Ammonium dithiocarbamate

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  • Identifiers

    CAS number
    513-74-6

    Molecular formula
    CH6N2S2

    SMILES
    C(=S)(N)[S-].[NH4+]

    Safety labels

    Flammable
    Flammable

  • Odor profile

    Fragrance
    Sulfurous 55.98%
    Odorless 47.84%
    Meaty 38.49%
    Garlic 32.96%
    Onion 31.05%
    Savory 30.12%
    Pungent 29.1%
    Cooked 27.8%
    Roasted 26.36%
    Alliaceous 25.9%

     

    Flavor
    Odorless 33.49%
    Mustard 26.81%
    Sulfur 26.02%
    Garlic 25.09%
    Pungent 24.89%
    Sulfurous 22.39%
    Mousy 21.4%
    Formyl 20.98%
    Rotten 20.54%
    Roasted 19.86%

     

    Odor impact est.
    Low

  • Properties

    pKa est.
    7.0 (neutral)

    Molecular weight
    110.21 g/mol

    Melting point expt.

    • 99 °C

    Flash point

    • 43.38 ˚C est.

    Solubility expt.

    • SOL IN WATER

  • Synonyms

    • AMMONIUM DITHIOCARBAMATE
    • 513-74-6
    • ammonium carbamodithioate
    • Carbamodithioic acid, monoammonium salt
    • Ammonium sulfocarbamate
    • azanium;carbamodithioate
    • UNII-VH74O7C5IH
    • Dithiocarbamic acid monoammonium salt
    • VH74O7C5IH
    • Carbamic acid, dithio-, monoammonium salt
    • HSDB 5675
    • EINECS 208-166-8
    • NSC 202959
    • Carbamodithioic acid ammonium salt (1:1)
    • DTXSID3027166
    • AMMONIUM DITHIOCARBAMATE [MI]
    • AMMONIUM DITHIOCARBAMATE [HSDB]
    • NSC-202959
    • Carbamodithioic acid, ammonium salt (1:1)
    • dithiocarbamic acid ammonium salt
    • CH6N2S2
    • SCHEMBL111884
    • DTXCID107166
    • MFCD00036377
    • AKOS009156810
    • Carbamic acid, dithio, monoammonium salt
    • CARBAMODITHIOIC ACID AMMONIUM SALT
    • FA151678
    • DB-021816
    • NS00044092
    • Carbamic acid, dithio-, monoammonium salt (8CI)
    • 208-166-8

  • Applications

    Ammonium dithiocarbamate is commonly used as a precursor in the synthesis of metal dithiocarbamate compounds, including fungicidal agents for crop protection; it may be employed as a processing aid or stabilizer in polymer formulations, notably PVC and other plastics; in coatings and inks it can act as a metal-complexing additive to improve performance such as adhesion, corrosion resistance, or pigment stability; it serves as a chelating agent in metal cleaning formulations and in electroplating baths; and it functions as an intermediate for preparing dithiocarbamate ligands and other metal complexes used in chemical synthesis and materials applications.

    gpt-5-nano

  • Solubility @25˚C

    Solvent Solubility (g/L)
    ethanol 46.56
    methanol 79.62
    isopropanol 40.47
    water 15.72
    ethyl acetate 38.15
    n-propanol 35.35
    acetone 119.36
    n-butanol 34.15
    acetonitrile 45.56
    DMF 289.8
    toluene 9.98
    isobutanol 26.94
    1,4-dioxane 72.8
    methyl acetate 50.94
    THF 139.52
    2-butanone 64.79
    n-pentanol 27.5
    sec-butanol 31.84
    n-hexane 1.04
    ethylene glycol 46.25
    NMP 134.7
    cyclohexane 1.32
    DMSO 181.91
    n-butyl acetate 30.08
    n-octanol 21.84
    chloroform 18.2
    n-propyl acetate 30.08
    acetic acid 66.6
    dichloromethane 15.0
    cyclohexanone 53.2
    propylene glycol 46.46
    isopropyl acetate 32.38
    DMAc 206.6
    2-ethoxyethanol 68.54
    isopentanol 28.17
    n-heptane 3.04
    ethyl formate 38.12
    1,2-dichloroethane 15.09
    n-hexanol 29.35
    2-methoxyethanol 110.16
    isobutyl acetate 23.43
    tetrachloromethane 5.65
    n-pentyl acetate 27.7
    transcutol 83.72
    n-heptanol 24.64
    ethylbenzene 4.98
    MIBK 38.0
    2-propoxyethanol 77.49
    tert-butanol 50.32
    MTBE 34.83
    2-butoxyethanol 54.81
    propionic acid 37.36
    o-xylene 9.42
    formic acid 65.97
    diethyl ether 30.18
    m-xylene 9.86
    p-xylene 6.53
    chlorobenzene 12.78
    dimethyl carbonate 52.37
    n-octane 1.53
    formamide 78.9
    cyclopentanone 95.69
    2-pentanone 52.36
    anisole 30.31
    cyclopentyl methyl ether 41.19
    gamma-butyrolactone 83.5
    1-methoxy-2-propanol 93.53
    pyridine 41.83
    3-pentanone 39.61
    furfural 92.2
    n-dodecane 1.58
    diethylene glycol 86.38
    diisopropyl ether 11.66
    tert-amyl alcohol 37.62
    acetylacetone 81.32
    n-hexadecane 1.7
    acetophenone 34.32
    methyl propionate 45.29
    isopentyl acetate 27.73
    trichloroethylene 29.17
    n-nonanol 20.75
    cyclohexanol 22.62
    benzyl alcohol 29.99
    2-ethylhexanol 18.62
    isooctanol 19.85
    dipropyl ether 23.59
    1,2-dichlorobenzene 11.83
    ethyl lactate 32.25
    propylene carbonate 48.67
    n-methylformamide 93.86
    2-pentanol 25.52
    n-pentane 1.82
    1-propoxy-2-propanol 58.6
    1-methoxy-2-propyl acetate 50.33
    2-(2-methoxypropoxy) propanol 52.71
    mesitylene 7.31
    ε-caprolactone 42.62
    p-cymene 8.83
    epichlorohydrin 65.11
    1,1,1-trichloroethane 16.46
    2-aminoethanol 48.41
    morpholine-4-carbaldehyde 127.36
    sulfolane 118.4
    2,2,4-trimethylpentane 1.61
    2-methyltetrahydrofuran 53.52
    n-hexyl acetate 29.26
    isooctane 1.59
    2-(2-butoxyethoxy)ethanol 58.9
    sec-butyl acetate 22.12
    tert-butyl acetate 41.45
    decalin 1.16
    glycerin 79.21
    diglyme 95.45
    acrylic acid 46.85
    isopropyl myristate 17.0
    n-butyric acid 39.66
    acetyl acetate 33.83
    di(2-ethylhexyl) phthalate 20.74
    ethyl propionate 26.7
    nitromethane 114.79
    1,2-diethoxyethane 34.55
    benzonitrile 24.09
    trioctyl phosphate 17.26
    1-bromopropane 8.29
    gamma-valerolactone 112.87
    n-decanol 16.72
    triethyl phosphate 19.24
    4-methyl-2-pentanol 19.68
    propionitrile 29.74
    vinylene carbonate 43.47
    1,1,2-trichlorotrifluoroethane 72.26
    DMS 29.21
    cumene 4.95
    2-octanol 18.06
    2-hexanone 36.83
    octyl acetate 23.06
    limonene 12.4
    1,2-dimethoxyethane 94.12
    ethyl orthosilicate 17.61
    tributyl phosphate 17.09
    diacetone alcohol 64.77
    N,N-dimethylaniline 25.9
    acrylonitrile 41.54
    aniline 25.94
    1,3-propanediol 54.38
    bromobenzene 8.12
    dibromomethane 8.86
    1,1,2,2-tetrachloroethane 25.11
    2-methyl-cyclohexyl acetate 24.56
    tetrabutyl urea 26.3
    diisobutyl methanol 14.27
    2-phenylethanol 32.05
    styrene 6.37
    dioctyl adipate 25.21
    dimethyl sulfate 81.91
    ethyl butyrate 26.4
    methyl lactate 55.26
    butyl lactate 29.5
    diethyl carbonate 20.06
    propanediol butyl ether 51.61
    triethyl orthoformate 23.51
    p-tert-butyltoluene 10.11
    methyl 4-tert-butylbenzoate 41.96
    morpholine 75.31
    tert-butylamine 23.75
    n-dodecanol 13.46
    dimethoxymethane 124.2
    ethylene carbonate 34.78
    cyrene 60.82
    2-ethoxyethyl acetate 38.63
    2-ethylhexyl acetate 21.45
    1,2,4-trichlorobenzene 17.73
    4-methylpyridine 38.72
    dibutyl ether 14.52
    2,6-dimethyl-4-heptanol 14.27
    DEF 63.55
    dimethyl isosorbide 75.86
    tetrachloroethylene 16.08
    eugenol 49.32
    triacetin 38.11
    span 80 44.05
    1,4-butanediol 34.44
    1,1-dichloroethane 16.94
    2-methyl-1-pentanol 22.0
    methyl formate 83.92
    2-methyl-1-butanol 25.78
    n-decane 2.18
    butyronitrile 28.51
    3,7-dimethyl-1-octanol 18.73
    1-chlorooctane 7.93
    1-chlorotetradecane 4.3
    n-nonane 1.93
    undecane 1.81
    tert-butylcyclohexane 1.46
    cyclooctane 0.95
    cyclopentanol 36.73
    tetrahydropyran 38.02
    tert-amyl methyl ether 29.26
    2,5,8-trioxanonane 80.09
    1-hexene 4.15
    2-isopropoxyethanol 50.92
    2,2,2-trifluoroethanol 48.21
    methyl butyrate 33.35

    Scent© AI

1 4

IFRA standard 51

Recommendation
No restriction
Maximum acceptable concentrations in the finished product (%)
Category 1
Products applied to the lips
 No restriction Category 7A
Rinse-off products applied to the hair with some hand contact
 No restriction
Category 2
Products applied to the axillae
 No restriction Category 7B
Leave-on products applied to the hair with some hand contact
 No restriction
Category 3
Products applied to the face/body using fingertips
 No restriction Category 8
Products with significant anogenital exposure
 No restriction
Category 4
Products related to fine fragrance
 No restriction Category 9
Products with body and hand exposure, primarily rinse off
 No restriction
Category 5A
Body lotion products applied to the body using the hands (palms), primarily leave on
 No restriction Category 10A
Household care products with mostly hand contact
 No restriction
Category 5B
Face moisturizer products applied to the face using the hands (palms), primarily leave on
 No restriction Category 10B
Household care products with mostly hand contact, including aerosol/spray products (with potential leave-on skin contact)
 No restriction
Category 5C
Hand cream products applied to the hands using the hands (palms), primarily leave on
 No restriction Category 11A
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
 No restriction
Category 5D
Baby Creams, baby Oils and baby talc
 No restriction Category 11B
Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
 No restriction
Category 6
Products with oral and lip exposure
 No restriction Category 12
Products not intended for direct skin contact, minimal or insignificant transfer to skin
 No restriction