Propineb

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  • Identifiers

    CAS number
    12071-83-9

    Molecular formula
    C5H8N2S4Zn

    SMILES
    CC(CNC(=S)[S-])NC(=S)[S-].[Zn+2]

    Safety labels

    Irritant
    Irritant

    Health Hazard
    Health

    Environmental Hazard
    Environmental

  • Odor profile

    Fragrance
    Odorless 51.69%
    Meaty 43.33%
    Savory 39.99%
    Sulfurous 39.53%
    Cooked 28.1%
    Roasted 24.76%
    Pungent 23.47%
    Garlic 21.33%
    Fishy 21.29%
    Onion 20.83%

     

    Flavor
    Odorless 36.43%
    Bitter 29.88%
    Roasted 23.56%
    Bland 23.44%
    Mild 22.17%
    Cooked 21.88%
    Nitrile 19.68%
    Scallion 19.04%
    Sulfurous 18.89%
    Sulfury 18.88%

     

    Odor impact est.
    Low

  • Properties

    pKa est.
    9.83 (weak base)

    Molecular weight
    289.8 g/mol

    Flash point

    • 150.1 ˚C est.

  • Synonyms

    • Propineb
    • Antracol
    • 12071-83-9
    • Methylzineb
    • Mezineb
    • Propinebe
    • Airone
    • Taifen
    • Bayer 46131
    • Zinc propylene bisdithiocarbamate
    • BAY 46131
    • Zinc 1,2-propylene bisdithiocarbamate
    • BAYER-46131
    • CHEBI:81755
    • 003VPM353K
    • B-5078
    • propyneb
    • Tsipromat
    • Zipromat
    • Propylenebis(dithiocarbamato)zinc
    • DTXSID1052741
    • LH 30/Z
    • Antracol 70
    • LH 3012
    • RefChem:176410
    • DTXCID4031279
    • Zinc, ((2-((dithiocarboxy)amino)-1-methylethyl)carbamodithioato(2-)-kappaS,kappaS')-
    • 235-134-0
    • Propineb [ISO]
    • Zinc propylenebis(dithiocarbamate)
    • CYPROMATE
    • PROPINEB [MI]
    • SCHEMBL55379
    • MSK21009
    • AKOS016036574
    • AT25064
    • Zinc 1,2-propylenebis(dithiocarbamate)
    • C18450
    • Q2113032
    • CARBAMODITHIOIC ACID, (1-METHYL-1,2-ETHANEDIYL)BIS-, ZINC SALT
    • (N-(2-((DITHIOCARBOXY)AMINO)-1METHYLETHYL)CARBAMODITHIOATO(2)-.KAPPA.S,.KAPPA.S)ZINC
    • ZINC, (N-(2-((DITHIOCARBOXY)AMINO)-1-METHYLETHYL)CARBAMODITHIOATO(2-)-.KAPPA.S,.KAPPA.S')-
    • 12071-83-9

  • Applications

    Propineb is a broad-spectrum dithiocarbamate fungicide used in agriculture as a protective treatment to control fungal diseases on crops such as fruits, vegetables, and ornamentals. It is applied as a preventive spray in field and greenhouse programs, typically formulated as wettable powders, suspensions, or granules, and is often used in tank mixes or rotation schemes within integrated crop protection plans. Common applications include protecting orchards, vineyards, and vegetable crops from blights and mildews, as well as providing postharvest protection to extend storage life of fruits and vegetables by reducing decay. It may also be evaluated for use on ornamental plants and other horticultural crops, with usage governed by local regulations and formulation limits.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 16.58
    methanol 20.03
    isopropanol 12.79
    water 0.32
    ethyl acetate 22.66
    n-propanol 15.97
    acetone 59.27
    n-butanol 15.18
    acetonitrile 20.8
    DMF 225.51
    toluene 7.59
    isobutanol 13.08
    1,4-dioxane 36.8
    methyl acetate 30.05
    THF 88.28
    2-butanone 44.24
    n-pentanol 16.44
    sec-butanol 14.04
    n-hexane 0.43
    ethylene glycol 14.18
    NMP 162.29
    cyclohexane 0.5
    DMSO 177.01
    n-butyl acetate 25.23
    n-octanol 14.54
    chloroform 31.56
    n-propyl acetate 23.82
    acetic acid 25.83
    dichloromethane 30.5
    cyclohexanone 57.51
    propylene glycol 16.69
    isopropyl acetate 16.76
    DMAc 219.2
    2-ethoxyethanol 40.39
    isopentanol 13.8
    n-heptane 1.05
    ethyl formate 26.23
    1,2-dichloroethane 21.78
    n-hexanol 18.64
    2-methoxyethanol 56.68
    isobutyl acetate 18.11
    tetrachloromethane 4.01
    n-pentyl acetate 23.33
    transcutol 54.25
    n-heptanol 14.29
    ethylbenzene 5.27
    MIBK 22.66
    2-propoxyethanol 48.21
    tert-butanol 15.87
    MTBE 15.14
    2-butoxyethanol 32.83
    propionic acid 18.61
    o-xylene 6.68
    formic acid 13.66
    diethyl ether 11.13
    m-xylene 6.56
    p-xylene 6.88
    chlorobenzene 15.66
    dimethyl carbonate 25.62
    n-octane 0.75
    formamide 20.83
    cyclopentanone 92.93
    2-pentanone 33.94
    anisole 23.38
    cyclopentyl methyl ether 26.41
    gamma-butyrolactone 80.81
    1-methoxy-2-propanol 46.49
    pyridine 40.06
    3-pentanone 25.43
    furfural 101.17
    n-dodecane 0.92
    diethylene glycol 47.79
    diisopropyl ether 3.71
    tert-amyl alcohol 16.4
    acetylacetone 50.29
    n-hexadecane 1.05
    acetophenone 35.54
    methyl propionate 30.11
    isopentyl acetate 23.31
    trichloroethylene 53.27
    n-nonanol 14.19
    cyclohexanol 14.72
    benzyl alcohol 30.1
    2-ethylhexanol 13.66
    isooctanol 12.41
    dipropyl ether 12.31
    1,2-dichlorobenzene 17.87
    ethyl lactate 24.22
    propylene carbonate 42.45
    n-methylformamide 49.01
    2-pentanol 10.39
    n-pentane 0.51
    1-propoxy-2-propanol 37.99
    1-methoxy-2-propyl acetate 36.81
    2-(2-methoxypropoxy) propanol 38.01
    mesitylene 4.05
    ε-caprolactone 47.38
    p-cymene 7.66
    epichlorohydrin 73.61
    1,1,1-trichloroethane 17.39
    2-aminoethanol 17.9
    morpholine-4-carbaldehyde 130.77
    sulfolane 142.26
    2,2,4-trimethylpentane 0.61
    2-methyltetrahydrofuran 38.21
    n-hexyl acetate 26.09
    isooctane 0.46
    2-(2-butoxyethoxy)ethanol 39.84
    sec-butyl acetate 15.63
    tert-butyl acetate 19.14
    decalin 0.74
    glycerin 33.7
    diglyme 68.64
    acrylic acid 22.93
    isopropyl myristate 12.24
    n-butyric acid 24.4
    acetyl acetate 18.45
    di(2-ethylhexyl) phthalate 20.21
    ethyl propionate 19.68
    nitromethane 65.77
    1,2-diethoxyethane 22.75
    benzonitrile 31.83
    trioctyl phosphate 14.39
    1-bromopropane 10.34
    gamma-valerolactone 112.05
    n-decanol 11.21
    triethyl phosphate 14.1
    4-methyl-2-pentanol 7.75
    propionitrile 16.87
    vinylene carbonate 42.16
    1,1,2-trichlorotrifluoroethane 76.63
    DMS 24.47
    cumene 4.78
    2-octanol 10.8
    2-hexanone 29.86
    octyl acetate 17.82
    limonene 10.15
    1,2-dimethoxyethane 64.06
    ethyl orthosilicate 12.73
    tributyl phosphate 14.28
    diacetone alcohol 36.28
    N,N-dimethylaniline 21.71
    acrylonitrile 28.27
    aniline 18.1
    1,3-propanediol 21.28
    bromobenzene 13.2
    dibromomethane 16.42
    1,1,2,2-tetrachloroethane 46.91
    2-methyl-cyclohexyl acetate 21.71
    tetrabutyl urea 24.97
    diisobutyl methanol 8.21
    2-phenylethanol 30.08
    styrene 6.93
    dioctyl adipate 21.61
    dimethyl sulfate 63.45
    ethyl butyrate 20.67
    methyl lactate 34.82
    butyl lactate 26.96
    diethyl carbonate 14.62
    propanediol butyl ether 34.24
    triethyl orthoformate 16.41
    p-tert-butyltoluene 7.53
    methyl 4-tert-butylbenzoate 35.19
    morpholine 48.53
    tert-butylamine 7.5
    n-dodecanol 8.64
    dimethoxymethane 65.98
    ethylene carbonate 29.98
    cyrene 59.29
    2-ethoxyethyl acetate 31.95
    2-ethylhexyl acetate 19.06
    1,2,4-trichlorobenzene 25.73
    4-methylpyridine 43.54
    dibutyl ether 10.11
    2,6-dimethyl-4-heptanol 8.21
    DEF 52.43
    dimethyl isosorbide 61.28
    tetrachloroethylene 24.23
    eugenol 42.29
    triacetin 32.84
    span 80 33.2
    1,4-butanediol 15.37
    1,1-dichloroethane 18.89
    2-methyl-1-pentanol 14.69
    methyl formate 45.36
    2-methyl-1-butanol 14.55
    n-decane 1.35
    butyronitrile 19.23
    3,7-dimethyl-1-octanol 12.96
    1-chlorooctane 6.86
    1-chlorotetradecane 3.13
    n-nonane 1.16
    undecane 1.09
    tert-butylcyclohexane 0.87
    cyclooctane 0.3
    cyclopentanol 22.32
    tetrahydropyran 22.75
    tert-amyl methyl ether 14.77
    2,5,8-trioxanonane 54.92
    1-hexene 2.8
    2-isopropoxyethanol 31.3
    2,2,2-trifluoroethanol 16.23
    methyl butyrate 28.98

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction