Arsenic trisulfide

  • Identifiers

    Molecular formula
    As2S3

    SMILES
    S1[As]2S[As]1S2

    Safety labels

    Acute Toxic
    Acute Toxic

    Irritant
    Irritant

    Health Hazard
    Health

  • Odor profile

    Fragrance
    Odorless 38.71%
    Meaty 24.49%
    Fishy 23.37%
    Mushroom 19.35%
    Cooked 19.08%
    Sulfurous 17.34%
    Roasted 16.51%
    Nutty 13.72%
    Pungent 12.84%
    Animal 12.57%

     

  • Properties

    pKa est.
    -3.94 (strong acid)

    Molecular weight
    246.0 g/mol

    Melting point expt.

    • 572 °F (USCG, 1999)
    • 310 °C

    Boiling point

    • 707 °C

    Flash point

    • 186.72 ˚C est.

    Solubility expt.

    • Sol in alkalies, carbonates, alkali sulfides; slowly sol in hot HCl
    • Sol in alcohol; slightly sol in hot water
    • 0.00005 g/100 ml water at 18 °C

  • Synonyms

    • ARSENIC TRISULFIDE
    • Arsenic trisulphide
    • Diarsenic trisulfide
    • Arsenic sesquisulfide
    • Diarsenic trisulphide
    • Arsenic sesquisulphide
    • Yellow arsenic sulfide
    • Arsenic(III) sulphide
    • Sekio
    • Shio
    • Arsenic Yellow
    • Arsenic sulphide
    • Arsenous sulfide
    • Arsenic Red
    • Arsenious sulfide
    • Arsenic tersulfide
    • Arsenious sulphide
    • King's Gold
    • Arsenic tersulphide
    • 44SIJ800OX
    • Arsenic Sulfide Yellow
    • Arsenic sulphides, natural
    • UNII-44SIJ800OX
    • CI 77086
    • YELLOW ARSENIC SULPHIDE
    • HSDB 428
    • C.I. 77086
    • Arsenic sulfide (As0.4S0.6)
    • DTXSID50274153
    • ARSENIC SULPHIDE (AS2S3)
    • ARSENICUM SULPHURATUM FLAVUM
    • EINECS 215-117-4
    • Arsenic sulfide (As2S3), (yellow)
    • AI3-01006
    • NATURAL ORPIMENT
    • ARSENOUS SULPHIDE
    • Pesticide Code: 006901
    • ARSENIC TRISULFIDE [MI]
    • ARSENIC TRISULFIDE [HSDB]
    • DTXCID80196556
    • UKUVVAMSXXBMRX-UHFFFAOYSA-N
    • ARSENIC SULFIDE (ASS1.5)
    • ARSENIC TRISULFIDE (AS2S3)
    • ARSENIC TRISULFIDE [WHO-DD]
    • NA1557
    • ARSENIC SESQUISULFIDE (AS2S3)
    • Arsenic sulfide [NA1557] [Poison]
    • Arsenic trisulfide [NA1557] [Poison]
    • ARSENICUM SULPHURATUM FLAVUM [HPUS]
    • Q425065
  • Applications

    Arsenic trisulfide is primarily used as a precursor for chalcogenide and infrared-transmitting glasses, enabling infrared optics and fiber applications. It is also used in thin-film coatings and optical films to improve infrared transmission and performance in photonic devices. Historically, the compound served as a yellow-orange pigment (orpiment) in paints and ceramics and may appear in vintage ceramic coloration. Additionally, it can act as a precursor or additive for chalcogenide glass systems and other photonic materials when processed under controlled conditions. Use is subject to regulatory and safety considerations due to toxicity.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 75.47
    methanol 83.68
    isopropanol 73.85
    water 5.39
    ethyl acetate 99.3
    n-propanol 68.27
    acetone 154.69
    n-butanol 72.82
    acetonitrile 58.59
    DMF 396.55
    toluene 79.52
    isobutanol 57.34
    1,4-dioxane 203.47
    methyl acetate 99.24
    THF 355.93
    2-butanone 113.65
    n-pentanol 60.01
    sec-butanol 63.61
    n-hexane 15.6
    ethylene glycol 56.04
    NMP 374.45
    cyclohexane 27.01
    DMSO 410.61
    n-butyl acetate 91.37
    n-octanol 68.74
    chloroform 264.74
    n-propyl acetate 76.61
    acetic acid 106.84
    dichloromethane 206.58
    cyclohexanone 192.53
    propylene glycol 56.82
    isopropyl acetate 87.97
    DMAc 260.3
    2-ethoxyethanol 107.49
    isopentanol 63.89
    n-heptane 23.68
    ethyl formate 91.2
    1,2-dichloroethane 144.44
    n-hexanol 75.57
    2-methoxyethanol 179.0
    isobutyl acetate 62.91
    tetrachloromethane 76.21
    n-pentyl acetate 103.25
    transcutol 186.46
    n-heptanol 71.05
    ethylbenzene 45.02
    MIBK 93.69
    2-propoxyethanol 147.04
    tert-butanol 90.28
    MTBE 78.21
    2-butoxyethanol 120.07
    propionic acid 82.47
    o-xylene 65.42
    formic acid 64.65
    diethyl ether 90.37
    m-xylene 67.98
    p-xylene 55.65
    chlorobenzene 114.17
    dimethyl carbonate 107.92
    n-octane 16.4
    formamide 94.89
    cyclopentanone 283.44
    2-pentanone 119.12
    anisole 98.68
    cyclopentyl methyl ether 165.86
    gamma-butyrolactone 278.52
    1-methoxy-2-propanol 165.62
    pyridine 169.97
    3-pentanone 99.1
    furfural 294.36
    n-dodecane 15.32
    diethylene glycol 141.21
    diisopropyl ether 51.72
    tert-amyl alcohol 73.29
    acetylacetone 166.68
    n-hexadecane 17.33
    acetophenone 109.52
    methyl propionate 110.43
    isopentyl acetate 84.56
    trichloroethylene 260.53
    n-nonanol 66.27
    cyclohexanol 91.59
    benzyl alcohol 91.18
    2-ethylhexanol 58.83
    isooctanol 61.98
    dipropyl ether 79.81
    1,2-dichlorobenzene 127.4
    ethyl lactate 68.16
    propylene carbonate 169.17
    n-methylformamide 139.04
    2-pentanol 65.95
    n-pentane 21.75
    1-propoxy-2-propanol 119.28
    1-methoxy-2-propyl acetate 124.62
    2-(2-methoxypropoxy) propanol 100.97
    mesitylene 55.88
    ε-caprolactone 159.7
    p-cymene 48.67
    epichlorohydrin 242.76
    1,1,1-trichloroethane 156.33
    2-aminoethanol 68.2
    morpholine-4-carbaldehyde 302.79
    sulfolane 402.25
    2,2,4-trimethylpentane 15.44
    2-methyltetrahydrofuran 190.38
    n-hexyl acetate 108.72
    isooctane 14.93
    2-(2-butoxyethoxy)ethanol 132.86
    sec-butyl acetate 61.68
    tert-butyl acetate 103.87
    decalin 17.26
    glycerin 100.96
    diglyme 220.89
    acrylic acid 96.77
    isopropyl myristate 65.9
    n-butyric acid 99.67
    acetyl acetate 91.84
    di(2-ethylhexyl) phthalate 68.81
    ethyl propionate 77.06
    nitromethane 162.61
    1,2-diethoxyethane 101.81
    benzonitrile 105.13
    trioctyl phosphate 61.04
    1-bromopropane 85.84
    gamma-valerolactone 305.56
    n-decanol 55.75
    triethyl phosphate 60.28
    4-methyl-2-pentanol 53.56
    propionitrile 60.79
    vinylene carbonate 163.41
    1,1,2-trichlorotrifluoroethane 219.97
    DMS 101.94
    cumene 38.65
    2-octanol 64.01
    2-hexanone 84.16
    octyl acetate 81.07
    limonene 62.53
    1,2-dimethoxyethane 166.25
    ethyl orthosilicate 58.62
    tributyl phosphate 60.14
    diacetone alcohol 127.36
    N,N-dimethylaniline 88.95
    acrylonitrile 82.59
    aniline 104.01
    1,3-propanediol 88.53
    bromobenzene 118.78
    dibromomethane 156.9
    1,1,2,2-tetrachloroethane 234.56
    2-methyl-cyclohexyl acetate 79.85
    tetrabutyl urea 82.51
    diisobutyl methanol 51.25
    2-phenylethanol 97.61
    styrene 55.24
    dioctyl adipate 84.64
    dimethyl sulfate 204.74
    ethyl butyrate 77.93
    methyl lactate 106.36
    butyl lactate 88.9
    diethyl carbonate 60.52
    propanediol butyl ether 109.86
    triethyl orthoformate 71.57
    p-tert-butyltoluene 52.74
    methyl 4-tert-butylbenzoate 131.87
    morpholine 191.66
    tert-butylamine 62.86
    n-dodecanol 47.54
    dimethoxymethane 242.64
    ethylene carbonate 128.31
    cyrene 147.44
    2-ethoxyethyl acetate 125.98
    2-ethylhexyl acetate 77.4
    1,2,4-trichlorobenzene 151.28
    4-methylpyridine 154.89
    dibutyl ether 65.58
    2,6-dimethyl-4-heptanol 51.25
    DEF 150.35
    dimethyl isosorbide 194.17
    tetrachloroethylene 169.71
    eugenol 131.84
    triacetin 118.53
    span 80 114.27
    1,4-butanediol 52.1
    1,1-dichloroethane 127.65
    2-methyl-1-pentanol 55.96
    methyl formate 137.58
    2-methyl-1-butanol 58.62
    n-decane 21.54
    butyronitrile 69.36
    3,7-dimethyl-1-octanol 59.93
    1-chlorooctane 54.64
    1-chlorotetradecane 32.1
    n-nonane 19.96
    undecane 17.75
    tert-butylcyclohexane 17.57
    cyclooctane 16.17
    cyclopentanol 117.52
    tetrahydropyran 151.72
    tert-amyl methyl ether 76.78
    2,5,8-trioxanonane 176.75
    1-hexene 35.47
    2-isopropoxyethanol 89.42
    2,2,2-trifluoroethanol 77.61
    methyl butyrate 90.14

    Scent© AI

1 of 4
Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
No restriction
Category 2
Products applied to the axillae
No restriction Category 7B
Leave-on products applied to the hair with some hand contact
No restriction
Category 3
Products applied to the face/body using fingertips
No restriction Category 8
Products with significant anogenital exposure
No restriction
Category 4
Products related to fine fragrance
No restriction Category 9
Products with body and hand exposure, primarily rinse off
No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
No restriction Category 10A
Household care products with mostly hand contact
No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
No restriction
Category 5D
Baby Creams, baby Oils and baby talc
No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
No restriction
Category 6
Products with oral and lip exposure
No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
No restriction