Lithium Chloride

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  • Identifiers

    CAS number
    7447-41-8

    Molecular formula
    ClLi

    SMILES
    [Li+].[Cl-]

    Safety labels

    Irritant
    Irritant

  • Odor profile

  • Properties

    pKa est.
    -15.64 (strong acid)

    Molecular weight
    42.4 g/mol

    Melting point expt.

    • 1121 °F (NTP, 1992)
    • 610 °C
    • 613 °C

    Boiling point

    • 2417 to 2480 °F at 760 mmHg (NTP, 1992)
    • 1383 °C
    • 1360 °C

    Flash point

    • -126.26 ˚C est.

    Solubility expt.

    • Very soluble (NTP, 1992)
    • 84.5 g/100 g water at 25 °C; soluble in ethanol, acetone, pyridine
    • 25.10 G SOL IN 100 CC ALC @ 30 °C; 42.36 G SOL IN 100 CC METHANOL @ 25 °C; 4.11 G SOL IN 100 CC ACETONE @ 25 °C; 0.538 G SOL IN 100 CC AMMONIUM HYDROXIDE @ 33.9 °C
    • Very soluble in water alcohols, ether, pyridine, nitrobenzene
    • In water (g/100g): 83.2 at 20 °C, 89.8 at 40 °C, 98.4 at 60 °C, 111.9 at 80 °C, 128.3 at 100 °C; in ethanol: 2.5 g/100g at 25 °C; in methanol: 17 g/100g at 25 °C
    • Solubility in water, g/100ml: 76.9

  • Synonyms

    • LITHIUM CHLORIDE
    • 7447-41-8
    • chlorure de lithium
    • Chlorku litu
    • Lithium chloride (LiCl)
    • DTXSID2025509
    • CHEBI:48607
    • LITHIUM MURIATICUM
    • G4962QA067
    • NSC-327172
    • Chloride, Lithium
    • RefChem:5956
    • DTXCID105509
    • Bestmade Natural Products Lithium Chloride (Lith Mur)
    • 231-212-3
    • 629-585-6
    • LiCl
    • Lithiumchloride
    • lithium;chloride
    • ClLi
    • Lithium chloride (powder)
    • MFCD00011078
    • Lithium Cholride
    • Lithium Chloride, Anhydrous
    • Lithium chloride, 99%
    • Lithium chloride, ultra dry
    • CHEMBL69710
    • NSC327172
    • chlorolithium
    • Lithiumchlorid
    • Lithium chloride, for molecular biology, 99%
    • Chlorku litu [Polish]
    • Luthium chloride
    • Chlorure de lithium [French]
    • CCRIS 5924
    • HSDB 4281
    • EINECS 231-212-3
    • NSC 327172
    • LithiumChlorideGr(Anhydrous)
    • 2M Lithium Chloride Electrolyte, Electrode Filling Solution
    • Lithium Chloride (2.3% in Tetrahydrofuran, ca. 0.5mol/L)
    • lithim chloride
    • lithii chloridum
    • Lithium chloride, anhydrous, chunks, 99.99% trace metals basis
    • cloruro de litio
    • UNII-G4962QA067
    • Lithium chloride anhydrous
    • Lopac-L-4408
    • MolMap_000071
    • WLN: LI G
    • EC 231-212-3
    • SCHEMBL6309
    • Lithium chloride, ACS grade
    • Lopac0_000604
    • LITHIUM CHLORIDE [MI]
    • Lithium chloride battery grade
    • Lithium chloride, ACS reagent
    • orb2893618
    • SCHEMBL2721849
    • LITHIUM CHLORIDE [HSDB]
    • Lithium chloride anhyrous powder
    • HY-Y0649D
    • LITHIUM MURIATICUM [HPUS]
    • LITHIUM CHLORIDE [WHO-DD]
    • Lithium chloride, 3-5% in THF
    • HMS3261J10
    • HMS5087H09
    • HY-Y0649
    • Tox21_500604
    • BDBM50494542
    • AKOS015902822
    • AKOS015950647
    • AKOS024438070
    • CCG-204693
    • FL31857
    • lithium chloride, gamma irradiated, 8m
    • LP00604
    • SDCCGSBI-0050586.P002
    • Lithium chloride, ACS reagent, >=99%
    • Lithium chloride, ReagentPlus(R), 99%
    • NCGC00015607-01
    • NCGC00015607-02
    • NCGC00015607-03
    • NCGC00015607-04
    • NCGC00015607-07
    • NCGC00093980-01
    • NCGC00093980-02
    • NCGC00261289-01
    • BP-13612
    • SY002997
    • Lithium chloride, Vetec(TM) reagent grade
    • 7447-41-8(THF)
    • CS-0015406
    • CS-0694672
    • EU-0100604
    • L0204
    • L0222
    • Lithium chloride, Trace metals grade 99.9%
    • NS00075680
    • L 4408
    • L-0300
    • Lithium chloride, SAJ first grade, >=98.0%
    • Lithium chloride, for molecular biology, >=99%
    • Lithium chloride, SAJ special grade, >=99.0%
    • A838146
    • F091451
    • Lithium chloride, BioXtra, >=99.0% (titration)
    • Q422930
    • SR-01000076252
    • SR-01000076252-1
    • Lithium chloride, powder, >=99.99% trace metals basis
    • Lithium chloride, puriss. p.a., anhydrous, >=99.0% (AT)
    • Standard substance for lithium ion composition analysis in water
    • Lithium chloride, anhydrous, beads, -10 mesh, >=99.9% trace metals basis
    • Lithium chloride, anhydrous, beads, -10 mesh, 99.998% trace metals basis
    • Lithium chloride, puriss. p.a., ACS reagent, anhydrous, >=99.0% (AT)
    • Lithium chloride, anhydrous, free-flowing, Redi-Dri(TM), ACS reagent, >=99%
    • Lithium chloride, anhydrous, free-flowing, Redi-Dri(TM), ReagentPlus(R), 99%
    • Lithium chloride, BioUltra, for molecular biology, anhydrous, >=99.0% (AT)
    • 7447-41-8

  • Applications

    Lithium chloride (CAS 7447-41-8) is widely used as a desiccant for solvents and gas streams in chemical processing and electronics manufacturing; it serves as a flux for metal brazing and soldering and for metal finishing; it is employed as a reagent and processing aid in organic synthesis, providing Li+ and helping stabilize organolithium reagents in lithiation procedures; it can be a component in specialty high-temperature molten-salt electrolytes for electrochemical processing and energy storage applications; and it is used as a flux in ceramics and glassmaking to adjust melting behavior during processing.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 31.55
    methanol 30.16
    isopropanol 19.21
    water 0.29
    ethyl acetate 15.78
    n-propanol 21.71
    acetone 28.98
    n-butanol 18.96
    acetonitrile 18.94
    DMF 40.0
    toluene 6.66
    isobutanol 13.95
    1,4-dioxane 28.46
    methyl acetate 16.73
    THF 34.15
    2-butanone 19.43
    n-pentanol 14.13
    sec-butanol 16.16
    n-hexane 4.18
    ethylene glycol 11.8
    NMP 34.73
    cyclohexane 3.41
    DMSO 39.08
    n-butyl acetate 16.62
    n-octanol 11.41
    chloroform 21.55
    n-propyl acetate 11.58
    acetic acid 26.37
    dichloromethane 17.53
    cyclohexanone 25.44
    propylene glycol 11.52
    isopropyl acetate 8.51
    DMAc 20.18
    2-ethoxyethanol 16.08
    isopentanol 13.89
    n-heptane 3.73
    ethyl formate 10.05
    1,2-dichloroethane 14.02
    n-hexanol 20.29
    2-methoxyethanol 27.61
    isobutyl acetate 7.32
    tetrachloromethane 5.0
    n-pentyl acetate 9.21
    transcutol 50.15
    n-heptanol 10.55
    ethylbenzene 4.3
    MIBK 9.7
    2-propoxyethanol 24.39
    tert-butanol 19.3
    MTBE 13.64
    2-butoxyethanol 14.84
    propionic acid 20.01
    o-xylene 4.72
    formic acid 9.73
    diethyl ether 18.14
    m-xylene 5.17
    p-xylene 5.15
    chlorobenzene 9.43
    dimethyl carbonate 7.19
    n-octane 1.57
    formamide 13.13
    cyclopentanone 34.11
    2-pentanone 17.39
    anisole 9.88
    cyclopentyl methyl ether 18.24
    gamma-butyrolactone 31.54
    1-methoxy-2-propanol 22.19
    pyridine 18.79
    3-pentanone 12.18
    furfural 23.51
    n-dodecane 1.37
    diethylene glycol 20.11
    diisopropyl ether 5.66
    tert-amyl alcohol 15.6
    acetylacetone 14.69
    n-hexadecane 1.48
    acetophenone 9.17
    methyl propionate 13.6
    isopentyl acetate 12.34
    trichloroethylene 23.22
    n-nonanol 9.06
    cyclohexanol 14.09
    benzyl alcohol 8.14
    2-ethylhexanol 11.41
    isooctanol 7.85
    dipropyl ether 12.71
    1,2-dichlorobenzene 8.66
    ethyl lactate 6.48
    propylene carbonate 16.68
    n-methylformamide 19.87
    2-pentanol 13.39
    n-pentane 3.86
    1-propoxy-2-propanol 18.6
    1-methoxy-2-propyl acetate 13.41
    2-(2-methoxypropoxy) propanol 12.57
    mesitylene 3.58
    ε-caprolactone 20.66
    p-cymene 4.03
    epichlorohydrin 23.77
    1,1,1-trichloroethane 12.85
    2-aminoethanol 17.24
    morpholine-4-carbaldehyde 29.55
    sulfolane 34.7
    2,2,4-trimethylpentane 1.79
    2-methyltetrahydrofuran 25.86
    n-hexyl acetate 14.31
    isooctane 1.56
    2-(2-butoxyethoxy)ethanol 18.62
    sec-butyl acetate 7.22
    tert-butyl acetate 10.34
    decalin 2.07
    glycerin 14.6
    diglyme 29.05
    acrylic acid 18.54
    isopropyl myristate 5.83
