Ferbam

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  • Identifiers

    CAS number
    14484-64-1

    Molecular formula
    C9H18FeN3S6

    SMILES
    CN(C)C(=S)[S-].CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Fe+3]

    Safety labels

    Irritant
    Irritant

    Environmental Hazard
    Environmental

  • Odor profile

    Fragrance
    Sulfurous 58.3%
    Cheesy 38.72%
    Meaty 34.13%
    Odorless 31.94%
    Savory 31.8%
    Onion 30.77%
    Pungent 27.7%
    Roasted 27.24%
    Garlic 25.77%
    Cooked 25.66%

     

    Flavor
    Sulfurous 27.31%
    Roasted 26.39%
    Cooked 26.29%
    Sulfury 25.54%
    Onion 24.72%
    Odorless 20.98%
    Acrid 20.85%
    Meaty 20.79%
    Cabbage 20.41%
    Taco 20.13%

     

    Odor impact est.
    Low

  • Properties

    pKa est.
    4.49 (weak acid)

    Molecular weight
    416.5 g/mol

    Melting point expt.

    • greater than 356 °F (Decomposes) (NIOSH, 2024)
    • 180 °C
    • >356 °F (decomposes)
    • >356 °F (Decomposes)

    Boiling point

    • Decomposes (NIOSH, 2024)
    • decomposes
    • Decomposes

    Flash point

    • 58.13 ˚C est.

    Solubility expt.

    • 0.01 % (NIOSH, 2024)
    • Usually readily dispersible but very slightly soluble in water
    • Soluble in Me2CO3, trichlormethane, pyridene, and acetonitrile
    • In water, 130 mg/L at 25 °C
    • Solubility in water: none
    • 0.01%

  • Synonyms

    • Ferbam
    • 14484-64-1
    • Ferric dimethyldithiocarbamate
    • Iron(III) dimethyldithiocarbamate
    • Cormate
    • Fermacide
    • Hokmate
    • Trimanzone
    • Ferbam [ISO]
    • Ferbame [ISO-French]
    • Iron, tris(dimethyldithiocarbamato)-
    • DTXSID8020624
    • FERBAM [HSDB]
    • FERBAM [IARC]
    • FERBAM [MI]
    • DTXCID20624
    • SKM8W5154H
    • Ferbeck
    • Tris(N,N-dimethyldithiocarbamato)iron(III)
    • Aaferzimag
    • Ferbame (ISO-French)
    • Fermocide
    • Knockmate
    • Niacide
    • FERBAM (IARC)
    • Ferbam, iron salt
    • Caswell No. 458
    • Ferbam [BSI:ISO]
    • Ferbame
    • Fermate ferbam fungicide
    • Sup'R-flo ferbam flowable
    • (OC-6-11)-TRIS(DIMETHYLCARBAMODITHIOATO-.KAPPA.S,.KAPPA.S')IRON
    • CHEBI:5015
    • iron(3+) dimethyldithiocarbamate
    • Ferbam 76
    • CCRIS 1031
    • HSDB 1645
    • Iron tris(dimethyldithiocarbamate)
    • iron(3+) tris(dimethylcarbamodithioate)
    • EINECS 238-484-2
    • EPA Pesticide Chemical Code 034801
    • Dimethyldithiocarbamic acid, ferric salt
    • Tris(dimethylcarbamodithioato-S,S')iron
    • UNII-SKM8W5154H
    • Ferban
    • Ferric dimethyl dithiocarbamate
    • AI3-14689
    • iron N,N-dimethyldithiocarbamate
    • Carbamic acid, dimethyldithio-, iron(3+) salt
    • Tris(dimethyl)dithiocarbamato)-iron
    • (OC-6-11)-tris(dimethylcarbamodithioato-S,S')iron
    • iron(3+) tris(dimethyldithiocarbamate)
    • Ferric dimethyldithioate
    • Sup'Rflo ferbam flowable
    • Ferbam (ACGIH:OSHA)
    • WHDGWKAJBYRJJL-UHFFFAOYSA-K
    • Iron, tris(dimethyldithiocarbamato)
    • Tox21_202589
    • Iron, tris(dimethylcarbamodithioato-kappaS,kappaS')-, (OC-6-11)-
    • AKOS037654004
    • Iron, tris(dimethylcarbamodithioato-.kappa.S,.kappa.S')-, (OC-6-11)-
    • Tris(dimethylcarbamodithioatoS,S')iron
    • Dimethyldithiocarbamic Acid Ferric Salt
    • Tris(dimethylcarbamodithioate-S,S')iron
    • USEPA/OPP Pesticide Code: 034801
    • Carbamic acid, dimethyldithio, iron salt
    • NCGC00163965-01
    • NCGC00163965-02
    • NCGC00260137-01
    • Eisen(III)tris(N,Ndimethyldithiocarbamat)
    • Tris(N,Ndimethyldithiocarbamato)iron(III)
    • CAS-14484-64-1
    • Tris(N,Ndimethyldithiocarbamato) iron(111)
    • Carbamic acid, dimethyldithio-,iron(3+)salt
    • Carbamodithioic acid, dimethyl, iron complex
    • D1267
    • Dimethyl-carbamodithioic acid iron(3+) salt
    • NS00087127
    • Carbamic acid, dimethyldithio, iron(3+) salt
    • (OC611)tris(dimethylcarbamodithioatoS,S')iron
    • E78914
    • Q426535
    • (OC-6-11)-TRIS(DIMETHYLCARBAMODITHIOATO-KAPPAS,KAPPAS')IRON
    • 238-484-2

