1-ol
    • 7299-40-3
    • 4-Isopropenyl-1-methylcyclohexanol
    • cis-|A-Terpineol
    • (E)-beta-Terpineol
    • 7299-41-4
    • Cyclohexanol, 1-methyl-4-(1-methylethenyl)-, trans-
    • 1-methyl-4-prop-1-en-2-ylcyclohexan-1-ol
    • Terpineol, cis-.beta.-
    • Cyclohexanol, 1-methyl-4-(1-methylethenyl)-, cis-
    • S00R85C5ER
    • DTXSID7041209
    • 55258Z4SCW
    • p-Menth-8-en-1-ol, stereoisomer
    • Terpinol, beta-
    • t-Menth-1-en-8-ol
    • b-terpineol
    • FEMA No. 3564
    • beta-Terpineol, cis-
    • beta-Terpineol, trans-
    • EINECS 205-342-6
    • UNII-XS86XKC2VT
    • BRN 2205072
    • UNII-S00R85C5ER
    • beta-Terpinol
    • UNII-55258Z4SCW
    • beta -terpineol
    • AI3-00731
    • 4-isopropenyl-1-methyl-cyclohexanol
    • cis-I(2)-Terpineol
    • trans-I(2)-Terpineol
    • (E)-.beta.-terpineol
    • (Z)-.beta.-Terpineol
    • XS86XKC2VT
    • cis-p-Menth-8-en-1-ol
    • trans-p-Menth-8-en-1-ol
    • P-menth-8-en-1-ol, cis
    • 4-06-00-00254 (Beilstein Handbook Reference)
    • SCHEMBL1245775
    • .BETA.-TERPINEOL, CIS-
    • CHEMBL3184678
    • DTXCID5021209
    • SCHEMBL13895789
    • SCHEMBL14278527
    • SCHEMBL22882350
    • FEMA 3564
    • .BETA.-TERPINEOL, TRANS-
    • CHEBI:132899
    • DTXSID201317014
    • DTXSID301316364
    • Tox21_302378
    • MFCD00037724
    • AKOS006282035
    • HY-119963A
    • HY-119963B
    • 4-Isopropenyl-1-methylcyclohexanol, cis
    • NCGC00255487-01
    • CAS-138-87-4
    • DA-69594
    • DA-78581
    • 1-Methyl-4-(1-Methylethenyl)-cyclohexanol
    • 4-Isopropenyl-1-methylcyclohexanol, trans-
    • DB-243107
    • CS-0089116
    • CS-0089118
    • NS00012934
    • C17517
    • 1-Methyl-4-(1-methylethenyl)-trans-Cyclohexanol
    • 1beta-Methyl-4alpha-(1-methylethenyl)cyclohexanol
    • TERPIN MONOHYDRATE IMPURITY B [EP IMPURITY]
    • Q27261256
    • Q27288363
    • Q67880219
    • Rel-(1r,4r)-1-methyl-4-(prop-1-en-2-yl)cyclohexan-1-ol
    • (1S,4S)-1-METHYL-4-(PROP-1-EN-2-YL)CYCLOHEXAN-1-OL
    • 844-907-7

  • Applications

    1-Methyl-4-(1-methylvinyl)cyclohexan-1-ol (CAS 7299-41-4) is a monoterpenoid alcohol with broad utility: in fragrance it serves as a tone modifier and profile extender that rounds and bridges citrus, herbal, or woody notes in fine fragrance, personal care, and cleaners, and it can act as a co-solvent to aid perfume oil solubilization; in aroma–cosmetic chemistry it is a convenient intermediate for preparing terpenyl esters/ethers or carbonate derivatives to tune volatility, odor longevity, and formulation compatibility; in materials, terpene alcohols like this are used as bio-based high-boiling additives (coalescent/coupling agents) for waterborne coatings, inks, and bio-derived cleaners; in R&D it functions as a hydrophobic building block in pharma/agro discovery and is studied for typical terpene-related antimicrobial/antioxidant behaviors, as well as for chirality-related applications in asymmetric synthesis and chromatographic method development.

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 2113.15
    methanol 1776.0
    isopropanol 1817.56
    water 2.57
    ethyl acetate 1300.53
    n-propanol 1449.87
    acetone 1246.03
    n-butanol 1547.87
    acetonitrile 1142.31
    DMF 796.27
    toluene 390.53
    isobutanol 815.47
    1,4-dioxane 2804.47
    methyl acetate 906.95
    THF 3890.83
    2-butanone 966.41
    n-pentanol 669.63
    sec-butanol 941.74
    n-hexane 111.28
    ethylene glycol 167.13
    NMP 474.15
    cyclohexane 241.18
    DMSO 678.81
    n-butyl acetate 1037.62
    n-octanol 445.64
    chloroform 1766.36
    n-propyl acetate 556.73
    acetic acid 830.35
    dichloromethane 1368.16
    cyclohexanone 989.91
    propylene glycol 372.62
    isopropyl acetate 825.76
    DMAc 560.23
    2-ethoxyethanol 783.16
    isopentanol 1012.8
    n-heptane 168.69
    ethyl formate 736.12
    1,2-dichloroethane 683.93
    n-hexanol 1255.76
    2-methoxyethanol 1706.28
    isobutyl acetate 333.21
    tetrachloromethane 287.75
    n-pentyl acetate 435.13
    transcutol 2884.95
    n-heptanol 471.58
    ethylbenzene 149.8
    MIBK 519.9
    2-propoxyethanol 1531.37
    tert-butanol 1661.29
    MTBE 1181.44
    2-butoxyethanol 705.71
    propionic acid 605.26
    o-xylene 184.46
    formic acid 252.92
    diethyl ether 1526.95
    m-xylene 236.28
    p-xylene 202.75
    chlorobenzene 419.36
    dimethyl carbonate 209.35
    n-octane 52.47
    formamide 406.0
    cyclopentanone 1091.94
    2-pentanone 915.35
    anisole 414.92
    cyclopentyl methyl ether 1011.36
    gamma-butyrolactone 1121.57
    1-methoxy-2-propanol 1315.37
    pyridine 1055.59
    3-pentanone 503.35
    furfural 873.23
    n-dodecane 38.42
    diethylene glycol 735.26
    diisopropyl ether 396.92
    tert-amyl alcohol 800.79
    acetylacetone 783.18
    n-hexadecane 42.9
    acetophenone 272.18
    methyl propionate 642.31
    isopentyl acetate 784.28
    trichloroethylene 1067.36
    n-nonanol 387.07
    cyclohexanol 802.1
    benzyl alcohol 298.66
    2-ethylhexanol 590.62
    isooctanol 320.43
    dipropyl ether 902.51
    1,2-dichlorobenzene 303.75
    ethyl lactate 193.46
    propylene carbonate 649.94
    n-methylformamide 591.36
    2-pentanol 808.02
    n-pentane 165.14
    1-propoxy-2-propanol 1097.96
    1-methoxy-2-propyl acetate 906.12
    2-(2-methoxypropoxy) propanol 559.58
    mesitylene 149.75
    ε-caprolactone 881.81
    p-cymene 161.4
    epichlorohydrin 1360.71
    1,1,1-trichloroethane 694.23
    2-aminoethanol 561.83
    morpholine-4-carbaldehyde 1054.87
    sulfolane 629.77
    2,2,4-trimethylpentane 58.95
    2-methyltetrahydrofuran 1995.66
    n-hexyl acetate 666.15
    isooctane 62.06
    2-(2-butoxyethoxy)ethanol 943.8
    sec-butyl acetate 362.93
    tert-butyl acetate 716.24
    decalin 66.65
    glycerin 373.0
    diglyme 1520.94
    acrylic acid 352.17
    isopropyl myristate 239.83
    n-butyric acid 1240.07
    acetyl acetate 582.33
    di(2-ethylhexyl) phthalate 211.2
    ethyl propionate 430.96
    nitromethane 970.82
    1,2-diethoxyethane 1294.86
    benzonitrile 480.54
    trioctyl phosphate 159.02
    1-bromopropane 644.91
    gamma-valerolactone 1551.93
    n-decanol 270.05
    triethyl phosphate 183.0
    4-methyl-2-pentanol 445.01
    propionitrile 939.84
    vinylene carbonate 553.86
    1,1,2-trichlorotrifluoroethane 579.89
    DMS 316.45
    cumene 107.51
    2-octanol 289.63
    2-hexanone 479.01
    octyl acetate 318.59
    limonene 275.46
    1,2-dimethoxyethane 1400.75
    ethyl orthosilicate 198.26
    tributyl phosphate 202.3
    diacetone alcohol 671.73
    N,N-dimethylaniline 219.0
    acrylonitrile 680.1
    aniline 575.68
    1,3-propanediol 1026.12
    bromobenzene 400.05
    dibromomethane 905.65
    1,1,2,2-tetrachloroethane 796.29
    2-methyl-cyclohexyl acetate 353.93
    tetrabutyl urea 224.75
    diisobutyl methanol 310.07
    2-phenylethanol 466.47
    styrene 199.21
    dioctyl adipate 305.98
    dimethyl sulfate 183.47
    ethyl butyrate 615.44
    methyl lactate 266.74
    butyl lactate 316.37
    diethyl carbonate 348.84
    propanediol butyl ether 563.8
    triethyl orthoformate 412.98
    p-tert-butyltoluene 173.81
    methyl 4-tert-butylbenzoate 303.75
    morpholine 2922.28
    tert-butylamine 1108.07
    n-dodecanol 197.85
    dimethoxymethane 1010.45
    ethylene carbonate 549.63
    cyrene 282.93
    2-ethoxyethyl acetate 623.06
    2-ethylhexyl acetate 584.81
    1,2,4-trichlorobenzene 327.86
    4-methylpyridine 936.66
    dibutyl ether 601.3
    2,6-dimethyl-4-heptanol 310.07
    DEF 680.71
    dimethyl isosorbide 815.9
    tetrachloroethylene 514.95
    eugenol 295.94
    triacetin 458.74
    span 80 522.4
    1,4-butanediol 238.14
    1,1-dichloroethane 913.41
    2-methyl-1-pentanol 446.29
    methyl formate 410.06
    2-methyl-1-butanol 709.67
    n-decane 71.54
    butyronitrile 1211.85
    3,7-dimethyl-1-octanol 416.31
    1-chlorooctane 225.84
    1-chlorotetradecane 88.47
    n-nonane 71.59
    undecane 49.95
    tert-butylcyclohexane 69.85
    cyclooctane 76.56
    cyclopentanol 777.73
    tetrahydropyran 2533.85
    tert-amyl methyl ether 578.93
    2,5,8-trioxanonane 958.7
    1-hexene 336.02
    2-isopropoxyethanol 537.97
    2,2,2-trifluoroethanol 179.65
    methyl butyrate 524.15

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction

Botanical

Name CAS Botanical Proportion
Yuzu (Japan) 2 Citrus junos Sieb. ex Tanaka, fam. Rutaceae 0.03%
Pistacia lentiscus (Spain) 1a leaf 90082-83-0 Pistacia lentiscus L., fam. Anacardiaceae 0.04%
Grapefruit leaf (Mauritius) 90045-43-5 Citrus paradisi Macfayden, fam. Rutaceae 6.98%
Mandarin (Italy) 7 8008-31-9 Citrus deliciosa Tenore (C. reticulata Blanco, cv.mandarin), fam. Rutacaea 0.01%
Vitex agnus-castus leaf (Italy) Vitex agnus-castus L., fam. Verbenaceae 0.01%
Vitex agnus-castus fruit (Italy) Vitex agnus-castus L., fam. Verbenaceae 0.1%
Vitex agnus-castus inflorescence (Italy) Vitex agnus-castus L., fam. Verbenaceae 0.9%
Uromyrtus metrosideros (Australia) Uromyrtus metrosideros (F.M. Bailey) A.J. Scott, fam. Myrtaceae 0.17%
Lemon (Benin) 84929-31-7 Citrus limon (L.) Burm. f., fam. Rutaceae 0.1%
Marjoram, sweet (Egypt) 4 8015-01-8 Majorana hortensis Moench, Origanum majorana L., fam. Lamiaceae (Labiatae) 0.85%
Lime (Mexican, West Indian, Key) 5 8008-26-2 Citrus aurantifolia (Christm.) Swingle, fam. Rutaceae 0.22%
Lime (Mexican, West Indian, Key) (Peru) 8008-26-2 Citrus aurantifolia (Christm.) Swingle, fam. Rutaceae 0.4%
Lime (Mexican, West Indian, Key) (Ivory Coast) 8008-26-2 Citrus aurantifolia (Christm.) Swingle, fam. Rutaceae 0.72%
Lime (Mexican, West Indian, Key) 7 8008-26-2 Citrus aurantifolia (Christm.) Swingle, fam. Rutaceae 0.75%
Tagetes filifolia (Peru) Tagetes filifolia Lag., fam. Asteraceae (Compositae) 0.01%
Grapefruit (Cuba), distilled 8016-20-4 Citrus paradisi Macfayden, fam. Rutaceae 0.1%
Sage, dalmatian (Egypt) 2a 8022-56-8 Salvia officinalis L., fam. Lamiaceae (Labiatae) 0.1%
Pepper, black (India) 6b free volatiles 8006-82-4 Piper nigrum L., fam. Piperaceae 0.4%
Lime (Mexican, West Indian, Key) (Cuba) 8008-26-2 Citrus aurantifolia (Christm.) Swingle, fam. Rutaceae 2.2%
Lime (Persian) (Cuba) 90063-52-8 Citrus latifolia Tanaka, fam. Rutaceae 2.2%
Mandarin (Japan) 2c Minneola 8008-31-9 Citrus deliciosa Tenore cv. Minneola (C. reticulata Blanco), fam. Rutaceae 0.01%
Mandarin (Japan) 3d Kara 8008-31-9 Citrus deliciosa Tenore cv. Kara (C. reticulata Blanco), fam. Rutaceae 0.05%
Satsuma mandarin peel 2 Citrus unshiu Marcovitch f. Miyagawa, fam. Rutaceae 0.3%
Murraya koenigii (India) Murraya koenigii (L.) Spreng., fam. Rutaceae 0.05%