    n-butyric acid 19.69
    acetyl acetate 9.09
    di(2-ethylhexyl) phthalate 5.38
    ethyl propionate 9.14
    nitromethane 30.55
    1,2-diethoxyethane 16.49
    benzonitrile 10.74
    trioctyl phosphate 4.78
    1-bromopropane 10.87
    gamma-valerolactone 31.67
    n-decanol 6.89
    triethyl phosphate 4.88
    4-methyl-2-pentanol 7.58
    propionitrile 13.9
    vinylene carbonate 14.33
    1,1,2-trichlorotrifluoroethane 17.55
    DMS 9.53
    cumene 3.36
    2-octanol 7.54
    2-hexanone 13.48
    octyl acetate 7.61
    limonene 6.67
    1,2-dimethoxyethane 21.2
    ethyl orthosilicate 4.89
    tributyl phosphate 5.48
    diacetone alcohol 15.08
    N,N-dimethylaniline 6.85
    acrylonitrile 16.95
    aniline 10.06
    1,3-propanediol 19.52
    bromobenzene 8.82
    dibromomethane 14.08
    1,1,2,2-tetrachloroethane 18.06
    2-methyl-cyclohexyl acetate 7.86
    tetrabutyl urea 7.33
    diisobutyl methanol 6.41
    2-phenylethanol 10.81
    styrene 5.7
    dioctyl adipate 7.28
    dimethyl sulfate 10.23
    ethyl butyrate 9.86
    methyl lactate 9.24
    butyl lactate 8.23
    diethyl carbonate 6.24
    propanediol butyl ether 15.02
    triethyl orthoformate 6.89
    p-tert-butyltoluene 4.21
    methyl 4-tert-butylbenzoate 9.7
    morpholine 31.42
    tert-butylamine 13.39
    n-dodecanol 5.42
    dimethoxymethane 19.29
    ethylene carbonate 11.54
    cyrene 10.36
    2-ethoxyethyl acetate 12.05
    2-ethylhexyl acetate 10.16
    1,2,4-trichlorobenzene 9.87
    4-methylpyridine 16.77
    dibutyl ether 10.44
    2,6-dimethyl-4-heptanol 6.41
    DEF 18.82
    dimethyl isosorbide 17.15
    tetrachloroethylene 13.33
    eugenol 10.58
    triacetin 11.44
    span 80 12.4
    1,4-butanediol 8.94
    1,1-dichloroethane 13.86
    2-methyl-1-pentanol 11.42
    methyl formate 13.29
    2-methyl-1-butanol 13.21
    n-decane 2.13
    butyronitrile 13.81
    3,7-dimethyl-1-octanol 9.18
    1-chlorooctane 6.77
    1-chlorotetradecane 2.91
    n-nonane 2.26
    undecane 1.68
    tert-butylcyclohexane 2.26
    cyclooctane 1.56
    cyclopentanol 17.72
    tetrahydropyran 24.97
    tert-amyl methyl ether 11.13
    2,5,8-trioxanonane 20.52
    1-hexene 10.43
    2-isopropoxyethanol 12.31
    2,2,2-trifluoroethanol 8.78
    methyl butyrate 12.42

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
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Rinse-off products applied to the hair with some hand contact
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Category 2
Products applied to the axillae
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Leave-on products applied to the hair with some hand contact
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Category 3
Products applied to the face/body using fingertips
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Products with significant anogenital exposure
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Category 4
Products related to fine fragrance
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Products with body and hand exposure, primarily rinse off
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Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
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Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
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