  • Applications

    Ferbam (CAS 14484-64-1) is a dithiocarbamate fungicide used in agriculture to control fungal diseases on crops. Typical applications include field spray programs for fruits, vegetables, potatoes, grapes and cereals; seed treatments to protect emerging seedlings from fungal pathogens; post-harvest protection for certain stored crops; and use in greenhouse production and ornamental nursery settings. Use is generally implemented as part of integrated crop protection programs and subject to local regulations and formulation limits.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 37.02
    methanol 59.66
    isopropanol 23.46
    water 8.9
    ethyl acetate 48.9
    n-propanol 25.61
    acetone 108.68
    n-butanol 19.89
    acetonitrile 84.84
    DMF 210.08
    toluene 23.12
    isobutanol 17.87
    1,4-dioxane 107.76
    methyl acetate 76.62
    THF 105.21
    2-butanone 64.46
    n-pentanol 14.57
    sec-butanol 19.77
    n-hexane 1.22
    ethylene glycol 35.61
    NMP 226.35
    cyclohexane 4.54
    DMSO 199.21
    n-butyl acetate 34.86
    n-octanol 14.51
    chloroform 123.64
    n-propyl acetate 29.97
    acetic acid 101.47
    dichloromethane 100.68
    cyclohexanone 79.98
    propylene glycol 23.72
    isopropyl acetate 30.34
    DMAc 212.2
    2-ethoxyethanol 49.37
    isopentanol 15.46
    n-heptane 3.98
    ethyl formate 51.27
    1,2-dichloroethane 60.17
    n-hexanol 20.41
    2-methoxyethanol 98.83
    isobutyl acetate 20.08
    tetrachloromethane 37.04
    n-pentyl acetate 27.58
    transcutol 93.9
    n-heptanol 15.27
    ethylbenzene 11.01
    MIBK 24.33
    2-propoxyethanol 55.42
    tert-butanol 33.63
    MTBE 28.38
    2-butoxyethanol 37.96
    propionic acid 47.14
    o-xylene 23.48
    formic acid 76.54
    diethyl ether 27.98
    m-xylene 17.0
    p-xylene 18.95
    chlorobenzene 48.82
    dimethyl carbonate 42.14
    n-octane 2.01
    formamide 111.71
    cyclopentanone 114.84
    2-pentanone 40.9
    anisole 42.99
    cyclopentyl methyl ether 41.18
    gamma-butyrolactone 124.17
    1-methoxy-2-propanol 61.18
    pyridine 91.38
    3-pentanone 41.92
    furfural 169.8
    n-dodecane 2.04
    diethylene glycol 67.76
    diisopropyl ether 9.68
    tert-amyl alcohol 26.65
    acetylacetone 76.93
    n-hexadecane 2.34
    acetophenone 55.2
    methyl propionate 50.71
    isopentyl acetate 30.59
    trichloroethylene 140.58
    n-nonanol 15.05
    cyclohexanol 24.78
    benzyl alcohol 36.39
    2-ethylhexanol 16.69
    isooctanol 13.07
    dipropyl ether 21.79
    1,2-dichlorobenzene 52.82
    ethyl lactate 26.6
    propylene carbonate 69.56
    n-methylformamide 94.32
    2-pentanol 13.36
    n-pentane 2.35
    1-propoxy-2-propanol 41.94
    1-methoxy-2-propyl acetate 48.37
    2-(2-methoxypropoxy) propanol 47.94
    mesitylene 11.46
    ε-caprolactone 67.55
    p-cymene 16.48
    epichlorohydrin 101.63
    1,1,1-trichloroethane 86.13
    2-aminoethanol 35.4
    morpholine-4-carbaldehyde 178.2
    sulfolane 178.19
    2,2,4-trimethylpentane 2.29
    2-methyltetrahydrofuran 67.43
    n-hexyl acetate 30.81
    isooctane 1.33
    2-(2-butoxyethoxy)ethanol 48.35
    sec-butyl acetate 20.98
    tert-butyl acetate 35.36
    decalin 3.08
    glycerin 52.93
    diglyme 92.61
    acrylic acid 63.49
    isopropyl myristate 17.78
    n-butyric acid 42.37
    acetyl acetate 53.55
    di(2-ethylhexyl) phthalate 22.36
    ethyl propionate 28.88
    nitromethane 214.46
    1,2-diethoxyethane 38.29
    benzonitrile 50.19
    trioctyl phosphate 15.89
    1-bromopropane 24.56
    gamma-valerolactone 147.12
    n-decanol 12.54
    triethyl phosphate 26.46
    4-methyl-2-pentanol 9.22
    propionitrile 40.58
    vinylene carbonate 72.52
    1,1,2-trichlorotrifluoroethane 131.1
    DMS 41.6
    cumene 10.15
    2-octanol 10.45
    2-hexanone 27.98
    octyl acetate 22.63
    limonene 22.98
    1,2-dimethoxyethane 81.34
    ethyl orthosilicate 23.87
    tributyl phosphate 18.96
    diacetone alcohol 49.06
    N,N-dimethylaniline 35.86
    acrylonitrile 69.53
    aniline 43.1
    1,3-propanediol 39.77
    bromobenzene 44.63
    dibromomethane 58.51
    1,1,2,2-tetrachloroethane 106.78
    2-methyl-cyclohexyl acetate 32.62
    tetrabutyl urea 26.33
    diisobutyl methanol 12.73
    2-phenylethanol 39.59
    styrene 16.16
    dioctyl adipate 28.95
    dimethyl sulfate 93.19
    ethyl butyrate 31.66
    methyl lactate 45.41
    butyl lactate 26.18
    diethyl carbonate 26.97
    propanediol butyl ether 31.52
    triethyl orthoformate 27.22
    p-tert-butyltoluene 17.18
    methyl 4-tert-butylbenzoate 49.11
    morpholine 94.43
    tert-butylamine 19.39
    n-dodecanol 10.57
    dimethoxymethane 78.27
    ethylene carbonate 52.12
    cyrene 66.86
    2-ethoxyethyl acetate 41.79
    2-ethylhexyl acetate 26.23
    1,2,4-trichlorobenzene 76.52
    4-methylpyridine 77.16
    dibutyl ether 16.02
    2,6-dimethyl-4-heptanol 12.73
    DEF 65.55
    dimethyl isosorbide 87.25
    tetrachloroethylene 82.06
    eugenol 49.1
    triacetin 49.11
    span 80 39.51
    1,4-butanediol 18.76
    1,1-dichloroethane 60.34
    2-methyl-1-pentanol 13.11
    methyl formate 89.47
    2-methyl-1-butanol 15.76
    n-decane 2.93
    butyronitrile 31.54
    3,7-dimethyl-1-octanol 16.24
    1-chlorooctane 12.08
    1-chlorotetradecane 6.55
    n-nonane 2.56
    undecane 2.39
    tert-butylcyclohexane 2.91
    cyclooctane 1.75
    cyclopentanol 35.49
    tetrahydropyran 51.63
    tert-amyl methyl ether 25.11
    2,5,8-trioxanonane 77.69
    1-hexene 5.2
    2-isopropoxyethanol 34.13
    2,2,2-trifluoroethanol 74.74
    methyl butyrate 35.93

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction