Arsenic trisulfide
-
Identifiers
Molecular formula
As2S3SMILES
S1[As]2S[As]1S2
Safety labels
Acute Toxic
Irritant
Health -
Odor profile
Fragrance Odorless 38.71% Meaty 24.49% Fishy 23.37% Mushroom 19.35% Cooked 19.08% Sulfurous 17.34% Roasted 16.51% Nutty 13.72% Pungent 12.84% Animal 12.57% -
Properties
pKa est.
-3.94 (strong acid)Molecular weight
246.0 g/molMelting point expt.
- 572 °F (USCG, 1999)
- 310 °C
Boiling point
- 707 °C
Flash point
- 186.72 ˚C est.
Solubility expt.
- Sol in alkalies, carbonates, alkali sulfides; slowly sol in hot HCl
- Sol in alcohol; slightly sol in hot water
- 0.00005 g/100 ml water at 18 °C
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Synonyms
- ARSENIC TRISULFIDE
- Arsenic trisulphide
- Diarsenic trisulfide
- Arsenic sesquisulfide
- Diarsenic trisulphide
- Arsenic sesquisulphide
- Yellow arsenic sulfide
- Arsenic(III) sulphide
- Sekio
- Shio
- Arsenic Yellow
- Arsenic sulphide
- Arsenous sulfide
- Arsenic Red
- Arsenious sulfide
- Arsenic tersulfide
- Arsenious sulphide
- King's Gold
- Arsenic tersulphide
- 44SIJ800OX
- Arsenic Sulfide Yellow
- Arsenic sulphides, natural
- UNII-44SIJ800OX
- CI 77086
- YELLOW ARSENIC SULPHIDE
- HSDB 428
- C.I. 77086
- Arsenic sulfide (As0.4S0.6)
- DTXSID50274153
- ARSENIC SULPHIDE (AS2S3)
- ARSENICUM SULPHURATUM FLAVUM
- EINECS 215-117-4
- Arsenic sulfide (As2S3), (yellow)
- AI3-01006
- NATURAL ORPIMENT
- ARSENOUS SULPHIDE
- Pesticide Code: 006901
- ARSENIC TRISULFIDE [MI]
- ARSENIC TRISULFIDE [HSDB]
- DTXCID80196556
- UKUVVAMSXXBMRX-UHFFFAOYSA-N
- ARSENIC SULFIDE (ASS1.5)
- ARSENIC TRISULFIDE (AS2S3)
- ARSENIC TRISULFIDE [WHO-DD]
- NA1557
- ARSENIC SESQUISULFIDE (AS2S3)
- Arsenic sulfide [NA1557] [Poison]
- Arsenic trisulfide [NA1557] [Poison]
- ARSENICUM SULPHURATUM FLAVUM [HPUS]
- Q425065
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Applications
Arsenic trisulfide is primarily used as a precursor for chalcogenide and infrared-transmitting glasses, enabling infrared optics and fiber applications. It is also used in thin-film coatings and optical films to improve infrared transmission and performance in photonic devices. Historically, the compound served as a yellow-orange pigment (orpiment) in paints and ceramics and may appear in vintage ceramic coloration. Additionally, it can act as a precursor or additive for chalcogenide glass systems and other photonic materials when processed under controlled conditions. Use is subject to regulatory and safety considerations due to toxicity.
gpt-5-nano
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Solubility @25˚C
Solvent Solubility (g/L) ethanol 75.47 methanol 83.68 isopropanol 73.85 water 5.39 ethyl acetate 99.3 n-propanol 68.27 acetone 154.69 n-butanol 72.82 acetonitrile 58.59 DMF 396.55 toluene 79.52 isobutanol 57.34 1,4-dioxane 203.47 methyl acetate 99.24 THF 355.93 2-butanone 113.65 n-pentanol 60.01 sec-butanol 63.61 n-hexane 15.6 ethylene glycol 56.04 NMP 374.45 cyclohexane 27.01 DMSO 410.61 n-butyl acetate 91.37 n-octanol 68.74 chloroform 264.74 n-propyl acetate 76.61 acetic acid 106.84 dichloromethane 206.58 cyclohexanone 192.53 propylene glycol 56.82 isopropyl acetate 87.97 DMAc 260.3 2-ethoxyethanol 107.49 isopentanol 63.89 n-heptane 23.68 ethyl formate 91.2 1,2-dichloroethane 144.44 n-hexanol 75.57 2-methoxyethanol 179.0 isobutyl acetate 62.91 tetrachloromethane 76.21 n-pentyl acetate 103.25 transcutol 186.46 n-heptanol 71.05 ethylbenzene 45.02 MIBK 93.69 2-propoxyethanol 147.04 tert-butanol 90.28 MTBE 78.21 2-butoxyethanol 120.07 propionic acid 82.47 o-xylene 65.42 formic acid 64.65 diethyl ether 90.37 m-xylene 67.98 p-xylene 55.65 chlorobenzene 114.17 dimethyl carbonate 107.92 n-octane 16.4 formamide 94.89 cyclopentanone 283.44 2-pentanone 119.12 anisole 98.68 cyclopentyl methyl ether 165.86 gamma-butyrolactone 278.52 1-methoxy-2-propanol 165.62 pyridine 169.97 3-pentanone 99.1 furfural 294.36 n-dodecane 15.32 diethylene glycol 141.21 diisopropyl ether 51.72 tert-amyl alcohol 73.29 acetylacetone 166.68 n-hexadecane 17.33 acetophenone 109.52 methyl propionate 110.43 isopentyl acetate 84.56 trichloroethylene 260.53 n-nonanol 66.27 cyclohexanol 91.59 benzyl alcohol 91.18 2-ethylhexanol 58.83 isooctanol 61.98 dipropyl ether 79.81 1,2-dichlorobenzene 127.4 ethyl lactate 68.16 propylene carbonate 169.17 n-methylformamide 139.04 2-pentanol 65.95 n-pentane 21.75 1-propoxy-2-propanol 119.28 1-methoxy-2-propyl acetate 124.62 2-(2-methoxypropoxy) propanol 100.97 mesitylene 55.88 ε-caprolactone 159.7 p-cymene 48.67 epichlorohydrin 242.76 1,1,1-trichloroethane 156.33 2-aminoethanol 68.2 morpholine-4-carbaldehyde 302.79 sulfolane 402.25 2,2,4-trimethylpentane 15.44 2-methyltetrahydrofuran 190.38 n-hexyl acetate 108.72 isooctane 14.93 2-(2-butoxyethoxy)ethanol 132.86 sec-butyl acetate 61.68 tert-butyl acetate 103.87 decalin 17.26 glycerin 100.96 diglyme 220.89 acrylic acid 96.77 isopropyl myristate 65.9 n-butyric acid 99.67 acetyl acetate 91.84 di(2-ethylhexyl) phthalate 68.81 ethyl propionate 77.06 nitromethane 162.61 1,2-diethoxyethane 101.81 benzonitrile 105.13 trioctyl phosphate 61.04 1-bromopropane 85.84 gamma-valerolactone 305.56 n-decanol 55.75 triethyl phosphate 60.28 4-methyl-2-pentanol 53.56 propionitrile 60.79 vinylene carbonate 163.41 1,1,2-trichlorotrifluoroethane 219.97 DMS 101.94 cumene 38.65 2-octanol 64.01 2-hexanone 84.16 octyl acetate 81.07 limonene 62.53 1,2-dimethoxyethane 166.25 ethyl orthosilicate 58.62 tributyl phosphate 60.14 diacetone alcohol 127.36 N,N-dimethylaniline 88.95 acrylonitrile 82.59 aniline 104.01 1,3-propanediol 88.53 bromobenzene 118.78 dibromomethane 156.9 1,1,2,2-tetrachloroethane 234.56 2-methyl-cyclohexyl acetate 79.85 tetrabutyl urea 82.51 diisobutyl methanol 51.25 2-phenylethanol 97.61 styrene 55.24 dioctyl adipate 84.64 dimethyl sulfate 204.74 ethyl butyrate 77.93 methyl lactate 106.36 butyl lactate 88.9 diethyl carbonate 60.52 propanediol butyl ether 109.86 triethyl orthoformate 71.57 p-tert-butyltoluene 52.74 methyl 4-tert-butylbenzoate 131.87 morpholine 191.66 tert-butylamine 62.86 n-dodecanol 47.54 dimethoxymethane 242.64 ethylene carbonate 128.31 cyrene 147.44 2-ethoxyethyl acetate 125.98 2-ethylhexyl acetate 77.4 1,2,4-trichlorobenzene 151.28 4-methylpyridine 154.89 dibutyl ether 65.58 2,6-dimethyl-4-heptanol 51.25 DEF 150.35 dimethyl isosorbide 194.17 tetrachloroethylene 169.71 eugenol 131.84 triacetin 118.53 span 80 114.27 1,4-butanediol 52.1 1,1-dichloroethane 127.65 2-methyl-1-pentanol 55.96 methyl formate 137.58 2-methyl-1-butanol 58.62 n-decane 21.54 butyronitrile 69.36 3,7-dimethyl-1-octanol 59.93 1-chlorooctane 54.64 1-chlorotetradecane 32.1 n-nonane 19.96 undecane 17.75 tert-butylcyclohexane 17.57 cyclooctane 16.17 cyclopentanol 117.52 tetrahydropyran 151.72 tert-amyl methyl ether 76.78 2,5,8-trioxanonane 176.75 1-hexene 35.47 2-isopropoxyethanol 89.42 2,2,2-trifluoroethanol 77.61 methyl butyrate 90.14 Scent© AI
| Maximum acceptable concentrations in the finished product (%) | |||
|---|---|---|---|
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Category 1
Products applied to the lips
|
No restriction |
Category 7A
Rinse-off products applied to the hair with some hand contact
|
No restriction |
|
Category 2
Products applied to the axillae
|
No restriction |
Category 7B
Leave-on products applied to the hair with some hand contact
|
No restriction |
|
Category 3
Products applied to the face/body using fingertips
|
No restriction |
Category 8
Products with significant anogenital exposure
|
No restriction |
|
Category 4
Products related to fine fragrance
|
No restriction |
Category 9
Products with body and hand exposure, primarily rinse off
|
No restriction |
|
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
|
No restriction |
Category 10A
Household care products with mostly hand contact
|
No restriction |
|
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
|
No restriction |
Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
|
No restriction |
|
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
|
No restriction |
Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
|
No restriction |
|
Category 5D
Baby Creams, baby Oils and baby talc
|
No restriction |
Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
|
No restriction |
|
Category 6
Products with oral and lip exposure
|
No restriction |
Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
|
No restriction |